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Optically dark excitonic states play a critical role in the valleytronic, electronic, and optical properties of monolayer semiconducting transition metal dichalcogenides. Here, we investigate how electrostatic doping affects the in-plane…

Exciton spectroscopy serves as a sensitive probe of electronic states in two-dimensional semiconductors. A prominent feature in optical spectra is the trion peak arising from the binding of a charge carrier to an exciton. The splitting…

Mesoscale and Nanoscale Physics · Physics 2025-07-23 Arthur Christianen , Atac Imamoglu

We revisit low-temperature optical spectra of transition-metal dichalcogenide monolayers and point to a possible crystallization of electrons (or holes) at low to moderate charge densities. To calculate the excitonic spectra under such…

Mesoscale and Nanoscale Physics · Physics 2023-08-16 Dinh Van Tuan , Hanan Dery

The photoluminescence (PL) spectrum of transition metal dichalcogenides (TMDs) shows a multitude of emission peaks below the bright exciton line and not all of them have been explained yet. Here, we study the emission traces of…

Charged excitons, or X$^{\pm}$-trions, in monolayer transition metal dichalcogenides have binding energies of several tens of meV. Together with the neutral exciton X$^0$ they dominate the emission spectrum at low and elevated temperatures.…

We present low temperature magneto-photoluminescence experiments which demonstrate the brightening of dark excitons by an in-plane magnetic field $B$ applied to monolayers of different semiconducting transition metal dichalcogenides. For…

Mesoscale and Nanoscale Physics · Physics 2017-01-18 M. R. Molas , C. Faugeras , A. O. Slobodeniuk , K. Nogajewski , M. Bartos , D. M. Basko , M. Potemski

Excitons and trions (or exciton-polarons) in transition metal dichalcogenides (TMDs) are known to decay predominantly through intravalley transitions. Electron-hole recombination across different valleys can also play a significant role in…

Monolayer transition-metal dichalcogenides, such as WSe$_2$, are direct gap, multi-valley semiconductors. Long-range electron-hole exchange interactions mix the valleys, yielding dispersion relations for massive ($\propto Q^2$) as well as…

Mesoscale and Nanoscale Physics · Physics 2025-08-20 A. Delhomme , T. Amit , P. Ji , C. Faugeras , S. Refaely-Abramson , J. J. Finley , A. V. Stier

Low temperature and polarization resolved magneto-photoluminescence experiments are used to investigate the properties of dark excitons and dark trions in a monolayer of WS$_2$ encapsulated in hexagonal BN (hBN). We find that this system is…

We report charged exciton (trion) formation dynamics in doped monolayer transition metal dichalcogenides (TMDs), specifically molybdenum diselenide (MoSe2), using resonant two-color pump-probe spectroscopy. When resonantly pumping the…

The direct band gap character and large spin-orbit splitting of the valence band edges (at the K and K' valleys) in monolayer transition metal dichalcogenides have put these two-dimensional materials under the spot-light of intense…

Mesoscale and Nanoscale Physics · Physics 2017-04-10 Mark Danovich , Viktor Zólyomi , Vladimir I. Fal'ko

Light emission from higher-order correlated excitonic states has been recently reported in hBN-encapsulated monolayer WSe2 and WS2 upon optical excitation. These exciton complexes are found to be bound states of excitons residing in…

Mesoscale and Nanoscale Physics · Physics 2019-04-19 Matthias Paur , Aday J. Molina-Mendoza , Rudolf Bratschitsch , Kenji Watanabe , Takashi Taniguchi , Thomas Mueller

Monolayer group VI transition metal dichalcogenides have recently emerged as semiconducting alternatives to graphene in which the true two-dimensionality (2D) is expected to illuminate new semiconducting physics. Here we investigate…

Mesoscale and Nanoscale Physics · Physics 2014-03-05 Jason S Ross , Sanfeng Wu , Hongyi Yu , Nirmal J Ghimire , Aaron M Jones , Grant Aivazian , Jiaqiang Yan , David G. Mandrus , Di Xiao , Wang Yao , Xiaodong Xu

The monolayer transition metal dichalcogenides are an emergent semiconductor platform exhibiting rich excitonic physics with coupled spin-valley degree of freedom and optical addressability. Here, we report a new series of low energy…

Spin-forbidden intravalley dark exciton in tungsten-based transition metal dichalcogenides (TMDCs), owing to its unique spin texture and long lifetime, has attracted intense research interest. Here, we show that we can control the dark…

The optical properties of semiconducting transition metal dichalcogenides are dominated by both neutral excitons (electron-hole pairs) and charged excitons (trions) that are stable even at room temperature. While trions directly influence…

Mesoscale and Nanoscale Physics · Physics 2016-07-26 Kai Hao , Lixiang Xu , Philipp Nagler , Akshay Singh , Kha Tran , Chandriker Kavir Dass , Christian Schüller , Tobias Korn , Xiaoqin Li , Galan Moody

Monolayer transition metal dichalcogenides (TMDs) are direct gap semiconductors that hold great promise for advanced applications in photonics and optoelectronics. Understanding the interplay between their radiative and non-radiative…

We present photoluminescence measurements in monolayer WSe$_2$, which point to the importance of the interaction between charged particles and excitonic complexes. The theoretical analysis highlights the key role played by exchange…

Materials Science · Physics 2022-02-15 Min Yang , Lei Ren , Cedric Robert , Dinh Van Tuan , Laurent Lombez , Bernhard Urbaszek , Xavier Marie , Hanan Dery

Monolayer transition metal dichalcogenide (TMDC) crystals, as direct-gap materials with unusually strong light-matter interaction, have attracted much recent attention. In contrast to the initial understanding, the minima of the conduction…

The possibility of almost linear tuning of the band gap and of the electrical and optical properties in monolayers (MLs) of semiconducting transition metal dichalcogenide (S-TMD) alloys opens up the way to fabricate materials with on-demand…

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