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The Trotterized Unitary Coupled Cluster Single and Double (UCCSD) ansatz has recently attracted interest due to its use in Variation Quantum Eigensolver (VQE) molecular simulations on quantum computers. However, when the size of molecules…

Chemical Physics · Physics 2023-05-29 Mohammad Haidar , Marko J. Rančić , Yvon Maday , Jean-Philip Piquemal

We introduce the Nuclear Electronic All-Particle Density Matrix Renormalization Group (NEAP-DMRG) method for solving the time-independent Schr\"odinger equation simultaneously for electrons and other quantum species. In contrast to already…

Chemical Physics · Physics 2020-05-29 Andrea Muolo , Alberto Baiardi , Robin Feldmann , Markus Reiher

We present an improved variant of the in-medium similarity renormalization group (IM-SRG) based on the Magnus expansion. In the new formulation, one solves flow equations for the anti-hermitian operator that, upon exponentiation, yields the…

Nuclear Theory · Physics 2015-10-07 T. D. Morris , N. Parzuchowski , S. K. Bogner

We apply the renormalization group optimized perturbation theory (RGOPT)to evaluate the QCD (matter) pressure at the two-loop level considering three flavors of massless quarks in a dense and cold medium. Already at leading order…

High Energy Physics - Phenomenology · Physics 2019-12-11 Jean-Loïc Kneur , Marcus Benghi Pinto , Tulio Eduardo Restrepo

A novel multiscale numerical method is developed to accelerate direct simulation Monte Carlo (DSMC) simulations for polyatomic gases with internal energy. This approach applies the general synthetic iterative scheme to stochastic…

Computational Physics · Physics 2025-01-22 Liyan Luo , Tao Huang , Qi Li , Lei Wu

The goal of the present paper is twofold. First, a novel expansion many-body method applicable to superfluid open-shell nuclei, the so-called Bogoliubov in-medium similarity renormalization group (BIMSRG) theory, is formulated. This…

Nuclear Theory · Physics 2021-02-23 A. Tichai , P. Arthuis , H. Hergert , T. Duguet

We investigate the numerical stability of time-dependent coupled-cluster theory for many-electron dynamics in intense laser pulses, comparing two coupled-cluster formulations with full configuration interaction theory. Our numerical…

The accuracy at which total energies of open-shell atoms and organic radicals may be calculated is assessed for selected coupled cluster perturbative triples expansions, all of which augment the coupled cluster singles and doubles (CCSD)…

Chemical Physics · Physics 2016-05-17 Janus Juul Eriksen , Devin A. Matthews , Poul Jørgensen , Jürgen Gauss

We study the distorted wave renormalisation group (DWRG), a tool for constructing power-counting schemes in systems where some diagrams must be summed to all orders. We solve the DWRG eqaution for a variety of long-range potentials…

Nuclear Theory · Physics 2007-05-23 T. Barford

The density matrix renormalization group (DMRG) is a powerful method to treat static correlation. Here we present an inexpensive way to add additional dynamic correlation energy to a DMRG self-consistent field (DMRG) wave function using…

Chemical Physics · Physics 2018-08-21 Prachi Sharma , Varinia Bernales , Stefan Knecht , Donald G. Truhlar , Laura Gagliardi

We have developed an {\it ab initio} deformed in-medium similarity renormalization group (IMSRG) for open-shell nuclei. This is a single-reference IMSRG in deformed Hartree-Fock (HF) basis. Deformed wave functions are more efficient in…

Nuclear Theory · Physics 2022-07-13 Q. Yuan , S. Q. Fan , B. S. Hu , J. G. Li , S. Zhang , S. M. Wang , Z. H. Sun , Y. Z. Ma , F. R. Xu

We propose a second renormalization group (SRG) in the triad representation of tensor networks. The SRG method improves two parts of the triad tensor renormalization group, which are the decomposition of intermediate tensors and the…

Strongly Correlated Electrons · Physics 2022-05-11 Daisuke Kadoh , Hideaki Oba , Shinji Takeda

In this paper, a way of generalizing the tensor renormalization group(TRG) is proposed. Mathematically, the connection between patterns of tensor renormalization group and the concept of truncation sequence in polytope geometry is…

Statistical Mechanics · Physics 2017-06-12 Peiyuan Teng

We have studied electron correlations in the doped two-dimensional (2D) Hubbard model by using the coupled-cluster method (CCM) to investigate whether or not the method can be applied to correct the independent particle approximations…

Strongly Correlated Electrons · Physics 2009-10-31 Yoshihiro Asai , Hideki Katagiri

A momentum-space approach of the density-matrix renormalization-group (DMRG) method is developed. Ground state energies of the Hubbard model are evaluated using this method and compared with exact diagonalization as well as quantum…

Condensed Matter · Physics 2009-10-28 T. Xiang

The recently developed tensor renormalization-group (TRG) method provides a highly precise technique for deriving thermodynamic and critical properties of lattice Hamiltonians. The TRG is a local coarse-graining transformation, with the…

Statistical Mechanics · Physics 2008-02-18 Michael Hinczewski , A. Nihat Berker

We present a cost-effective treatment of the triple excitation amplitudes in the time-dependent optimized coupled-cluster (TD-OCC) framework called TD-OCCDT(4) for studying intense laser-driven multielectron dynamics. It considers triple…

Chemical Physics · Physics 2021-07-07 Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa

We discuss diagrammatic modifications to the coupled cluster doubles (CCD) equations, wherein different groups of terms out of rings, ladders, crossed-rings and mosaics can be removed to form approximations to the coupled cluster method, of…

Chemical Physics · Physics 2014-05-06 James J. Shepherd , Thomas. M. Henderson , Gustavo E. Scuseria

The method of sub-iteration, which was previously applied to the higher-order coupled cluster amplitude equations, is extended to the case of the coupled cluster $\Lambda$ equations. The sub-iteration procedure for the $\Lambda$ equations…

Chemical Physics · Physics 2025-03-26 Devin A. Matthews

The presence of many degenerate $d/f$ orbitals makes polynuclear transition metal compounds such as iron-sulfur clusters in nitrogenase challenging for state-of-the-art quantum chemistry methods. To address this challenge, we present the…

Chemical Physics · Physics 2023-12-22 Chunyang Xiang , Weile Jia , Wei-Hai Fang , Zhendong Li