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Metal halide perovskites have shown extraordinary performance in solar energy conversion technologies. They have been classified as "soft semiconductors" due to their flexible corner-sharing octahedral networks and polymorphous nature.…

Materials Science · Physics 2023-09-11 Xia Liang , Johan Klarbring , William Baldwin , Zhenzhu Li , Gábor Csányi , Aron Walsh

Recent observations indicated that the photoelectric conversion properties of perovskite materials are intimately related to the presence of superlattice structures and other unusual nanoscale features in them. The low dimensional or mixed…

Mesoscale and Nanoscale Physics · Physics 2021-05-11 Susmita Bhattacharya , Goutam Kumar Chandra , P. Predeep

Layered halide perovskites are solution-processed natural heterostructures where quantum and dielectric confinement effects down to the nanoscale strongly influence the optical properties, leading to stabilization of bound excitons.…

Materials Science · Physics 2022-12-09 Claudio Quarti , Giacomo Giorgi , Claudine Katan , Jacky Even , Maurizia Palummo

Interfacial engineering has fueled recent development of p-i-n perovskite solar cells (PSCs), with self-assembled monolayer-based hole-transport layers (SAM-HTLs) enabling almost lossless contacts for solution-processed PSCs, resulting in…

Anharmonicity and local disorder (polymorphism) are ubiquitous in perovskite physics, inducing various phenomena observed in scattering and spectroscopy experiments. Several of these phenomena still lack interpretation from first-principles…

Materials Science · Physics 2023-08-30 Marios Zacharias , George Volonakis , Feliciano Giustino , Jacky Even

Metal halide perovskites (MHPs) have had a profound impact on numerous emerging optoelectronic technologies, achieving performance metrics that rival or exceed incumbent materials. This impact is underpinned by the exceptional properties of…

This thesis demonstrates the photo-physics of hybrid metal halide perovskite semiconductor thin films and its application to solar cells.

Applied Physics · Physics 2023-11-07 Shivam Singh

Metal halide perovskites single-crystalline thin films (SCTFs) have recently emerged as promising materials for the next generation of optoelectronic devices due to their superior intrinsic properties. However, it is still challenging to…

Applied Physics · Physics 2020-11-03 Yu-Hao Deng

Two-dimensional (2D) halide perovskites (HPs) are promising materials for various optoelectronic applications, yet a comprehensive understanding of their dynamics is still elusive. Here, we offer insight into the dynamics of prototypical 2D…

Materials Science · Physics 2024-08-15 Erik Fransson , Julia Wiktor , Paul Erhart

Owing to its superior visible light absorption and high chemical stability, chalcogenide perovskite barium zirconium sulfide has attracted significant attention in the past few years as a potential alternative to hybrid halide perovskites…

Size- and shape- dependent unique properties of the metal halide perovskite nanocrystals make them promising building blocks for constructing various electronic and optoelectronic devices. These unique properties together with their easy…

Materials Science · Physics 2023-06-07 Athanasia Kostopoulou , Ioannis Konidakis , Emmanuel Stratakis

Metal-halide perovskites are promising lasing materials for realization of monolithically integrated laser sources, the key components of silicon photonic integrated circuits (PICs). Perovskites can be deposited from solution and require…

This study introduces a new chemical method for controlling the strain in methylammonium lead iodide (MAPbI3) perovskite crystals by varying the ratio of Pb(Ac)2 and PbCl2 in the precursor solution. To observe the effect on crystal strain,…

Over the last few years of the heyday of hybrid halide perovskites, so many metal cations additives have been tested to improve their optoelectronic properties that it is already difficult to find an element that has not yet been tried. In…

Metal-halide perovskites are a class of solution processed materials with remarkable optoelectronic properties such as high photoluminescence quantum yields and long carrier lifetimes, which makes them promising for a wide range of…

Discovering new materials that efficiently catalyze the oxygen reduction and evolution reactions is critical for facilitating the widespread adoption of solid oxide fuel cell and electrolyzer (SOFC/SOEC) technologies. Here, we develop…

Materials Science · Physics 2023-11-03 Ryan Jacobs , Jian Liu , Harry Abernathy , Dane Morgan

Halide perovskites are perceived to be the promising class of materials for optoelectronics, spinorbitronics and topological electronics due to presence of strong spin-orbit coupling and polarized field. Here, we develop a Hamiltonian using…

Materials Science · Physics 2022-02-02 Mayank Gupta , B. R. K. Nanda

Halide perovskites have been extensively studied as materials of interest for optoelectronic applications. There is a major emphasis on ways to tailor the stability, defect behavior, electronic band structure, and optical absorption in…

Materials Science · Physics 2023-09-29 Jiaqi Yang , Arun Mannodi-Kanakkithodi

Ion and metal diffusion in metal halide perovskites, charge-transporting layers, and electrodes are detrimental to the performance and stability of perovskite-based photovoltaic devices. As a result, there is an intense research interest in…

The high optoelectronic quality of halide perovskites lends them to be utilized in optoelectronic devices and recently in emerging quantum emission applications. Advancements in perovskite nanomaterials have led to the discovery of…

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