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Charged colloidal particles propel themselves through asymmetric fluxes of chemically generated ions on their surface. We show that asymmetry in the surface charge distribution introduces a new mode of self-phoretic motion for chemically…

Soft Condensed Matter · Physics 2023-05-03 Ahis Shrestha , Monica Olvera de la Cruz

In charged nanopores, ionic diffusion current reflects the ionic selectivity and ionic permeability of nanopores which determines the performance of osmotic energy conversion, i.e. the output power and efficiency. Here, theoretical…

Chemical Physics · Physics 2023-09-15 Long Ma , Zihao Gao , Jia Man , Jianyong Li , Guanghua Du , Yinghua Qiu

The dynamics of ideally polarizable spherical particles in concentrated suspensions under the effects of nonlinear electrokinetic phenomena is analysed using large-scale numerical simulations. Particles are assumed to carry no net charge…

Soft Condensed Matter · Physics 2019-07-23 Siamak Mirfendereski , Jae Sung Park

We study the problem of homogenization for inertial particles moving in a time dependent random velocity field and subject to molecular diffusion. We show that, under appropriate assumptions on the velocity field, the large--scale,…

Mathematical Physics · Physics 2007-05-23 G. A. Pavliotis , A. M. Stuart , K. C. Zygalakis

We study theoretically the phoretic motion of a spheroidal particle, which generates solute gradients in the surrounding unbounded solvent via chemical reactions active on its surface in a cap-like region centered at one of the poles of the…

Statistical Mechanics · Physics 2010-07-27 M. N. Popescu , S. Dietrich , M. Tasinkevych , J. Ralston

We present the results of direct simulation of the expansionof a two-component ultracold plasmafor various numbers of particles, densities, and electron temperatures. A description of the expansionprocess common to all plasma parameters is…

Plasma Physics · Physics 2021-07-28 E. V. Vikhrov , S. Ya. Bronin , B. B. Zelener , B. V. Zelener

A variational theory is developed to study electrolyte solutions, composed of interacting point-like ions in a solvent, in the presence of dielectric discontinuities and charges at the boundaries. Three important and non-linear…

Soft Condensed Matter · Physics 2013-05-29 Sahin Buyukdagli , Manoel Manghi , John Palmeri

Catalytic bimetallic Janus particles swim by a bipolar electrochemical propulsion mechanism that results from electroosmotic fluid slip around the particle surface. The flow is driven by electrical body forces which are generated from a…

Fluid Dynamics · Physics 2015-06-17 Jeffrey L. Moran , Jonathan D. Posner

Diffusiophoresis (DP) refers to the migration of particles driven by a solute concentration gradient in a liquid. Observations in the case of molecular neutral solutes are rather scarce, due to the low drift velocities in dilute solutions,…

We study a simple model for a particle that is active due to self-phoresis and that has been proposed to model symmetric camphor grains. The particle generates a concentration field through the continuous emission of a chemical substance,…

Statistical Mechanics · Physics 2026-02-18 Leah Anderson , David S. Dean

Most available theoretical predictions for the self-diffusiophoretic motion of colloidal particles are based on the hydrodynamic thin boundary layer approximation in combination with a solvent body force due to a self-generated local solute…

Soft Condensed Matter · Physics 2019-06-19 Thomas Speck

Catalytically active particles suspended in a liquid can move due to self-phoresis by generating solute gradients via chemical reactions of the solvent occurring at parts of their surface. Such particles can be used as carriers at the…

Soft Condensed Matter · Physics 2011-07-22 M. N. Popescu , M. Tasinkevych , S. Dietrich

We report an experimental study on the manipulation of colloidal particles in a drop sitting on a hydrogel. The manipulation is achieved by diffusiophoresis, which describes a directed motion of particles induced by solute gradients. By…

Soft Condensed Matter · Physics 2017-10-17 François Boulogne , Sangwoo Shin , Julien Dervaux , Laurent Limat , Howard A. Stone

We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

Statistical Mechanics · Physics 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov

We study the problem of homogenization for inertial particles moving in a periodic velocity field, and subject to molecular diffusion. We show that, under appropriate assumptions on the velocity field, the large scale, long time behavior of…

Statistical Mechanics · Physics 2009-11-11 G. A. Pavliotis , A. M. Stuart

The transport and dispersion of multiple species of charged ions are central to many biological and physical processes, including electrokinetic ion separation. However, most theoretical studies of dispersion in channels have focused on…

Soft Condensed Matter · Physics 2026-05-04 Thakurdas Mahata , Anirban Chatterjee , Ameeya Kumar Nayak

Particles moving along curved trajectories will diffuse if the curvature fluctuates sufficiently in either magnitude or orientation. We consider particles moving at a constant speed with either a fixed or with a Gaussian distributed…

Soft Condensed Matter · Physics 2009-11-10 Andrew D. Rutenberg , Andrew J. Richardson , Claire J. Montgomery

Turbophoresis in inhomogeneous turbulent flows leads to the formation of large-scale nonuniform particle number density distributions of inertial particles. This effect is associated with an effective drift velocity directed toward regions…

Fluid Dynamics · Physics 2026-05-15 E. Elmakies , O. Shildkrot , N. Kleeorin , A. Levy , I. Rogachevskii

Electrophoresis is the motion of particles relative to a surrounding fluid driven by a uniform electric field. In conventional electrophoresis, the electrophoretic velocity grows linearly with the applied field. Nonlinear effects with a…

Soft Condensed Matter · Physics 2024-03-19 Mojtaba Rajabi , Taras Turiv , Bing-Xiang Li , Hend Baza , Dmitry Golovaty , Oleg D. Lavrentovich

The problem of eliminating fast-relaxing variables to obtain an effective drift-diffusion process in position is solved in a uniform and straightforward way for models with velocity a function jointly of position and fast variables. A more…

Statistical Mechanics · Physics 2019-11-13 Paul E. Lammert