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The topic of this thesis is the theoretical analysis of the optomechanical coupling effects in a high-finesse optical cavity, and the experimental realization of such a device. Radiation pressure exerted by light limits the sensitivity of…

Quantum Physics · Physics 2009-09-29 Yassine Hadjar

Recent experiments have shown contradictory effects of strong light-matter coupling on exciton-exciton annihilation (EEA) in organic molecular systems. In this work, we perform numerical simulations of polariton dynamics and reveal the role…

Chemical Physics · Physics 2026-05-20 I. Sokolovskii , B. S. Humphries , J. Blumberger , G. Groenhof

Experiments at the interface of quantum-optics and chemistry have revealed that strong coupling between light and matter can substantially modify chemical and physical properties of molecules and solids. While the theoretical description of…

Quantum Physics · Physics 2020-02-06 Christian Schäfer , Michael Ruggenthaler , Vasil Rokaj , Angel Rubio

We study the cavity mode frequencies of a Fabry-P\'erot cavity containing two vibrating dielectric membranes. We derive the equations for the mode resonances and provide approximate analytical solutions for them as a function of the…

Quantum Physics · Physics 2016-06-30 J. Li , A. Xuereb , N. Malossi , D. Vitali

The interaction between vortex beam (VB) and molecule has drawn much attention in recent years, but the lack of theoretical method somehow limits its further analysis, especially when the molecular rotational degree of freedom is involved…

Optics · Physics 2021-05-04 Guanming Lao

For a small fraction of hot CO2 molecules immersed in a liquid-phase CO2 thermal bath, classical cavity molecular dynamics simulations show that forming collective vibrational strong coupling (VSC) between the C=O asymmetric stretch of CO2…

Chemical Physics · Physics 2021-05-11 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

Irradiation with light provides a powerful tool to interrogate, control or induce new quantum states of matter out of equilibrium, however a microscopic understanding of light-matter coupling in interacting electron systems remains a…

Strongly Correlated Electrons · Physics 2023-03-06 Wai Ting Tai , Martin Claassen

Demonstrating and exploiting the quantum nature of larger, more macroscopic mechanical objects would help us to directly investigate the limitations of quantum-based measurements and quantum information protocols, as well as test long…

Quantum Physics · Physics 2011-03-16 J. D. Teufel , D. Li , M. S. Allman , K. Cicak , A. J. Sirois , J. D. Whittaker , R. W. Simmonds

The resonant interaction between two two-level atoms and m- electromagnetic modes in a cavity is considered. Entanglement dynamics between two atoms is examined. In particular we compare dynamical variations for different cavity modes as…

Quantum Physics · Physics 2009-03-24 P. Saha , N. Nayak , A. S. Majumdar

The electromagnetic field in an optical cavity can dramatically modify and even control chemical reactivity via vibrational strong coupling (VSC). Since the typical vibration and cavity frequencies are considerably higher than thermal…

Quantum Physics · Physics 2021-09-29 Peiyun Yang , Jianshu Cao

Following experimental evidence that vibrational polaritons, formed from collective vibrational strong coupling (VSC) in optical microcavities, can modify ground-state reaction rates, a spate of theoretical explanations relying on…

Chemical Physics · Physics 2023-04-14 Matthew Du , Yong Rui Poh , Joel Yuen-Zhou

We investigate the influence of thermally activated internal molecular dynamics on the phase shifts of matter waves inside a molecule interferometer. While de Broglie physics generally describes only the center-of-mass motion of a quantum…

As per the Franck-Condon principle, absorption spectroscopy reveals changes in nuclear geometry in molecules or solids upon electronic excitation. It is often assumed these changes cannot be resolved beyond the ground vibrational…

Chemical Physics · Physics 2024-01-23 Sindhana Pannir-Sivajothi , Joel Yuen-Zhou

Ultracold atoms coupled to optical cavities offer a powerful platform for studying strongly correlated many-body physics. Here, we propose an experimental scheme for creating biatomic molecules via cavity-enhanced photoassociation from an…

Quantum Gases · Physics 2026-04-17 Yun Chen , Yuqi Wang , Jingjun You , Yingqi Liu , Su Yi , Yuangang Deng

Using carefully designed hybrid metal-dielectric resonators, we study molecular optomechanics in the strong coupling regime ($g_{\rm }^2/\omega_m {>} \kappa$), which manifests in anharmonic emission lines in the sideband-resolved region of…

Mesoscale and Nanoscale Physics · Physics 2019-11-28 Mohsen Kamandar Dezfouli , Reuven Gordon , Stephen Hughes

Engineering the properties of quantum materials via strong light-matter coupling is a compelling research direction with a multiplicity of modern applications. Those range from modifying charge transport in organic molecules, steering…

We show that strong electron-electron interactions in cavity-coupled quantum materials can enable collectively enhanced light-matter interactions with ultrastrong effective coupling strengths. As a paradigmatic example we consider a…

Strongly Correlated Electrons · Physics 2019-09-04 Martin Kiffner , Jonathan Coulthard , Frank Schlawin , Arzhang Ardavan , Dieter Jaksch

An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…

Chemical Physics · Physics 2024-06-19 Lorenz S. Cederbaum

Cavity electro-(opto-)mechanics allows us to access not only single isolated but also multiple mechanical modes in a massive object. Here we develop a multi-mode electromechanical system in which a several membrane vibrational modes are…

We propose an optomechanical scheme for reaching quantum entanglement in vibration polaritons. The system involves $N$ molecules, whose vibrations can be fairly entangled with plasmonic cavities. We find that the vibration-photon…

Quantum Physics · Physics 2024-05-28 Jian Huang , Dangyuan Lei , Girish S. Agarwal , Zhedong Zhang
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