Related papers: Quasi-equilibrium chemical evolution in starless c…
(Abridged) JWST observations have measured the ice composition toward two highly-extinguished field stars in the Chamaeleon I cloud. The observed extinction excess on the long-wavelength side of the H2O ice band at 3 micron has been…
Hot molecular cores (HMCs) are intermediate stages of high-mass star formation and are also known for their rich emission line spectra at (sub-)mm wavebands. The observed spectral feature of HMCs such as total number of emission lines and…
The general lack of molecular oxygen in molecular clouds is an outstanding problem in astrochemistry. Extensive searches with SWAS, Odin and Herschel have only produced two detections; upper limits to the O_2 abundance in the remaining…
We present a study of gas-phase H2O and CO2 toward a sample of 14 massive protostars with the Short Wavelength Spectrometer (SWS) on board the Infrared Space Observatory (ISO). Modeling of the H2O spectra using a homogeneous model with a…
We extend the non-equilibrium model for the chemical and thermal evolution of diffuse interstellar gas presented in Richings et al. (2014) to account for shielding from the UV radiation field. We attenuate the photochemical rates by dust…
Recent interferometer observations have found that the D2O/HDO abundance ratio is higher than that of HDO/H2O by about one order of magnitude in the vicinity of low-mass protostar NGC 1333-IRAS 2A, where water ice has sublimated. Previous…
Aims. We present a new sub-grid model, HYACINTH -- HYdrogen And Carbon chemistry in the INTerstellar medium in Hydro simulations -- for computing the non-equilibrium abundances of ${\rm H_2}$ and its carbon-based tracers, namely ${\rm CO}$,…
L1521E seems unique among starless cores. It stands out in a distribution of a ratio (R) that we define to asses core evolution, and which compares the emission of the easily-depleted C18O molecule with that of the hard to deplete,…
We introduce a sub-grid model for the non-equilibrium abundance of molecular hydrogen in cosmological simulations of galaxy formation. We improve upon previous work by accounting for the unresolved structure of molecular clouds in a…
Astrochemical observations have revealed a surprisingly high level of chemical complexity, including long carbon chains, in the earliest stages of Sun-like star formation. The origin of these species and whether they undergo further growth,…
Radiative processes play a pivotal role in shaping the thermal and chemical states of gas across diverse astrophysical environments, from the interstellar medium (ISM) to the intergalactic medium. We present a hybrid cooling model for…
We investigate the chemical evolution of a collapsing core that starts from a hydrostatic core and finally form a low-mass protostar. New multiphase gas-grain models that include bulk diffusion and photon penetration are simulated by the…
Radiative transfer models of multi-transition observations are used to determine molecular abundances as functions of position in pre- and protostellar cores. The data require a "drop" abundance profile with radius, with high abundances in…
We combine the latest observationally motivated constraints on stellar properties in dark matter haloes, along with data-driven predictions for the atomic (HI) and molecular (H$_2$) gas evolution in galaxies, to derive empirical…
Gas-phase processes were long thought to be the key formation mechanisms for complex organic molecules in star-forming regions. However, recent experimental and theoretical evidence has cast doubt on the efficiency of such processes.…
Nearby dwarf irregular galaxies are ideal laboratories for studying the interstellar medium (ISM) at low metallicity, which is expected to be common for galaxies at very high redshift being observed by the James Webb Space Telescope. We…
New HCN, HNC, and HCO+ measurements of 46 normal galaxies in transitions up to J=4-3 are included in a multitransition database covering HCN and HCO+ (130 galaxies) and HNC (94 galaxies). The near-linear luminosity relations are dominated…
Recent observations with the Submillimeter Wave Astronomy Satellite indicate abundances of gaseous H2O and O2 in dense molecular clouds which are significantly lower than found in standard homogeneous chemistry models. We present here…
Understanding the gas abundance distribution is essential when tracing star formation using molecular line observations. Changing density and temperature conditions cause gas to freeze-out onto dust grains, and this needs to be taken into…
Investigating the chemical homogeneity of stars born from the same molecular cloud at virtually the same time is very important for our understanding of the chemical enrichment of the interstellar medium and with it the chemical evolution…