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Dual-comb spectroscopy has been proven a powerful tool in molecular characterization, which remains challenging to implement in the mid-infrared region due to difficulties in the realization of two mutually locked comb sources and efficient…

Optical frequency-comb-based-high-resolution spectrometers offer enormous potential for spectroscopic applications. Although various implementations have been demonstrated, the lack of suitable mid-infrared comb sources has impeded…

Dual-frequency comb spectroscopy has emerged as a disruptive technique for measuring wide-spanning spectra with high resolution, yielding a particularly powerful technique for sensitive multi-component gas analysis. We present a…

Absorption spectroscopy is a widely used technique that permits the detection and characterization of gas species at low concentrations. We propose a sensing strategy combining the advantages of frequency modulation spectroscopy with the…

Quantum Physics · Physics 2023-03-30 Alexandre Belsley

Frequency comb spectroscopy provides broadband access to molecular fingerprints with mode-defined spectral resolution. However, its deployment in non-cooperative gas sensing remains challenging because conventional implementations require…

We demonstrate dual-comb spectroscopy based on difference frequency generation of frequency-agile near-infrared frequency combs, produced with the help of electro-optic modulators. The combs have a remarkably flat intensity distribution and…

Mid-infrared optical frequency combs are of significant interest for molecular spectroscopy due to the large absorption of molecular vibrational modes on one hand, and the ability to implement superior comb-based spectroscopic modalities…

The mid-infrared spectral range (2 to 20 \mu m) is of particular importance for chemistry, biology and physics as many molecules exhibit strong ro-vibrational fingerprints. Frequency combs - broad spectral bandwidth coherent light sources…

Mid-infrared (mid-IR) frequency combs have broad applications in molecular spectroscopy and chemical/biological sensing. Recently developed microresonator-based combs in this wavelength regime could enable portable and robust devices using…

Cavity-enhanced frequency comb spectroscopy for molecule detection in the mid-infrared powerfully combines high resolution, high sensitivity, and broad spectral coverage. However, this technique, and essentially all spectroscopic methods,…

We report multipass broadband photoacoustic spectroscopy of trace gases in the mid-infrared. The measurement principle of the sensor relies on supercontinuum-based Fourier transform photoacoustic spectroscopy (FT-PAS), in which a scanning…

Instrumentation and Detectors · Physics 2022-08-31 Tommi Mikkonen , Tuomas Hieta , Goëry Genty , Juha Toivonen

Molecular diagnostics are a primary tool of modern chemistry, enabling researchers to map chemical reaction pathways and rates to better design and control chemical systems. Many chemical reactions are complex and fast, and existing…

Molecular spectroscopy in the mid-infrared portion of the electromagnetic spectrum (3--25 um) has been a cornerstone interdisciplinary analytical technique widely adapted across the biological, chemical, and physical sciences. Applications…

Instrumentation and Detectors · Physics 2018-09-18 Abijith S. Kowligy , Henry Timmers , Alex Lind , Ugaitz Elu , Flavio C. Cruz , Peter G. Schunemann , Jens Biegert , Scott A. Diddams

Mid-infrared high-resolution spectroscopy has proven an invaluable tool for the study of the structure and dynamics of molecules in the gas phase. The advent of frequency combs advances the frontiers of precise molecular spectroscopy. Here…

Optics · Physics 2019-02-28 Zaijun Chen , Theodor W. Hänsch , Nathalie Picqué

We devise a new detection technique for mid-infrared multi-heterodyne spectroscopy. As an experimental implementation, mid-infrared light interrogates a gas sample in the 3-$\mu$m region of the fundamental CH, OH, NH stretch in molecules…

Optics · Physics 2020-03-17 Zaijun Chen , Theodor W. Hänsch , Nathalie Picqué

While mid-infrared optical frequency combs have been widely utilized in areas such as trace gas sensing, chemical kinetics, and combustion science, the relatively low power per comb tooth has limited acquisition times and sensitivities. We…

Optics · Physics 2023-09-28 Adam T. Heiniger , Matthew J. Cich , David A. Long

We demonstrate coherent dual frequency-comb spectroscopy for detecting variations in greenhouse gases. High signal-to-noise spectra are acquired spanning 5990 to 6260 cm^-1 (1600 to 1670 nm) covering ~700 absorption features from CO2, CH4,…

The femtosecond laser frequency comb has enabled the 21st century revolution in optical synthesis and metrology. A particularly compelling technique that relies on the broadband coherence of two laser frequency combs is dual-comb…

Optics · Physics 2023-07-19 Vicente Duran , Santiago Tainta , Victor Torres-Company

Mid-infrared microscopy is an important tool for biological analyses, allowing a direct probe of molecular bonds in their low energy landscape. In addition to the label-free extraction of spectroscopic information, the application of…

High resolution and fast detection of molecular vibrational absorption is important for organic synthesis, pharmaceutical process and environmental monitoring, and is enabled by mid-infrared (mid-IR) laser frequency combs via dual-comb…

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