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The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

The second law of thermodynamics is a statement about the statistics of the entropy production, $\langle \Sigma \rangle \geq 0$. For small systems, it is known that the entropy production is a random variable and negative values ($\Sigma <…

Statistical Mechanics · Physics 2022-01-05 Domingos S. P. Salazar

Physical systems that power motion and create structure in a fixed amount of time dissipate energy and produce entropy. Whether living or synthetic, systems performing these dynamic functions must balance dissipation and speed. Here, we…

Statistical Mechanics · Physics 2020-12-18 Schuyler B. Nicholson , Luis Pedro Garcia-Pintos , Adolfo del Campo , Jason R. Green

We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

Statistical Mechanics · Physics 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe

We proved when random-variable fluctuations obey the central limit theorem the equality of the uncertainty relation corresponds to the thermodynamic equilibrium state. The inequality corresponds to the thermodynamic non-equilibrium state.…

Quantum Physics · Physics 2007-05-23 You-gang Feng

We generalize stochastic thermodynamics to include information reservoirs. Such information reservoirs, which can be modeled as a sequence of bits, modify the second law. For example, work extraction from a system in contact with a single…

Statistical Mechanics · Physics 2014-11-17 Andre C. Barato , Udo Seifert

Fluctuations of thermodynamic observables, such as heat and work, contain relevant information on the underlying physical process. These fluctuations are however not taken into account in the traditional laws of thermodynamics. While the…

Quantum Physics · Physics 2022-05-25 Timo Kerremans , Peter Samuelsson , Patrick P. Potts

There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…

Statistical Mechanics · Physics 2009-09-25 Gavin E. Crooks

Statistical mechanics descriptions of the second law of thermodynamics generally imply point-like particles driven by a dissipative overall mechanism for their simultaneous time-evolution. As the number of involved particles grows larger,…

General Physics · Physics 2016-02-16 Hans R. Moser

In a thermodynamical process, the dissipation or production of entropy can only be positive or zero according to the second law of thermodynamics. However the laws of thermodynamics are applicable to large systems in the thermodynamic…

Statistical Mechanics · Physics 2015-05-13 Soma Datta , Arun Roy

Isoenergetic thermalization amongst $n$ bodies is a well-known irreversible process, bringing the bodies to a common temperature $T_F$ and leading to a rise in the total entropy of the bodies. We express this change in entropy using the…

Statistical Mechanics · Physics 2024-11-07 Vansh Narang , Renuka Rai , Ramandeep S. Johal

With the discussion of three examples, we aim at clarifying the concept of energy transfer associated with dissipation in mechanics and in thermodynamics. The dissipation effects due to dissipative forces, such as the friction force between…

Classical Physics · Physics 2016-06-09 Julio Guemez , Manuel Fiolhais

At the dawn of thermodynamics, Carnot's constraint on efficiency of heat engines stimulated the formulation of one of the most universal physical principles, the second law of thermodynamics. In recent years, the field of heat engines…

Statistical Mechanics · Physics 2021-12-23 Viktor Holubec , Artem Ryabov

This paper is a non-technical, informal presentation of our theory of the second law of thermodynamics as a law that is independent of statistical mechanics and that is derivable solely from certain simple assumptions about adiabatic…

Mathematical Physics · Physics 2009-10-31 Elliott H. Lieb , Jakob Yngvason

This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

We derive a general quantum exchange fluctuation theorem for multipartite systems with arbitrary coupling strengths by taking into account the informational contribution of the back-action of the quantum measurements, which contributes to…

Quantum Physics · Physics 2023-07-18 Akira Sone , Diogo O. Soares-Pinto , Sebastian Deffner

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…

Statistical Mechanics · Physics 2009-11-11 D. H. E. Gross , J. F. Kenney

The reliability of physical theories depends on whether they agree with well established physical laws. In this work, we address the compatibility of the Hamiltonian formulation of linear-response theory with the Second Law of…

Statistical Mechanics · Physics 2020-01-16 Pierre Nazé , Marcus V. S. Bonança

The authors of Ref. [1] claim to have experimental verification of violations of the second law of thermodynamics based on the assertions: (i) "for large systems and over long times the entropy production rate is necessarily positive"; (ii)…

Quantum Physics · Physics 2007-06-20 Elias P. Gyftopoulos

Thermodynamic uncertainty relations quantify how the signal-to-noise ratio of a given observable is constrained by dissipation. Fluctuation relations generalize the second law of thermodynamics to stochastic processes. We show that any…

Statistical Mechanics · Physics 2019-11-26 Patrick P. Potts , Peter Samuelsson