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Perovskite solar cells (PSCs) represent a breakthrough in photovoltaic technology, combining high power conversion efficiencies (PCEs), ease of fabrication, and tunable optoelectronic properties. However, their commercial viability is…

Materials Science · Physics 2025-06-30 Dilshod Nematov

Organic-inorganic metal halide perovskites (HaPs) are intensively studied for their light-harvesting properties. Owing to the interplay between strong electron-electron interaction and spin-orbit coupling (SOC), their quantitative…

Materials Science · Physics 2021-11-02 Cecilia Vona , Dmitrii Nabok , Claudia Draxl

Perovskite solar cells (PSCs) have shown remarkably improved power-conversion efficiency of around 25%. However, their working principle remains arguable and the stability issue has not been solved yet. In this report, we revealed that the…

Applied Physics · Physics 2019-10-29 Junseop Byeon , Jutae Kim , Ji-Young Kim , Gunhee Lee , Kijoon Bang , Namyoung Ahn , Mansoo Choi

Hybrid organic-inorganic halide perovskites for photovoltaics have attracted research interest due to their unique material properties, but suffered from poor material stability. In this work, we investigated the surface phase diagrams of…

Applied Physics · Physics 2021-09-30 Yun-Sim Kim , Chol-Hyok Ri , Yun-Hyok Kye , Un-Gi Jong , Chol-Jun Yu

Negative capacitance at the low-frequency domain and inverted hysteresis are familiar features in perovskite solar cells, where the origin is still under discussion. Here we use Impedance Spectroscopy to analyse these responses in…

One of the most significant features of lead-halide perovskites are their ability to have comparably slow recombination despite the fact that these materials are mostly processed from solution at room temperature. The slow recombination…

Applied Physics · Physics 2019-07-26 Thomas Kirchartz

The competition between corner, edge and face-sharing octahedral networks is a cause of phase inhomogeneity in metal halide perovskite thin-films. Here we probe the charged iodine vacancy distribution and transport at the junction between…

Materials Science · Physics 2022-11-03 Young Won Woo , Zhenzhu Li , Young-Kwang Jung , Ji-Sang Park , Aron Walsh

The esoteric importance of intermolecular hydrogen bonding interaction to design novel methylammonium trihalide organic-inorganic hybrid perovskite solar cell materials is uncovered, establishing the unified structure-property relationship…

Materials Science · Physics 2017-04-25 Arpita Varadwaj , Pradeep R. Varadwaj , Koichi Yamashita

Quasi two-dimensional (2D) colloidal synthesis made quantum confinement readily accessible in perovskites, generating additional momentum in perovskite LED research and lasing. Ultrathin perovskite layers exhibit high exciton binding…

Materials Science · Physics 2024-09-04 André Niebur , Eugen Klein , Rostyslav Lesyuk , Christian Klinke , Jannika Lauth

All-perovskite tandem solar cells promise high photovoltaic performance at low cost. So far however, their efficiencies cannot compete with traditional inorganic multi-junction solar cells and they generally underperform in comparison to…

Semipermeable silica membranes are attractive as protective coatings for metal electrocatalysts such as platinum but their impact on the catalytic properties has not been fully understood. Here, we develop a first principles formalism to…

Materials Science · Physics 2020-10-27 Jianzhou Qu , Alexander Urban

Non-stoichiometric nickel oxide (NiOx) is the only metal oxide successfully used as hole transport material in p-i-n type perovskite solar cells (PSCs). Its favorable opto-electronic properties and facile large-scale preparation methods are…

Lead halide perovskites have emerged as highly efficient solar cell materials. However, to date, the most promising members of this class are polymorphs, in which a wide-band gap $\delta$ phase competes with the photoactive perovskite…

Materials Science · Physics 2024-07-08 C. Vona , M. Dankl , A. Boziki , M. P. Bircher , U. Rothlisberger

A ferroelectric field effect in the bulk heterojunction was found when an external electric field (EEF) was applied on the active layer of polymer solar cells (PSCs) during the annealing process of the active layer spin-coated with poly…

Materials Science · Physics 2015-06-17 Meng Li , Heng Ma , Hairui Liu , Yurong Jiang , Heying Niu , Adil Amat

Perovskite photovoltaics (PVs) have attracted attention because of their excellent power conversion efficiency (PCE). Critical issues related to large area PV performance, reliability and lifetime need to be addressed. Here, we show that…

Materials Science · Physics 2016-10-07 Achilleas Savva , Ignasi Burgues-Ceballos , Stelios A. Choulis

Herein, we report on the synthesis and investigation of two triazino-isoquinoline tetrafluoroborate electrolytes as hole-blocking layers in methylammonium triiodide perovskite photovoltaic devices with fullerene electron extraction layer.…

Lead iodide perovskites have attracted considerable interest in the upcoming photovoltaic technologies and optoelectronic devices. Therefore, an accurate theoretical description of the electronic and optical properties especially to…

Materials Science · Physics 2022-01-20 Pooja Basera , Arunima Singh , Deepika Gill , Saswata Bhattacharya

The atomic scale dynamics of halide perovskites have a direct impact not only on their thermal stability but their optoelectronic properties. Progress in machine learned potentials has only recently enabled modeling the finite temperature…

Materials Science · Physics 2023-11-20 Erik Fransson , Julia Wiktor , Paul Erhart

Perovskite photoelectrodes are being extensively studied in search for photocatalytic materials that can produce hydrogen through water splitting. The solar-to-hydrogen efficiency of these materials is critically dependent on the…

Applied Physics · Physics 2019-06-26 Yihuang Xiong , Ismaila Dabo

Perovskites are promising next-generation absorber materials for low-cost and high-efficiency solar cells. Although perovskite cells are configured similar to the classical solar cells, their operation is unique and requires development of…

Mesoscale and Nanoscale Physics · Physics 2018-02-01 Xingshu Sun , Reza Asadpour , Wanyi Nie , Aditya D. Mohite , Muhammad A. Alam