Related papers: Quasi-equilibrium chemical evolution in starless c…
Chemical models are routinely used to predict the atmospheric composition of exoplanets and compare it with the composition retrieved from observations, but little is known about the reliability of the calculated composition. We carried out…
L1521E is a dense starless core in Taurus that was found to have relatively low molecular depletion by earlier studies, thus suggesting a recent formation. We aim to characterize the chemical structure of L1521E and compare it to the more…
We present the results of chemical modeling of complex organic molecules (COMs) under conditions typical for prestellar cores. We utilize an advanced gas-grain astrochemical model with updated gas-phase chemistry, with a multilayer approach…
We investigate the chemical and observational implications of repetitive transient dense core formation in molecular clouds. We allow a transient density fluctuation to form and disperse over a period of 1 Myr, tracing its chemical…
Linear C4H and cyclic c-C3H2, as small unsaturated hydrocarbons, are the key precursors to complex organic molecules and are critical components of the interstellar medium. We present on-the-fly mapping observations of C4H 9-8 lines, c-C3H2…
We present a detailed model for the thermal balance, chemistry, and radiative transfer within quiescent dense molecular cloud cores that contain a central protostar. Large variations in the gas temperature are expected to affect the…
We present an extension of the code ProDiMo that allows for a modeling of processes pertinent to active galactic nuclei and to an ambient chemistry that is time dependent. We present a proof-of-concept and focus on a few astrophysically…
[ABRIDGED]We study the carbon abundances with a twofold objective. On the one hand, we want to evaluate the behaviour of carbon in the context of Galactic chemical evolution. On the other hand, we focus on the possible dependence of carbon…
Complex organic molecules (COMs) are widely detected in protostellar and protoplanetary systems, where they are thought to have been inherited in large part from earlier evolutionary phases. The chemistry of COMs in these earlier phases,…
The molecular evolution that occurs in collapsing prestellar cores is investigated. To model the dynamics, we adopt the Larson-Penston (L-P) solution and analogues with slower rates of collapse. For the chemistry, we utilize the new…
The chemical complexity in low-metallicity hot cores has been confirmed by observations. We investigate the effect of varying physical parameters, such as temperature, density and the cosmic ray ionisation rate (CRIR), on the molecular…
The supernova explosion increases cosmic ray and x-ray fluxes in the surrounding interstellar medium. Cosmic ray particles and x-ray radiation penetrate nearby molecular clouds and affect the chemical and thermal evolution of the gas. Here…
(Abridged) We carried out a comprehensive far-ultraviolet (UV) survey of ^12CO and H_2 column densities along diffuse molecular Galactic sight lines in order to explore in detail the relationship between CO and H_2. We measured new CO…
During the evolution of diffuse clouds to molecular clouds, gas-phase molecules freeze out on surfaces of small dust particles to form ices. On dust surfaces, water is the main constituent of the icy mantle in which a complex chemistry is…
Molecular inventories in starless cores are powerful tools for probing the physical and chemical structures at the earliest stages of star formation. Wide-band spectral scans are invaluable for obtaining a comprehensive view of the chemical…
AIM: We have recently developed a microscopic Monte Carlo approach to study surface chemistry on interstellar grains and the morphology of ice mantles. The method is designed to eliminate the problems inherent in the rate-equation formalism…
Context: The chemical composition of a molecular cloud changes dramatically as it collapses to form a low-mass protostar and circumstellar disk. Two-dimensional (2D) chemodynamical models are required to properly study this process. Aims:…
We report the presence of a systematic excess in the molecular hydrogen fraction ($f_{\mathrm{H2}} = 2 \, n_{\mathrm{H2}}/n_{\mathrm{H}}$) in studies that use a reduced chemistry network to calculate $f_{\mathrm{H2}}$ of gas with a non-zero…
Estimating molecular abundances ratios from the direct measurement of the emission of the molecules towards a variety of interstellar environments is indeed very useful to advance in our understanding of the chemical evolution of the…
Aims: Interstellar molecules form early in the evolutionary sequence of interstellar material that eventually forms stars and planets. To understand this evolutionary sequence, it is important to characterize the chemical composition of its…