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The correspondence principle in physics between quantum mechanics and classical mechanics suggests deep relations between spectral and geometric entities of Riemannian manifolds. We survey---in a way intended to be accessible to a wide…

Dynamical Systems · Mathematics 2020-11-20 A. Pohl , D. Zagier

It is shown that the vacuum state of weakly interacting quantum field theories can be described, in the Heisenberg picture, as a linear combination of randomly distributed incoherent paths that obey classical equations of motion with…

High Energy Physics - Theory · Physics 2009-11-07 Ram Brustein , David H. Oaknin

The dynamics of hybrid systems -- i.e. ones in which classical and quantum degrees of freedom co-exist and interact -- feature both diffusion in the classical sector and decoherence in the quantum state. In this article, we will consider…

Quantum Physics · Physics 2025-10-10 Emanuele Panella

This work identifies geometric effects on dynamics due to nonadiabatic couplings in Born Oppenheimer systems and provides a systematic method for deriving corrections to mixed quantum-classical methods. Specifically, an exact path integral…

Chemical Physics · Physics 2007-05-23 Vinod Krishna

We address the decay in open chaotic quantum systems and calculate semiclassical corrections to the classical exponential decay. We confirm random matrix predictions and, going beyond, calculate Ehrenfest time effects. To support our…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Daniel Waltner , Martha Gutierrez , Arseni Goussev , Klaus Richter

Trajectory-based mixed quantum-classical approaches to coupled electron-nuclear dynamics suffer from well-studied problems such as the lack of (or incorrect account for) decoherence in the trajectory surface hopping method and the inability…

Quantum Physics · Physics 2016-02-29 Federica Agostini , Seung Kyu Min , Ali Abedi , E. K. U. Gross

We consider a coupled system of Schr\"odinger equations, arising in quantum mechanics via the so-called time-dependent self-consistent field method. Using Wigner transformation techniques we study the corresponding classical limit dynamics…

Analysis of PDEs · Mathematics 2014-06-17 Shi Jin , Christof Sparber , Zhennan Zhou

We study the semiclassical Ehrenfest trajectories in open quantum systems. We first derive in explicit form the Fokker-Planck equation that governs the time evolution of the mixing measure for a Gaussian mixture. Then, we embed the…

Quantum Physics · Physics 2026-05-01 Xiao-Kan Guo

We describe vacuum fluctuations and photon-field correlations in interacting quantum mechanical light-matter systems, by generalizing the application of mixed quantum-classical dynamics techniques. We employ the multi-trajectory…

Quantum Physics · Physics 2019-06-26 Norah M. Hoffmann , Christian Schäfer , Angel Rubio , Aaron Kelly , Heiko Appel

Descriptions of classical mechanics in Hilbert space go back to the work of Koopman and von Neumann in the 1930s. Decades later, van Hove derived a unitary representation of the group of contact transformations which recently has been used…

Quantum Physics · Physics 2025-04-02 Marcel Reginatto , Andrés Darío Bermúdez Manjarres , Sebastian Ulbricht

Experiments indicate that collective coupling of molecular ensembles to confined optical modes can modify excited-state dynamics and photochemical reactivity. To describe such cavity-induced effects at atomic resolution, semi-classical…

Chemical Physics · Physics 2026-03-06 Arun Kumar Kanakati , Oriol Vendrell , Gerrit Groenhof

Consistent dynamics which couples classical and quantum degrees of freedom exists, provided it is stochastic. This dynamics is linear in the hybrid state, completely positive and trace preserving. One application of this is to study the…

Quantum Physics · Physics 2023-01-04 Jonathan Oppenheim , Carlo Sparaciari , Barbara Šoda , Zachary Weller-Davies

Based on the assumption that time evolves only in one direction and mechanical systems can be described by Lagrangeans, a dynamical C*-algebra is presented for non-relativistic particles at atomic scales. Without presupposing any…

Quantum Physics · Physics 2019-05-08 Detlev Buchholz , Klaus Fredenhagen

Adequate simulation of non-adiabatic dynamics through conical intersection requires account for a non-trivial geometric phase (GP) emerging in electronic and nuclear wave-functions in the adiabatic representation. Popular mixed…

Chemical Physics · Physics 2015-07-20 Rami Gherib , Ilya G. Ryabinkin , Artur F. Izmaylov

Classical simulation of quantum systems plays an important role in the study of many-body phenomena and in the benchmarking and verification of quantum technologies. Exact simulation is often limited to small systems because the dimension…

Quantum Physics · Physics 2024-06-04 Dominik S. Wild , Sabina Drăgoi , Corbin McElhanney , Jonathan Wurtz , Sheng-Tao Wang

The definition of a consistent evolution equation for statistical hybrid quantum-classical systems is still an open problem. In this paper we analyze the case of Ehrenfest dynamics on systems defined by a probability density and identify…

Quantum Physics · Physics 2023-08-30 J. L. Alonso , C. Bouthelier-Madre , J. Clemente-Gallardo , D. Martínez-Crespo , J. Pomar

We investigate the nonequilibrium dynamics induced by an interaction quench in the semiclassical Holstein model within the Ehrenfest nonadiabatic framework, which describes an isolated hybrid quantum-classical system with strictly conserved…

Strongly Correlated Electrons · Physics 2026-02-06 Ho Jang , Gia-Wei Chern

Mixed quantum-classical dynamics is a set of methods often used to understand systems too complex to treat fully quantum mechanically. Many techniques exist for full quantum mechanical evolution on quantum computers, but mixed…

Quantum Physics · Physics 2023-08-22 Daniel Bultrini , Oriol Vendrell

Using a group theoretical approach we derive an equation of motion for a mixed quantum-classical system. The quantum-classical bracket entering the equation preserves the Lie algebra structure of quantum and classical mechanics: The bracket…

Quantum Physics · Physics 2009-10-30 Oleg V. Prezhdo , Vladimir V. Kisil

We derive a formulation of mixed quantum-classical dynamics for describing electronic carriers interacting with phonons in reciprocal space. For dispersionless phonons, we start by expressing the real-space classical coordinates in terms of…

Chemical Physics · Physics 2021-06-30 Alex Krotz , Justin Provazza , Roel Tempelaar