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We investigate the chemical evolution of a forming molecular cloud behind an interstellar shock wave. We conduct three-dimensional magnetohydrodynamics simulations of the converging flow of atomic gas, including a simple chemical network…

Astrophysics of Galaxies · Physics 2026-01-08 Yuto Komichi , Yuri Aikawa , Kazunari Iwasaki , Kenji Furuya

The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry…

We have compared molecular line emission to dust continuum emission and modeled molecular lines using Monte Carlo simulations in order to study the depletion of molecules and the ionization fraction in three preprotostellar cores, L1512,…

Astrophysics · Physics 2009-11-07 Jeong-Eun Lee , Neal J. Evans , Yancy L. Shirley , Ken'ichi Tatematsu

Astrochemical models can be greatly simplified, with obvious computational advantages, if the reaction networks for key species can be reduced to a bare minimum. In addition, if chemical equilibrium holds, then simple analytical solutions…

Astrophysics of Galaxies · Physics 2025-08-26 Jonathan Rawlings , Eric Keto , Paola Caselli

(Abridged) We present evidence that low-mass starless cores, the simplest units of star formation, are systematically differentiated in their chemical composition. Molecules including CO and CS almost vanish near the core centers, where the…

Astrophysics · Physics 2008-11-26 M. Tafalla , P. C. Myers , P. Caselli , C. M. Walmsley , C. Comito

In star-forming regions, molecular cloud history and dynamics set the trend in the chemical composition. Ice formation, in particular, is affected by the evolution of physical conditions, which can lead to different ice compositions within…

Astrophysics of Galaxies · Physics 2025-07-02 A. Taillard , V. Wakelam , P. Gratier , E. Dartois , M. Chabot , J. A. Noble , L. Chu

We develop a detailed chemical model for the starless cores of strongly magnetized molecular clouds, with the ambipolar diffusion-driven dynamic evolution of the clouds coupled to the chemistry through ion abundances. We concentrate on two…

Astrophysics · Physics 2009-11-07 Zhi-Yun Li , V. I. Shematovich , D. S. Wiebe , B. M. Shustov

Pre-stellar cores are the basic unit for the formation of stars and stellar systems. The anatomy of the physical and chemical structures of pre-stellar cores is critical for understanding the star formation process. L1544 is a prototypical…

Astrophysics of Galaxies · Physics 2022-09-21 Yuxin Lin , Silvia Spezzano , Olli Sipilä , Anton Vasyunin , Paola Caselli

Context: Chemical models of dense cloud cores often utilize the so-called pseudo-time-dependent approximation, in which the physical conditions are held fixed and uniform as the chemistry occurs. In this approximation, the initial…

Solar and Stellar Astrophysics · Physics 2015-05-18 G. E. Hassel , E. Herbst , E. A. Bergin

Prior to star formation, pre-stellar cores accumulate matter towards the centre. As a consequence, their central density increases while the temperature decreases. Understanding the evolution of the chemistry and physics in this early phase…

Astrophysics of Galaxies · Physics 2017-10-18 S. Spezzano , P. Caselli , L. Bizzocchi , B. M. Giuliano , V. Lattanzi

Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, surface, and mantle) model. We considered the center part of…

Astrophysics of Galaxies · Physics 2015-04-24 Juris Kalvans

Seven isolated, nearby low-mass starless molecular cloud cores have been observed as part of the Herschel key program Earliest Phases of Star formation (EPoS). By applying a ray-tracing technique to the obtained continuum emission and…

Aims: We aim to simulate radial profiles of molecular abundances and the gas temperature in cold and heavily shielded starless cores by combining chemical and radiative transfer models. Methods: A determination of the dust temperature in a…

Astrophysics of Galaxies · Physics 2015-06-05 O. Sipilä

Our understanding of the physical and chemical structure of pre-stellar cores, the simplest star-forming sites, has significantly improved since the last IAU Symposium on Astrochemistry (South Korea, 1999). Research done over these years…

Astrophysics · Physics 2015-06-24 M. Tafalla

Much of what we know about molecular clouds, and by extension star formation, comes from molecular line observations. Interpreting these correctly requires knowledge of the underlying molecular abundances. Simulations of molecular clouds…

Astrophysics of Galaxies · Physics 2023-08-02 F. D. Priestley , P. C. Clark , S. C. O. Glover , S. E. Ragan , O. Fehér , L. R. Prole , R. S. Klessen

We present results from the Spitzer Space Telescope and molecular line observations of 9 species toward the dark cloud L43. The Spitzer images and molecular line maps suggest it has a starless core and a Class I protostar evolving in the…

Astrophysics of Galaxies · Physics 2014-11-20 Jo-Hsin Chen , Neal J. Evans , Jeong-Eun Lee , Tyler L. Bourke

We present the results of astrochemical modeling of complex organic molecules (COMs) in the ice and gas of the prestellar core L1544 with the recently updated MONACO rate equations-based model. The model includes, in particular,…

Recent observations of the pre-stellar core L1544 and the younger starless core L1498 have revealed that complex organic molecules (COMs) are enhanced in the gas phase toward their outer and intermediate-density shells. Our goal is to…

The physical conditions in a collapsing cloud can be traced by observations of molecular lines. To correctly interpret these observations the abundance distributions of the observed species need to be derived. The chemistry in a collapsing…

Solar and Stellar Astrophysics · Physics 2009-11-13 R. J. van Weeren , C. Brinch , M. R. Hogerheijde

This paper presents the first substantial study of the chemistry of the envelopes around a sample of 18 low-mass pre- and protostellar objects for which physical properties have previously been derived from radiative transfer modeling of…

Astrophysics · Physics 2009-11-10 J. K. Jorgensen , F. L. Schoeier , E. F. van Dishoeck
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