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Related papers: Ca substituion instead of Sr in La$_{0.58}$Sr$_{0.…

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We evaluated for the first time the use of nanostructured layered perovskites of formulae LnBaCo2O6-d with Ln = Sm and Gd (SBCO and GBCO, respetively) as SOFC cathodes, finding promising electrochemical properties in the intermediate…

Materials Science · Physics 2017-04-26 Augusto E. Mejía Gómez , Diego G. Lamas , Ana Gabriela Leyva , Joaquín Sacanell

In the paper a mathematical model of the PEN structure (positive electrode - electrolyte - negative electrode) of the Solid Oxide Fuel Cell (SOFC) is analyzed. It is proved that classical formulation of the problem leads inevitably to…

Numerical Analysis · Mathematics 2021-04-21 Michal Wrobel , Grzegorz Brus

In recent years, the Na-ion SuperIonic CONductor (NASICON) based polyanionics are considered the pertinent cathode materials in sodium-ion batteries due to their 3D open framework, which can accommodate a wide range of Na content and can…

Chemical Physics · Physics 2024-05-10 Simranjot K. Sapra , Jeng-Kuei Chang , Rajendra S. Dhaka

Sr$_2$RuO$_4$ is an unconventional superconductor with a tetragonal structure, whereas Ca$_2$RuO$_4$ is a Mott insulator with orthorhombic symmetry. The substituted Ca$_{2-x}$Sr$_x$RuO$_4$ has yielded a rich phase diagram that is just…

Strongly Correlated Electrons · Physics 2012-08-27 R. Jin , J. R. Thompson , J. He , J. M. Farmer , N. Lowhorn , G. A. Lamberton, , T. M. Tritt , D. Mandrus

The identification of alternatives to the Lithium-ion battery architecture remains a crucial priority in the diversification of energy storage technologies. Accompanied by the low reduction potential of $\mathrm{Ca^{2+}/Ca}$, -2.87 V vs.…

Materials Science · Physics 2021-07-29 Wang Lu , Juefan Wang , Gopalakrishnan Sai Gautam , Pieremanuele Canepa

The development of silicon anodes to replace conventional graphite in efforts to increase energy densities of lithium-ion batteries has been largely impeded by poor interfacial stability against liquid electrolytes. Here, stable operation…

We present measurements of electrical resistivity, thermal conductivity and thermopower of polycrystalline Sr-doped LaCoO3 with composition La0.95Sr0.05CoO3. Our data show that the investigated compound exhibits a very respectable room…

Materials Science · Physics 2007-05-23 J. Androulakis , P. Migiakis , J. Giapintzakis

Direct carbon fuel cells (DCFCs) are highly efficient power generators fueled by abundant and cheap solid carbons. However, the limited formation of triple phase boundaries (TPBs) within fuel electrodes inhibits their performance even at…

Applied Physics · Physics 2018-02-19 Wei Wu , Yunya Zhang , Dong Ding , Ting He

Results of phase formation, resistivity (r), and thermo-electric power (S), are reported on Y1-xCaxBa2Cu2.7Co0.3O7 compounds with x = 0.1 and 0.2. Pristine compound i.e. without Co or Ca substitution crystallizes in orthorhombic structure…

An approach is presented to modify the WF of solution-processed sol-gel derived ZnOover an exceptionally wide range of more than 2.3 eV. This approach relies on the formation of dense and homogeneous self-assembled monolayers based on…

A full lithium-ion-sulfur cell with a remarkable cycle life was achieved by combining an environmentally sustainable biomass-derived sulfur-carbon cathode and a pre-lithiated silicon oxide anode. X-ray diffraction, Raman spectroscopy,…

Micro-solid oxide fuel cells based on thin films have strong potential for use in portable power devices. However, devices based on silicon substrates typically involve thin-film metallic electrodes which are unstable at high temperatures.…

Sodium-ion batteries (SIBs) have received significant attention as promising alternative for energy storage applications owing to the large availability and low cost of sodium. In this paper we study the electrochemical behavior of…

Chemical Physics · Physics 2020-12-02 Jayashree Pati , Mahesh Chandra , Rajendra S. Dhaka

Correlating the microstructure of an energy conversion device to its performance is often a complex exercise, notably in solid oxide fuel cell (SOFC) research. SOFCs combine multiple materials and interfaces that evolve in time due to high…

We present a structural and magnetic study on two batches of polycrystalline LiNi$_{0.8}$Mn$_{0.1}$Co$_{0.1}$O$_2$ (commonly known as Li NMC 811), a Ni-rich Li ion battery cathode material, using elemental analysis, X-ray and neutron…

Materials Science · Physics 2021-01-19 P. Mukherjee , J. A. M. Paddison , C. Xu , Z. Ruff , A. R. Wildes , D. A. Keen , R. I. Smith , C. P. Grey , S. E. Dutton

Li-CO$_2$ batteries are promising energy storage systems due to their high theoretical energy density and CO$_2$ fixation capability, relying on reversible Li$_2$CO$_3$/C formation during discharge/charge cycles. We present a multiscale…

ZrCo alloy is promising to substitute uranium for handling hydrogen isotope storage in thermonuclear reactor. The alloying substitution of Zr in ZrCo with Hf or Ti can enhance the ability of anti-disproportionation. In this work,…

Materials Science · Physics 2022-01-19 Gan Ren

We report the transport, thermodynamic, $\mu$SR and neutron study of the Ca$_{0.74(1)}$La$_{0.26(1)}$(Fe$_{1-x}$Co$_{x}$)As$_{2}$ single crystals, mapping out the temperature-doping level phase diagram. Upon Co substitution on the Fe site,…

La-substituted CaFeAsH,(Ca1-xLax)FeAsH, were synthesized by the solid state reaction at 1173 K under high pressure of 2.5 GPa. The r-T anomaly corresponding to tetragonal to orthorhombic structural transition was suppressed by…

Superconductivity · Physics 2014-02-19 Yoshinori Muraba , Satoru Matsuishi , Hideo Hosono

A key bottleneck to solar fuels is the absence of stable and strongly absorbing photoelectrode materials for the oxygen evolution reaction (OER). Modern approaches generally trade off between stable but weakly absorbing materials, such as…