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Ionic mobility determines the rate performance of several applications, such as batteries, fuel cells, and electrochemical sensors and is exponentially dependent on the migration barrier ($E_m$), a difficult to measure/calculate quantity.…

Materials Science · Physics 2026-02-16 Reshma Devi , Keith T. Butler , Gopalakrishnan Sai Gautam

We demonstrate that for polycrystalline LiNi0.33Mn0.33Co0.33O2 c-axis textured thin film cathodes of rechargeable lithium-ion batteries, the kinetics of Li storage and release including maximum specific capacity is determined by Li…

Materials Science · Physics 2025-09-11 Erwin Hüger , Harald Schmidt

Sodium-ion batteries (SIBs) share similar electrochemistry with Li but offer several advantages, including high abundance in nature and low cost, as well as suitability for fast charging due to a Na-ion mobility higher than that of Li. The…

Materials Science · Physics 2026-05-27 Suchona Akter , Mohammad R. Momeni

The state of health for lithium battery is necessary to ensure the reliability and safety for battery energy storage system. Accurate prediction battery state of health plays an extremely important role in guaranteeing safety and minimizing…

Signal Processing · Electrical Eng. & Systems 2019-04-02 Xiaoyu Li , Zhenpo Wang

The rapid pace of replacing fossil fuel propelled transport by electric vehicles is critically dependent on high-performing, high energy density and efficient batteries. Optimal and safe use of existing battery cells and development of…

We develop a mathematical framework to analyze electrochemical impedance spectra in terms of a distribution of diffusion times (DDT) for a parallel array of random finite-length Warburg (diffusion) or Gerischer (reaction-diffusion) circuit…

Chemical Physics · Physics 2018-03-21 Juhyun Song , Martin Z. Bazant

This work presents a comprehensive study on the aging behavior of 18650-type lithium-ion batteries, focusing on the uneven intercalation of lithium ions during fast charging processes. It introduces a novel approach using color visual…

Materials Science · Physics 2025-04-17 Yihan Shi , Qingrui Pan , Jitao Li , Xiaoze Shi , Youchang Wang , Peng Xiao

Traditional equivalent circuit models (ECMs) have difficulties in estimating battery internal states due to the lack of relevant physics, such as the lithium diffusion in active particles. Here we configure a circuit network to describe the…

Materials Science · Physics 2023-04-04 Mingzhao Zhuo , Niall Kirkaldy , Tom Maull , Timothy Engstrom , Gregory Offer , Monica Marinescu

Accurately measuring the cycle lifetime of commercial lithium-ion batteries is crucial for performance and technology development. We introduce a novel hybrid approach combining a physics-based equation with a self-attention model to…

Machine Learning · Computer Science 2025-05-07 Constantin-Daniel Nicolae , Sara Sameer , Nathan Sun , Karena Yan

Li$_6$PS$_5$Cl is a promising candidate for the solid electrolyte in all-solid-state Li-ion batteries. In applications, this material is in a polycrystalline state with grain boundaries (GBs) that can affect ionic conductivity. While…

Materials Science · Physics 2024-12-02 Yongliang Ou , Yuji Ikeda , Lena Scholz , Sergiy Divinski , Felix Fritzen , Blazej Grabowski

Understanding the response of the surface of metallic solids to external electric field sources is crucial to characterize electrode-electrolyte interfaces. Continuum electrostatics offer a simple description of the induced charge density…

Chemical Physics · Physics 2021-12-14 Giovanni Pireddu , Laura Scalfi , Benjamin Rotenberg

Accurate prediction of thermal runaway in lithium-ion batteries is essential for ensuring the safety, efficiency, and reliability of modern energy storage systems. Conventional data-driven approaches, such as Long Short-Term Memory (LSTM)…

Machine Learning · Computer Science 2026-05-12 Salman Khan , Syed Sajid Ullah , Muhammad Zunair Zamir , Jie Li , Abdul Malik , Saeed Mian Qaisar

In this article, we derive and discuss a physics-based model for impedance spectroscopy of lithium batteries. Our model for electrochemical cells with planar electrodes takes into account the solid-electrolyte interphase (SEI) as porous…

Chemical Physics · Physics 2020-04-03 Fabian Single , Birger Horstmann , Arnulf Latz

Effective early-stage detection of internal short circuit in lithium-ion batteries is crucial to preventing thermal runaway. This report proposes an effective approach to address this challenging issue, in which the current change, state of…

Systems and Control · Electrical Eng. & Systems 2024-12-24 Chengzhong Zhang , Hongyu Zhao , Wenjie Zhang

The surface coating of cathodes using insulator films has proven to be a promising method for high-voltage cathode stabilization in Li-ion batteries. However, there is still substantial uncertainty about how these films function,…

With the rapid development of energy storage technology, high-performance solid-state electrolytes (SSEs) have become critical for next-generation lithium-ion batteries. These materials require high ionic conductivity, excellent…

Materials Science · Physics 2025-02-17 Hongwei Du , Jian Hui , Lanting Zhang , Hong Wang

The degradation process of lithium-ion batteries is intricately linked to their entire lifecycle as power sources and energy storage devices, encompassing aspects such as performance delivery and cycling utilization. Consequently, the…

Machine Learning · Computer Science 2023-08-16 Yue Xiang , Bo Jiang , Haifeng Dai

This work presents a comparative study of optimization techniques for parameter identification in equivalent electrical models of lithium-ion batteries. The 2RC model is applied to a set of twelve batteries using four publicly available…

Optimization and Control · Mathematics 2025-12-03 Johan Sebastian Suarez Sepúlveda , Edgar Hernando Sepúlveda-Oviedo , Bruno Jammes , Corinne Alonso

When State of Charge, State of Health, and parameters of the Lithium-ion battery are estimated simultaneously, the estimation accuracy is hard to be ensured due to uncertainties in the estimation process. To improve the estimation…

Systems and Control · Electrical Eng. & Systems 2024-12-20 Ziyou Song , Jun Hou , Xuefeng Li , Xiaogang Wu , Xiaosong Hu , Heath Hofmann , Jing Sun

Early degradation prediction of lithium-ion batteries is crucial for ensuring safety and preventing unexpected failure in manufacturing and diagnostic processes. Long-term capacity trajectory predictions can fail due to cumulative errors…

Signal Processing · Electrical Eng. & Systems 2023-04-03 Seongyoon Kim , Hangsoon Jung , Minho Lee , Yun Young Choi , Jung-Il Choi