English
Related papers

Related papers: Neural Thermodynamic Integration: Free Energies fr…

200 papers

The free energy of a system is central to many material models. Although free energy data is not generally found directly, its derivatives can be observed or calculated. In this work, we present an Integrable Deep Neural Network (IDNN) that…

Materials Science · Physics 2019-06-26 G. H. Teichert , A. R. Natarajan , A. Van der Ven , K. Garikipati

Thermal Interface Materials (TIMs) are widely used in electronic packaging. Increasing power density and limited assembly space pose high demands on thermal management. Large cooling surfaces need to be covered efficiently. When joining the…

Machine Learning · Computer Science 2024-10-28 Simon Baeuerle , Marius Gebhardt , Jonas Barth , Andreas Steimer , Ralf Mikut

We demonstrate an efficient and accurate, general-purpose first-principles blueprint for calculating anharmonic vibrational free energy and predicting structural phase transition temperatures of solids. Thermodynamic integration is…

Materials Science · Physics 2024-03-14 Junsoo Park , Zhigang Wu , John W. Lawson

We present an implementation of alchemical free energy simulations at the quantum mechanical level by directly interpolating the electronic Hamiltonian. The method is compatible with any level of electronic structure theory and requires…

Chemical Physics · Physics 2024-09-02 Chenghan Li , Xing Zhang , Garnet Kin-Lic Chan

Metals which can form intermetallic compounds by an exothermic reaction constitute a class of reactive materials with multiple applications. Ni-Al laminates of thin alternating layers are being considered as model nanometric metallic…

Materials Science · Physics 2015-06-17 Luis Sandoval , Geoffrey H. Campbell , Jaime Marian

The process of deriving an interatomic potentials represents an attempt to integrate out the electronic degrees of freedom from the full quantum description of a condensed matter system. In practice it is the derivatives of the interatomic…

Materials Science · Physics 2016-06-23 G. J. Ackland

Targeted free energy perturbation uses an invertible mapping to promote configuration space overlap and the convergence of free energy estimates. However, developing suitable mappings can be challenging. Wirnsberger et al. (2020)…

Statistical Mechanics · Physics 2024-01-02 Soohaeng Yoo Willow , Lulu Kang , David D. L. Minh

The free energy plays a fundamental role in descriptions of many systems in continuum physics. Notably, in multiphysics applications, it encodes thermodynamic coupling between different fields. It thereby gives rise to driving forces on the…

Machine Learning · Computer Science 2023-07-19 Gregory Teichert , Anirudh Natarajan , Anton Van der Ven , Krishna Garikipati

Complex systems produce high-dimensional signals that lack macroscopic variables analogous to entropy, temperature, or free energy. This work introduces a thermoinformational formulation that derives entropy, internal energy, temperature,…

Neurons and Cognition · Quantitative Biology 2026-01-30 George-Rafael Domenikos , Victoria Leong

Computing free energy is a fundamental problem in statistical physics. Recently, two distinct methods have been developed and have demonstrated remarkable success: the tensor-network-based contraction method and the neural-network-based…

Statistical Mechanics · Physics 2025-04-17 Hanyan Cao , Yijia Wang , Feng Pan , Pan Zhang

Thermally coupled distillation is a new energy-saving method, but the traditional thermally coupled distillation simulation calculation process is complicated, and the optimization method based on the traditional simulation process is…

Chemical Physics · Physics 2021-02-09 ZhaoLan Zheng , Yu Qi

We develop a methodology for the calculation of surface free energies based on the probability distribution of a wandering interface. Using a simple extension of the NpT sampling, we allow the interface area to randomly probe the available…

Soft Condensed Matter · Physics 2009-11-13 Luis G. MacDowell , Pawel Bryk

The present research proposes a new memory-efficient method using diffusion models to inject turbulent inflow conditions into Large Eddy Simulation (LES) and Direct Numerical Simulation (DNS) for various flow problems. A guided diffusion…

We present a methodology for accelerating the estimation of the free energy from path integral Monte Carlo simulations by considering an intermediate artificial reference system where interactions are inexpensive to evaluate numerically.…

Ensuring a satisfactory statistical convergence of anharmonic thermodynamic properties requires sampling of many atomic configurations, however the methods to obtain those necessarily produce correlated samples, thereby reducing the…

Statistical Mechanics · Physics 2022-06-07 Erki Metsanurk

Accurate phase diagram calculation from molecular dynamics requires systematic treatment and convergence of statistical averages. In this work we propose a Gaussian process regression based framework for reconstructing the free energy…

Computational Physics · Physics 2021-11-02 V. Ladygin , I. Beniya , E. Makarov , A. Shapeev

Most currently available methods for modeling multiphysics, including thermoelasticity, using machine learning approaches, are focused on solving complete multiphysics problems using data-driven or physics-informed multi-layer perceptron…

Computational Engineering, Finance, and Science · Computer Science 2024-04-29 Diab W. Abueidda , Mostafa E. Mobasher

This article describes nonequilibrium techniques for the calculation of free energies of solids using molecular dynamics (MD) simulations. These methods provide an alternative to standard equilibrium thermodynamic integration methods and…

Materials Science · Physics 2022-01-13 Rodrigo Freitas , Mark Asta , Maurice de Koning

Excess contributions to the free energy due to interfaces occur for many problems encountered in the statistical physics of condensed matter when coexistence between different phases is possible (e.g. wetting phenomena, nucleation, crystal…

Statistical Mechanics · Physics 2015-05-27 Kurt Binder , Benjamin Block , Subir K. Das , Peter Virnau , David Winter

We introduce an efficient and robust method to compute alchemical free energy differences, resulting from the application of multiple walker Adaptive Biasing Force (ABF) in conjunction with strongly damped Langevin $\lambda$-dynamics.…