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Traps and structural defects at the hole and electron transport interfaces of the microcrystalline absorber limits the efficiency and long-term stability of perovskite solar cells (PSCs) due to accumulation of the ionic clusters,…

Perovskite solar cell (PSC) is one of the most promising next generation photovoltaic technologies, and there are considerable interests in the role of possible polarization of organic-inorganic halide perovskites (OIHPs) in photovoltaic…

Applied Physics · Physics 2021-08-29 Boyuan Huang , Zhenghao Liu , Changwei Wu , Yuan Zhang , Jinjin Zhao , Xiao Wang , Jiangyu Li

Recent observations indicated that the photoelectric conversion properties of perovskite materials are intimately related to the presence of superlattice structures and other unusual nanoscale features in them. The low dimensional or mixed…

Mesoscale and Nanoscale Physics · Physics 2021-05-11 Susmita Bhattacharya , Goutam Kumar Chandra , P. Predeep

Perovskite/Si tandem solar cells have the potential to considerably out-perform conventional solar cells. Under standard test conditions, perovskite/Si tandem solar cells already outperform the Si single junction. Under realistic…

Materials Science · Physics 2017-08-23 Moritz H. Futscher , Bruno Ehrler

Organic molecular hole-transport materials (HTMs) are appealing for the scalable manufacture of perovskite solar cells (PSCs) because they are easier to reproducibly prepare in high purity than polymeric and inorganic HTMs. There is also a…

Organic solar cells have reached record efficiencies with non-fullerene acceptors, yet their translation to industrial printing remains a critical bottleneck. Here we report the highest efficiency achieved for a fully…

Charge transport layers (CTLs) are key components of diffusion controlled perovskite solar cells, however, they can induce additional non-radiative recombination pathways which limit the open circuit voltage (V_OC) of the cell. In order to…

Interface engineering is one of the promising strategies for the long-term stabilization of perovskite solar cells, preventing chemical decomposition induced by external agents and promoting fast charge transfer. Recently, MXenes-2D…

To be able to increase the efficiency of perovskite solar cells which is one of the most substantial challenges ahead in photovoltaic industry, the structural and optical properties of perovskite CH3NH3PbI3-xBrx for values x=1-3 have been…

[4-(3,6-dimethyl-9H-carbazole-9-yl)butyl]phosphonic acid (Me-4PACz) self-assembled monolayer (SAM) has been employed in perovskite single junction and tandem devices demonstrating high efficiencies. However, a uniform perovskite layer does…

Semiconducting transition metal dichalcogenides (TMDs) are promising for flexible high-specific-power photovoltaics due to their ultrahigh optical absorption coefficients, desirable band gaps and self-passivated surfaces. However,…

Perovskite solar cells (PSCs) continue to be the front runner technology among emerging photovoltaic devices in terms of power conversion efficiency and application versatility. However, not only the stability but also the understanding of…

The material class of hybrid organic-inorganic perovskites has risen rapidly from a virtually unknown material in photovoltaic applications a short 7 years ago into a ~20% efficient thin-film solar cell material. As promising as this class…

Materials Science · Physics 2017-05-29 Dongwen Yang , Jian Lv , Xingang Zhao , Qiaoling Xu , Yuhao Fu , Yiqiang Zhan , Alex Zunger , Lijun Zhang

Here, we report an experimental demonstration of perovskite solar cells dominated by bimolecular recombination and critically analyse their performance against radiative limits. To this end, we first establish a set of quantitative…

Materials Science · Physics 2024-04-23 Kashimul Hossain , Dhyana Sivadas , Dinesh Kabra , Pradeep R. Nair

Tin fluoride (SnF2) is an indispensable additive for high-efficiency Pb-Sn perovskite solar cells (PSCs). However, the spatial distribution of SnF2 in the perovskite absorber is seldom investigated while essential for a comprehensive…

Despite the exceeding 23\% photovoltaic efficiency achieved in organic-inorganic hybrid perovskite solar cells obtaining, the stable materials with desirable band gap are rare and are highly desired. With the aid of first-principles…

Applied Physics · Physics 2020-02-21 Qiaoqiao Li , Liujiang Zhou , Yanfeng Ge , Yulu Ren , Jiangshan Zhao , Wenhui Wan , Kaicheng Zhang , Yong Liu

We demonstrate reduced surface recombination velocity (SRV) and enhanced power-conversion efficiency (PCE) in mixed-cation mixed-halide perovskite solar cells by using (3-aminopropyl)trimethoxysilane (APTMS) as a surface passivator. We show…

The use of antisolvents during the fabrication of solution-processed lead halide perovskite layers is increasingly common. Usually, the antisolvent is applied by pipetting during the spin-coating process, which often irreversibly alters the…

Previous studies of reverse-bias stability in perovskite solar cells have focused primarily on voltage controlled reverse-bias tests. Here we instead present an investigation of perovskite solar cell degradation under well-defined, constant…

The establishment of a rigorous theory on thermodynamics of light management in photovoltaics that accommodates various loss mechanisms as well as wave-optical effects in the absorption and reemission of light is at stake in this…