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The elemental composition and electronic structure of materials analyzed by electron energy loss spectroscopy (EELS) are probed by the inner-shell ionization of atoms. This is a localized process that can be approximated by the scattering…

Atomic Physics · Physics 2026-02-06 Ioannis Iatrakis , Valerii Brudanin

We concentrate on several relatively new aspects of the study of fast electron scattering by atoms and atom-like objects, namely endohedral atoms and fullerenes. We show that the corresponding cross sections, being expressed via so-called…

Atomic Physics · Physics 2007-05-23 M. Ya. Amusia

Electron microscopy prevalently uses energy-dispersive x-ray spectroscopy (EDS) and electron energy loss spectroscopy (EELS) for elemental analysis. EDS and EELS energy resolutions are commonly between 30-100 eV or 0.01-1 eV, respectively.…

In the last decades, the blossoming of experimental breakthroughs in the domain of electron energy loss spectroscopy (EELS) has triggered a variety of theoretical developments. Those have to deal with completely different situations, from…

Mesoscale and Nanoscale Physics · Physics 2021-02-10 Hugo Lourenço-Martins , Axel Lubk , Mathieu Kociak

A quantum-mechanical model to calculate the electron energy-loss spectra (EELS) for the system of a closely located metallic nanoshell and a molecule has been developed. At the resonance between the molecular excitation and plasmon modes in…

Atomic Physics · Physics 2014-10-07 I. Yu. Goliney , Ye. V. Onykienko

Inelastic scattering of electrons incident on a solid surface is determined by the two properties: (i) electronic response of the target system and (ii) the detailed quantum-mechanical motion of the projectile electron inside and in the…

Materials Science · Physics 2016-01-06 V. U. Nazarov , V. M. Silkin , E. E. Krasovskii

{\it Ab initio} calculations of relativistic electron energy loss spectra (REELS) are carried out using a generalization of the real-space Green's function code FEFF8 which is applicable to general aperiodic materials. Our approach…

Materials Science · Physics 2007-09-04 K. Jorissen , J. J. Rehr

Fast electrons spectromicroscopies enable to measure quantitatively the optical response of excitations with unrivaled spatial resolution. However, due to their inherently scalar nature, electron waves cannot access to polarization-related…

Optics · Physics 2021-05-26 Hugo Lourenço-Martins , Davy Gérard , Mathieu Kociak

Swift electrons passing near or through metallic structures have proven to be an excellent tool for studying plasmons and other types of confined optical modes involving collective charge oscillations in the materials hybridized with…

In previous work a different and powerful, analytical, technique was used to get data, such as the absolute atom concentration (AAC), specimen thickness etc., from public domain boron nitride EELS spectrum collected under a collection…

Materials Science · Physics 2020-09-24 Noureddine Hadji

An analytic description of laser-assisted electron-atom scattering (LAES) in an elliptically polarized field is presented using time-dependent effective range (TDER) theory to treat both electron-laser and electron-atom interactions…

Atomic Physics · Physics 2015-06-12 A. V. Flegel , M. V. Frolov , N. L. Manakov , Anthony F. Starace , A. N. Zheltukhin

Recent reviews in ultrafast electron diffraction (UED) have claimed that relativistic electrons exhibit enhanced elastic scattering efficiency, frequently quantified as a \gamma^2 increase in the differential cross section. These claims,…

Accelerator Physics · Physics 2025-09-24 Grant Brassem , Christian Viernes , German Sciaini

Electron energy-loss spectroscopy (EELS) can measure similar information to X-ray, UV-Vis, and IR spectroscopies but with atomic resolution and increased scattering cross sections. Recent advances in electron monochromators have expanded…

Chemical Physics · Physics 2024-04-26 Ye-Jin Kim , Levi D. Palmer , Wonseok Lee , Nicholas J. Heller , Scott K. Cushing

Electron beam energies in Transmission Electron Microscopes (TEMs) reach the relativistic realm constituting Quantum Electrodynamics (QED) the appropriate framework for the study of electron matter interaction in TEMs. We focus on the…

Atomic Physics · Physics 2026-01-12 Ioannis Iatrakis , Valerii Brudanin

Low-loss electron energy loss spectroscopy (EELS) in the scanning transmission electron microscope (STEM) probes the valence electron density and relevant optoelectronic properties such as band gap energies and other band structure…

Materials Science · Physics 2018-11-20 Alberto Eljarrat , Christoph T. Koch

A consistent theory of electron energy-loss spectroscopy (EELS) includes two indispensable elements: (i) electronic response of the target system and (ii) quantum kinematics of probing electrons. While for the bulk materials and their…

Mesoscale and Nanoscale Physics · Physics 2017-12-12 Vladimir U. Nazarov , Vyacheslav M. Silkin , Eugene E. Krasovskii

The variation with energy of the total cross section for elastic electron scattering from atoms of several elements is caused primarily by shape resonances corresponding to the formation of temporary negative ions. It is shown that such…

Atomic Physics · Physics 2007-05-23 Peter Nicoletopoulos

On- and off-axis electron energy loss spectroscopy (EELS) is a powerful method for probing local electronic structure on single atom level. However, many materials undergo electron-beam induced transformation during the scanning…

Materials Science · Physics 2023-10-23 Kevin M. Roccapriore , Riccardo Torsi , Joshua Robinson , Sergei V. Kalinin , Maxim Ziatdinov

Recent advancements in abilities to create and manipulate the electron's transverse wave function within the transmission electron microscope (TEM) and scanning TEM (STEM) have enabled vectorially-resolved electron energy loss (EEL) and…

Mesoscale and Nanoscale Physics · Physics 2024-03-12 Austin G. Nixon , Matthieu Chalifour , Marc R. Bourgeois , Michael Sanchez , David J. Masiello

We propose to use the near-threshold electron scattering data for atoms to guide the reliable experimental determination of their electron affinities (EAs), extracted using the Wigner Threshold Law, from laser photodetachment threshold…

Atomic Physics · Physics 2014-03-05 Zineb Felfli , Alfred Z. Msezane
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