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Modulation of the charge carrier density in a Mott material by remote doping from a highly doped conventional band insulator is proposed to test theoretical predictions of band filling control of the Mott metal-insulator transition without…

Materials Science · Physics 2011-11-11 Junwoo Son , Bharat Jalan , Adam P. Kajdos , Leon Balents , S. James Allen , Susanne Stemmer

Materials with field-tunable polarization are of broad interest to condensed matter sciences and solid-state device technologies. Here, using hydrogen (H) donor doping, we modify the room temperature metallic phase of a perovskite nickelate…

We report modulation of a reversible phase transition in VO2 films by hydrogen doping. A metallic phase and a new insulating phase are successively observed at room temperature as the doping concentration increases. It is suggested that the…

Strongly Correlated Electrons · Physics 2017-09-27 Shi Chen , Zhaowu Wang , Lele Fan , Yuliang Chen , Hui Ren , Heng Ji , Douglas Natelson , Yingying Huang , Jun Jiang , Chongwen Zou

Neodymium nickelate, NdNiO3 attracts attraction due to the simultaneous occurrence of several phase transitions around the same temperature. The electronic properties of NdNiO3 are extremely complex as structural distortion, electron…

Materials Science · Physics 2022-09-07 Raktima Basu , Reshma Kumawat , Mrinmay Sahu , Abu Bakkar Miah , Partha Mitra , Goutam Dev Mukherjee

Tungsten oxide and its associated bronzes (compounds of tungsten oxide and an alkali metal) are well known for their interesting optical and electrical characteristics. We have modified the transport properties of thin WO$_3$ films by…

Superconductivity · Physics 2017-07-19 X. Leng , J. Pereiro , J. Strle , G. Dubuis , A. T. Bollinger , A. Gozar , J. Wu , N. Litombe , C. Panagopoulos , D. Pavuna , I. Božović

Oxide semimetals exhibiting both nontrivial topological characteristics stand as exemplary parent compounds and multiple degrees of freedom, offering great promise for the realization of novel electronic states. In this study, we present…

We have measured the electrical conductivity of Ge:Ga samples prepared by neutron-transmutation doping of isotopically enriched 70Ge single crystals in order to study the metal-insulator transition (MIT) ruling out an ambiguity due to…

Disordered Systems and Neural Networks · Physics 2007-05-23 Michio Watanabe

Insulator to metal (IMT) transition (T$_t$ $\sim$ 341 K) in the VO2 accompanies transition from an infrared (IR) transparent to IR opaque phase. Tailoring of the IMT and associated IR switching behavior can offer potential thermochromic…

Materials Science · Physics 2020-01-22 S. S. Majid , S. R. Sahu , A. Ahad , K. Dey , K. Gautam , F. Rahman , P. Behera , U. Deshpande , V. G. Sathe , D. K. Shukla

$RE$NiO$_3$ is a negative charge transfer energy system and exhibits a temperature-driven metal-insulator transition (MIT), which is also accompanied by a bond disproportionation (BD) transition. In order to explore how hole doping affects…

The search for semiconductors with high thermoelectric figure of merit has been greatly aided by theoretical modeling of electron and phonon transport, both in bulk materials and in nanocomposites. Recent experiments have studied…

Strongly Correlated Electrons · Physics 2015-06-25 Subroto Mukerjee , J. E. Moore

Emergence of inorganic metal halide perovskites as multifunctional optoelectronic materials are due to their exceptional tunability in optoelectronic properties. This study sought to enhance the physical and mechanical properties of…

Materials Science · Physics 2023-05-02 Nazmul Hasan , Alamgir Kabir

Metal-insulator transitions (MITs) in correlated oxides offer immense potential for next-generation Mottronic devices. However, their integration into practical applications is often hindered by the coupling of MITs with symmetry-lowering…

We studied an electron-induced metal-insulator transition in a two-terminal device based on oxide NdNiO3. In our device, the NdNiO3 is electrostatically doped by the voltage applied between the terminals, resulting in an asymmetric…

Mesoscale and Nanoscale Physics · Physics 2012-10-11 W. L. Lim , E. J. Moon , J. W. Freeland , D. J. Meyers , M. Kareev , J. Chakhalian , S. Urazhdin

The microscopic mechanism of the hydrogen-induced metal-insulator transition in SmNiO$_3$ is clarified by means of density-functional theory with the Hubbard U correction. While 100% of hydrogen doping per Ni atom has been supposed to be…

Strongly Correlated Electrons · Physics 2022-10-17 Kunihiko Yamauchi , Ikutaro Hamada

Understanding the thermal conductivity of chromium doped V2O3 is crucial for optimizing the design of selectors for memory and neuromorphic devices. We utilized the time-domain thermoreflectance technique to measure the thermal conductivity…

Strongly Correlated Electrons · Physics 2024-09-18 Johannes Mohr , Kiumars Aryana , Md. Rafiqul Islam , Dirk J. Wouters , Rainer Waser , Patrick E. Hopkins , Joyeeta Nag , Daniel Bedau

Mg2NiH4 is a promising hydrogen storage material with fast (de)hydrogenation kinetics. Its hydrogen desorption enthalpy, however, is too large for practical applications. In this paper we study the effects of transition metal doping by…

Materials Science · Physics 2007-09-11 M. J. van Setten , G. A. de Wijs , G. Brocks

The dissociation of hydrogen molecules on the \gamma-U(100) surface is systematically studied with the density functional theory method. Through potential energy surface calculations, we find that hydrogen molecules can dissociate without…

Materials Science · Physics 2011-10-27 Yu Yang , Ping Zhang , Peng Shi , Xiaolin Wang

High-speed electrical switching of Ge2Sb2Te5 (GST) remains a challenging task due to the large impedance mismatch between the low-conductivity amorphous state and the high-conductivity crystalline state. In this letter, we demonstrate an…

Controlling electronic population through chemical doping is one way to tip the balance between competing phases in materials with strong electronic correlations. Vanadium dioxide exhibits a first-order phase transition at around 338 K…

We investigate the possibility of achieving high-temperature superconductivity in hydrides under pressure by inducing metallization of otherwise insulating phases through doping, a path previously used to render standard semiconductors…

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