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We study structural properties of a ring polymeric melt confined in a film in comparison to a linear counterpart using molecular dynamics simulations. Local structure orderings of ring and linear polymers in the vicinity of the surface are…

Soft Condensed Matter · Physics 2015-10-21 Eunsang Lee , YounJoon Jung

The conformational properties of flexible and semiflexible polymers exposed to active noise are studied theoretically. The noise may originate from the interaction of the polymer with surround- ing active (Brownian) particles or from the…

Soft Condensed Matter · Physics 2024-06-03 Thomas Eisenstecken , Gerhard Gompper , Roland G. Winkler

The conformational and dynamical properties of active Brownian polymers embedded in a fluid depend on the nature of the driving mechanism, e.g., self-propulsion or external actuation of the monomers. Implementations of self-propelled and…

Soft Condensed Matter · Physics 2022-01-24 Judit Clopés Llahí , Aitor Martín-Gómez , Gerhard Gompper , Roland G. Winkler

Dynamical properties of a long polymer ring in a melt of unknotted and unconcatenated rings are calculated. We re-examine and generalize the well known model of a ring confined to a lattice of topological obstacles in the light of the…

Soft Condensed Matter · Physics 2015-06-22 Jan Smrek , Alexander Y. Grosberg

Various authors have invoked discretized fractional Brownian (fBm) motion as a model for chain polymers with long range interaction of monomers along the chain. We show that for these, in contrast to the Brownian case, linear forces are…

Mathematical Physics · Physics 2019-07-24 Wolfgang Bock , Jinky Bornales , Ludwig Streit

In our combined experimental, theoretical and numerical work, we study the out of equilibrium deformations in a shrinking ring of optically trapped, interacting colloidal particles. Steerable optical tweezers are used to confine dielectric…

Ring, or cyclic, polymers have unique properties compared to linear polymers, due to their topologically closed structure that has no beginning or end. Experimental measurements on molecular ring polymers are challenging due to their…

Soft Condensed Matter · Physics 2023-03-15 Ruben Verweij , Julio Melio , Indrani Chakraborty , Daniela J Kraft

To understand the dynamical and conformational properties of deformable active agents in porous media, we computationally investigate the dynamics of linear chains and rings made of active Brownian monomers. In porous media, flexible linear…

Soft Condensed Matter · Physics 2023-07-07 Ligesh Theeyancheri , Subhasish Chaki , Tapomoy Bhattacharjee , Rajarshi Chakrabarti

Active polymers are driven out of equilibrium by internal forces and exhibit conformational properties that differ fundamentally from those of passive chains. Here we study how spatially modulated tangential activity reshapes the…

Soft Condensed Matter · Physics 2025-12-17 Paolo Malgaretti , Emanuele Locatelli

Polymer networks formed by cross linking flexible polymer chains are ubiquitous in many natural and synthetic soft-matter systems. Current micromechanics models generally do not account for excluded volume interactions except, for instance,…

Soft Condensed Matter · Physics 2023-06-05 Pratik Khandagale , Timothy Breitzman , Carmel Majidi , Kaushik Dayal

We consider a two-dimensional, tangentially active, semi-flexible, self-avoiding polymer to find a dynamical re-entrant transition between motile open chains and spinning achiral spirals with increasing activity. Utilizing probability…

Soft Condensed Matter · Physics 2024-10-08 Chitrak Karan , Abhishek Chaudhuri , Debasish Chaudhuri

The dynamics of a polymer ring enclosing a constant {\sl algebraic} area is studied. The constraint of a constant area is found to couple the dynamics of the two Cartesian components of the position vector of the polymer ring through the…

Soft Condensed Matter · Physics 2009-11-10 Arti Dua , Thomas A. Vilgis

By using the blob theory and computer simulations, we investigate the properties of a linear polymer performing a stationary rotational motion around a long impenetrable rod. In particular, in the simulations the rotation is induced by a…

We present a Brownian dynamics theory with full hydrodynamics (Stokesian dynamics) for a Gaussian polymer chain embedded in a liquid membrane which is surrounded by bulk solvent and walls. The mobility tensors are derived in Fourier space…

Soft Condensed Matter · Physics 2011-04-04 Sanoop Ramachandran , Shigeyuki Komura , Kazuhiko Seki , Gerhard Gompper

We examine entanglements using monomer contacts between pairs of chains in a Brownian-dynamics simulation of a polymer melt. A map of contact positions with respect to the contacting monomer numbers (i,j) shows clustering in small regions…

Condensed Matter · Physics 2009-10-28 E. Ben-Naim , G. S. Grest , T. A. Witten , A. R. C. Baljon

The rheological properties of tangentially propelled flexible polymers under linear shear flow are studied by computer simulations and are compared with analytical calculations. We find a significant impact of the coupled nonequilibrium…

Soft Condensed Matter · Physics 2025-05-26 Arindam Panda , Roland G. Winkler , Sunil P. Singh

In this paper, we construct an effective model for the dynamics of an excluded-volume chain under confinement, by extending the formalism of Rouse modes. We make specific predictions about the behavior of the modes for a single polymer…

Soft Condensed Matter · Physics 2009-09-29 Joshua Kalb , Bulbul Chakraborty

The dynamics of flexible polymer molecules are often assumed to be governed by hydrodynamics of the solvent. However there is considerable evidence that internal dissipation of a polymer contributes as well. Here we investigate the dynamics…

Soft Condensed Matter · Physics 2013-05-29 J. M. Deutsch

The breakage of a polymer chain of segments, coupled by anharmonic bonds with applied constant external tensile force is studied by means of Molecular Dynamics simulation. We show that the mean life time of the chain becomes progressively…

Soft Condensed Matter · Physics 2015-05-27 J. Paturej , A. Milchev , V. G. Rostiashvili , T. A. Vilgis

A narrow Gaussian excluded volume potential, which tends to a delta-function repulsive potential in the limit of a width parameter d* going to zero, has been used to examine the universal consequences of excluded volume interactions on the…

Soft Condensed Matter · Physics 2020-07-03 K. Satheesh Kumar , J. Ravi Prakash