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A relativistic version of the coupled-cluster single-double (CCSD) method is developed for atoms with a single valence electron. In earlier work, a linearized version of the CCSD method (with extensions to include a dominant class of triple…

Atomic Physics · Physics 2009-11-13 Rupsi Pal , M. S. Safronova , W. R. Johnson , Andrei Derevianko , Sergey G. Porsev

In this work, we investigate the possibility of improving multireference-driven coupled cluster (CC) approaches with an algorithm that iteratively combines complete active space (CAS) calculations with tailored CC and externally corrected…

Chemical Physics · Physics 2025-03-06 Robin Feldmann , Max Mörchen , Jakub Lang , Michał Lesiuk , Markus Reiher

In this article, we investigate the numerical and theoretical aspects of the coupled-cluster method tailored by matrix-product states. We investigate chemical properties of the used method, such as energy size extensivity and the…

We introduce a method for analyzing ground state properties of quantum many body systems, based on the characterization of separability and entanglement by single subsystem unitary operations. We apply the method to the study of the ground…

Quantum Physics · Physics 2008-01-19 S. M. Giampaolo , F. Illuminati , P. Verrucchi , S. De Siena

This chapter gives an introduction to qualitative and quantitative topological analyses of molecular electronic transitions. Among the possibilities for qualitatively describing how the electronic structure of a molecule is reorganized upon…

Chemical Physics · Physics 2018-11-27 Thibaud Etienne

A determination of the excited energy eigenstates of the nucleon, $s=c{1}{2}$, $I={1}{2}$, $N^{\pm}$, is presented in full QCD using 2+1 flavor PACS-CS gauge configurations. The correlation-matrix method is used and is built using standard…

High Energy Physics - Lattice · Physics 2013-06-26 M. Selim Mahbub , Waseem Kamleh , Derek B. Leinweber , Peter J. Moran , Anthony G. Williams

The excess entanglement resulting from exciting a finite number of quasiparticles above the ground state of a free integrable quantum field theory has been investigated quite extensively in the literature. It has been found that it takes a…

High Energy Physics - Theory · Physics 2023-01-18 Luca Capizzi , Olalla A. Castro-Alvaredo , Cecilia De Fazio , Michele Mazzoni , Lucía Santamaría-Sanz

This paper describes a geometrical method for finding the roots $r_1$, $r_2$ of a quadratic equation in one complex variable of the form $x^2+c_1 x+c_2=0$, by means of a Line $L$ and a Circumference $C$ in the complex plane, constructed…

Numerical Analysis · Mathematics 2024-07-31 Daniel Alba-Cuellar

We present a general theory to treat periodic solids with quantum-chemistry methods. It relies on two main developments: 1) the modeling of a solid as a Clifford torus which is a torus that is both periodic and flat and 2) the introduction…

Quantum Physics · Physics 2025-12-04 Amer Alrakik , Gian Luigi Bendazzoli , Stefano Evangelisti , J. Arjan Berger

A quantum computing algorithm is proposed to obtain low-lying excited states in many-body interacting systems. The approximate eigenstates are obtained by using a quantum space diagonalization method in a subspace of states selected from…

Quantum Physics · Physics 2025-06-30 Jing Zhang , Denis Lacroix

A novel, exact, theoretical method for the study of the excited states of a system is presented. It is demonstrated how to transform the excited state problem of one Hamiltonian into the ground state problem of an auxiliary one. From this,…

Quantum Physics · Physics 2012-06-22 Ramón Alain Miranda Quintana

By the analytical coupled cluster method (CCM), we study both the ground state and lowest-lying excited-state properties of the alternating bond diamond chain. The numerical exact diagonalization (ED) method is also applied to the chain to…

Strongly Correlated Electrons · Physics 2015-11-09 Jian-Jun Jiang , Yong-Jun Liu , Fei Tang , Cui-Hong Yang

We propose a framework to design concurrently a frustration-free quantum many-body Hamiltonian and its numerically exact ground states on a sufficiently large finite-size cluster in one and two dimensions using an elementary matrix product…

Strongly Correlated Electrons · Physics 2024-12-17 Hidehiro Saito , Chisa Hotta

Preparing the ground state of a given Hamiltonian and estimating its ground energy are important but computationally hard tasks. However, given some additional information, these problems can be solved efficiently on a quantum computer. We…

Quantum Physics · Physics 2020-12-16 Lin Lin , Yu Tong

Exascale computing could soon enable a predictive theory of nuclear structure and reactions rooted in the Standard Model, with quantifiable and systematically improvable uncertainties. Such a predictive theory will help exploit experiments…

Excited-state dynamics simulations are a powerful tool to investigate photo-induced reactions of molecules and materials and provide complementary information to experiments. Since the applicability of these simulation techniques is limited…

Geometric positions of square roots of coherent states of CCR algebras are investigated along with an explicit formula for transition amplitudes among them, which is a natural extension of our previous results on quasifree states and will…

Mathematical Physics · Physics 2012-07-03 Shigeru Yamagami

We present and compare several many-body methods as applied to two-dimensional quantum dots with circular symmetry. We calculate the approximate ground state energy using a harmonic oscillator basis optimized by Hartree-Fock (HF) theory and…

In this work we present a coupled-cluster theory for the propagation of multireference electronic systems initiating at general quantum mechanical states. Our formalism is based on the infinitesimal analysis of modified cluster operators,…

Chemical Physics · Physics 2025-05-09 Martín A. Mosquera

We employ the closed-shell perturbed relativistic coupled-cluster (RCC) theory developed by us earlier [Phys. Rev. A {\bf 77}, 062516 (2008)] to evaluate the ground state static electric dipole polarizabilities (\alpha s) of several atomic…

Atomic Physics · Physics 2013-12-09 Yashpal Singh , B. K. Sahoo , B. P. Das
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