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We study theoretically the fluoro-nickelate series $A$NiF$_2$ ($A=$ Li, Na, K, Rb, Cs) in the tetragonal $P4/mmm$ infinite-layer structure. We use density functional theory to determine the structural parameters and the electronic band…

Superconductivity · Physics 2020-08-03 F. Bernardini , V. Olevano , X. Blase , A. Cano

Motivated by recent photoemission measurements on the La$_{0.8}$Sr$_{0.2}$NiO$_2$, we carry out a systematic study of the infinite-layer nickelate using both dynamical mean-field theory and density matrix embedding theory. The renormalized…

Strongly Correlated Electrons · Physics 2024-11-07 Ziyan Chen , Yuxin Wang , Kun Jiang , Jiangping Hu

The recent observation of superconductivity in an infinite-layer and quintuple-layer nickelate within the same $R_{n+1}$Ni$_{n}$O$_{2n+2}$ series ($R$ = rare-earth, $n=2-\infty$, with $n$ indicating the number of NiO$_{2}$ layers along the…

Strongly Correlated Electrons · Physics 2022-10-05 Harrison LaBollita , Myung-Chul Jung , Antia S. Botana

To investigate the detailed magnetic properties of a recently discovered superconducting nickelate Nd6Ni5O12, we performed the first-principles electronic structure calculation based on density functional theory. The band dispersion,…

Superconductivity · Physics 2024-10-02 Terri Yoon , Myung Joon Han

Optimization of unconventional superconductivity involves a balance of interaction strengths. Precise determination of correlation strength across different material families is therefore important. Here, we present a combined X-ray…

The discovery of superconductivity in a $d^{9-{\delta}}$ nickelate has inspired disparate theoretical perspectives regarding the essential physics of this class of materials. A key issue is the magnitude of the magnetic superexchange, which…

The electronic and magnetic properties of epitaxial LaNiO3/LaAlO3 superlattices can be tuned by layer thickness and substrate-induced strain. Here, we report on direct measurements of the k-space-resolved electronic structure of buried…

Infinite-layer (IL) nickelates have rapidly emerged as a new class of superconductors. However, due to the technical challenges of their topotactic synthesis, they have so far been realized primarily as thin films or polycrystalline powder…

Nickel-based complex oxides have served as a playground for decades in the quest for a copper-oxide analog of the high-temperature superconductivity. They may provide clues towards understanding the mechanism and an alternative route for…

The 2019 discovery of high temperature superconductivity in layered nickelate films, Nd$_{1-x}$SrNiO$_2$, has galvanized a community that has been studying nickelates for more than 30 years both as cuprate analogs and in their own right. On…

Superconductivity · Physics 2021-12-24 J. F. Mitchell

Atomic structure and electronic band structure are fundamental properties for understanding the mechanism of superconductivity. Motivated by the discovery of pressure-induced high-temperature superconductivity at 80 K in the bilayer…

Rare-earth infinite-layer nickelates represent an emerging class of unconventional superconductors, with materials synthesis largely limited to early lanthanide compounds. Here, we report the synthesis and characterization of phase-pure…

The fundamental properties of infinite-layer rare-earth nickelates (RNiO2) are carefully revisited and compared with those of CaCuO2 and RNiO3 perovskites. Combining first-principles and finite-temperature second-principles calculations, we…

Materials Science · Physics 2022-01-04 Yajun Zhang , Jingtong Zhang , Xu He , Jie Wang , Philippe Ghosez

Motivated by the discovery of superconductivity in infinite-layer nickelates RNiO$_2$ (R= rare-earth), and the subsequent enhancement of their T$_c$ with pressure, we investigate the evolution of the electronic structure and magnetic…

Superconductivity · Physics 2025-03-28 Shekhar Sharma , Myung-Chul Jung , Harrison LaBollita , Antia S. Botana

We analyze the electronic structure of different surface terminations for infinite-layer nickelates. Surface NiO$_2$ layers are found to be buckled, in contrast to planar bulk layers. While the rare-earth terminated surface fermiology is…

Superconductivity · Physics 2020-09-01 Xianxin Wu , Kun Jiang , Domenico Di Sante , Werner Hanke , A. P. Schnyder , Jiangping Hu , Ronny Thomale

Infinite layer nickelates have garnered significant attention due to their potential for high-temperature superconductivity. Despite extensive research, the interplay between oxygen stoichiometry and electronic properties in infinite layer…

We study the magnetic and spectral properties of a single-band Hubbard model for the infinite-layer nickelate compound LaNiO$_2$. As spatial correlations turn out to be the key ingredient for understanding its physics, we use two…

Strongly Correlated Electrons · Physics 2022-02-22 Marcel Klett , Philipp Hansmann , Thomas Schäfer

The mechanism of unconventional superconductivity in correlated materials remains a great challenge in condensed matter physics. The recent discovery of superconductivity in infinite-layer nickelates, as analog to high-Tc cuprates, has…

We theoretically investigate a freestanding membrane of infinite-layer nickelate Nd$_{0.85}$Sr$_{0.15}$NiO$_2$ under pressure by constructing a seven-orbital effective model based on first-principles calculations. By performing the…

The discovery of superconductivity in hole-doped infinite layer nickelates, RNiO2 (R = Nd, Pr, La) has garnered sustained interest in the field. A definitive picture of low-energy many-body states has not yet emerged. We provide new…

Strongly Correlated Electrons · Physics 2023-03-28 Gheorghe Lucian Pascut , Lucian Cosovanu , Kristjan Haule , Khandker F. Quader