English
Related papers

Related papers: Compactification of Determinant Expansions via Tra…

200 papers

We benchmark ionisation and excitation energies of transition-metal atoms Sc-Zn with a transcorrelated Hamiltonian combined with pseudopotentials. The similarity transformed Hamiltonian provides compact TC wave functions in affordable…

Chemical Physics · Physics 2025-06-13 Kristoffer Simula , Maria-Andreea Filip , Ali Alavi

Accurate calculations of strongly correlated materials remain a formidable challenge in condensed matter physics, particularly due to the computational demand of conventional methods. This paper presents an efficient solver for dynamical…

Strongly Correlated Electrons · Physics 2025-12-04 Basile Herzog , Patrik Thunström , Olle Eriksson

Massive MIMO systems rely on accurate Channel State Information (CSI) feedback to enable high-gain beam-forming. However, the feedback overhead scales linearly with the number of antennas, presenting a major bottleneck. While recent deep…

Systems and Control · Electrical Eng. & Systems 2025-12-17 Maryam Ansarifard , Mostafa Rahmani , Mohit K. Sharma , Kishor C. Joshi , George Exarchakos , Alister Burr

Development of exponentially scaling methods has seen great progress in tackling larger systems than previously thought possible. One such technique, full configuration interaction quantum Monte Carlo, is a useful algorithm that allows…

Strongly Correlated Electrons · Physics 2016-08-23 Norm M. Tubman , Joonho Lee , Tyler Y. Takeshita , Martin Head-Gordon , K. Birgitta Whaley

The Perdew-Zunger self-interaction correction(PZ-SIC) improves the performance of density functional approximations(DFAs) for the properties that involve significant self-interaction error(SIE), as in stretched bond situations, but…

The near-exact iCIPT2 approach for strongly correlated systems of electrons, which stems from the combination of iterative configuration interaction (iCI, an exact solver of full CI) with configuration selection for static correlation and…

Chemical Physics · Physics 2022-04-13 Ning Zhang , Yunlong Xiao , Wenjian Liu

We investigate the performance of a class of compact and systematically improvable Jastrow-Slater wave functions for the efficient and accurate computation of structural properties, where the determinantal component is expanded with a…

Chemical Physics · Physics 2019-01-17 Monika Dash , Saverio Moroni , Anthony Scemama , Claudia Filippi

Massive multiple-input multiple-output (MIMO) is a promising approach for cellular communication due to its energy efficiency and high achievable data rate. These advantages, however, can be realized only when channel state information…

Information Theory · Computer Science 2015-04-01 Min Soo Sim , Jeonghun Park , Chan-Byoung Chae , Robert W. Heath

An accurate description of electron correlation is one of the most challenging problems in quantum chemistry. The exact electron correlation can be obtained by means of full configuration interaction (FCI). A simple strategy for…

Chemical Physics · Physics 2021-05-14 Jae Woo Park

The development of polynomial cost solvers for correlated quantum impurity models, with controllable errors, is a central challenge in quantum many-body physics, where these models find applications ranging from nano-science to the…

Strongly Correlated Electrons · Physics 2012-12-21 Dominika Zgid , Emanuel Gull , Garnet Chan

We study a variation of the Trotter-Suzuki decomposition, in which a Hamiltonian exponential is approximated by an ordered product of two-qubit operator exponentials such that the Trotter step size is enhanced for a small number of terms.…

Quantum Physics · Physics 2023-04-10 Finn Lasse Buessen , Dvira Segal , Ilia Khait

An efficient implementation for approximate inclusion of the three-body operator arising in transcorrelated methods via exclusion of explicit three-body components (xTC) is presented and tested against results in the "HEAT" benchmark set…

Density functional theory (DFT)-based simulations of materials have first-principles accuracy, but are very computationally expensive. For simulating various properties of multi-component alloys, the cluster expansion (CE) technique has…

Materials Science · Physics 2026-04-01 Jacob Jeffries , Bochuan Sun , Enrique Martinez

The short answer to the question in the title is 'no'. We identify classes of truncated configuration interaction (CI) wave functions for which the externally corrected coupled-cluster (ec-CC) approach using the three-body ($T_{3}$) and…

Chemical Physics · Physics 2021-08-24 Ilias Magoulas , Karthik Gururangan , Piotr Piecuch , J. Emiliano Deustua , Jun Shen

The exponential scaling of complete active space (CAS) and full configuration interaction (CI) calculations limits the ability of quantum chemists to simulate the electronic structures of strongly correlated systems. Herein, we present…

Chemical Physics · Physics 2024-08-01 Kenneth O. Berard , Hongji Gao , Alexander Teplukhin , Xiangmin Jiao , Benjamin G. Levine

To avoid the combinatorial computational cost of configuration interaction (CI), we have previously introduced the symmetric tensor decomposition CI (STD-CI) method, where we take advantage of the antisymmetric nature of the electronic wave…

Chemical Physics · Physics 2015-06-24 Wataru Uemura , Shusuke Kasamatsu , Osamu Sugino

Full configuration interaction (FCI) solvers are limited to small basis sets due to their expensive computational costs. An optimal orbital selection for FCI (OptOrbFCI) is proposed to boost the power of existing FCI solvers to pursue the…

Chemical Physics · Physics 2020-09-01 Yingzhou Li , Jianfeng Lu

The present work introduces a new form of explicitly correlated factor in the context of the transcorrelated methods. The new correlation factor is obtained from the r 12 $\approx$ 0 mathematical analysis of the transcorrelated Hamiltonian,…

Strongly Correlated Electrons · Physics 2021-03-17 Emmanuel Giner

Many-body simulations of quantum systems is an active field of research that involves many different methods targeting various computing platforms. Many methods commonly employed, particularly coupled cluster methods, have been adapted to…

Chemical Physics · Physics 2023-06-14 David B. Williams-Young , Norm M. Tubman , Carlos Mejuto-Zaera , Wibe A. de Jong

For noncovalent interactions (NCIs), the CCSD(T) coupled cluster method is widely regarded as the `gold standard'. With localized orbital approximations, benchmarks for ever larger NCI complexes are being published; yet tantalizing evidence…

Chemical Physics · Physics 2025-03-13 Vladimir Fishman , Michał Lesiuk , Jan M. L. Martin , A. Daniel Boese