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The density functional determining the Coulomb energy of nuclei is calculated to the first order in $e^2$. It is shown that the Coulomb energy includes three terms: the Hartree energy; the Fock energy; and the correlation Coulomb energy…

Nuclear Theory · Physics 2009-11-07 V. R. Shaginyan

We report on a methodology for the treatment of the Coulomb energy and potential in Kohn-Sham density functional theory that is free from self-interaction effects. Specifically, we determine the Coulomb potential given as the functional…

Materials Science · Physics 2016-06-29 M. Däne , A. Gonis , D. M. Nicholson , G. M. Stocks

Separating the Coulomb potential into short-range and long-range components enables the use of different electron repulsion integral algorithms for each component. The short-range part can be efficiently computed using the analytical…

Chemical Physics · Physics 2023-09-27 Qiming Sun

The dynamic structure factor ${\tilde S}({\bf k},\omega)$ and the two-particle distribution function $g({\bf r},t)$ of ions in a Coulomb crystal are obtained in a closed analytic form using the harmonic lattice (HL) approximation which…

Plasma Physics · Physics 2009-10-31 D. A. Baiko , D. G. Yakovlev , H. E. De Witt , W. L. Slattery

We present a new method to solve the nuclear density functional theory (DFT) equations using a two-center harmonic oscillator for Skyrme-like functionals, incorporating pairing and Coulomb interactions. The goal is to efficiently determine…

Nuclear Theory · Physics 2025-07-08 Adrián Sánchez-Fernández , Jacek Dobaczewski , Xuwei Sun , Herlik Wibowo

Coulomb interactions that occur in electronic structure calculations are correlated by allowing basis function components of the interacting densities to polarize, thereby reducing the magnitude of the interaction. Exchange integrals of…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

Considering the relationship between two bases in representation space of the three-dimensional proper Lorentz group, we derive some formulas with integrals involving Coulomb wave functions, which can be considered as Fourier, Mellin,…

Classical Analysis and ODEs · Mathematics 2019-04-09 Ilya Shilin

Classical mechanics and Time Dependent Hartree-Fock (TDHF) calculations of heavy ions collisions are performed to study the rotation of a deformed nucleus in the Coulomb field of its partner. This reorientation is shown to be independent on…

Nuclear Theory · Physics 2009-11-10 Cedric Simenel , Philippe Chomaz , Gilles De France

Coulomb integrals, i.e., matrix elements of bare or screened Coulomb interaction between one-electron orbitals, are fundamental objects in many approaches developed to tackle the challenging problem of calculating the electronic structure…

Strongly Correlated Electrons · Physics 2023-06-21 Coraline Letouzé , Guillaume Radtke , Benjamin Lenz , Christian Brouder

The first discussion of basis sets consisting of exponentially decaying Coulomb Sturmian functions for modelling electronic structures is presented. The proposed basis set construction selects Coulomb Sturmian functions using separate upper…

Chemical Physics · Physics 2019-01-23 Michael F. Herbst , James Emil Avery , Andreas Dreuw

We investigate configuration-interaction (CI) calculations on a basis of molecular orbitals generated by preliminary density-functional theory (DFT) calculations. We use this CI/DFT framework to improve the modeling of core-excited states…

Chemical Physics · Physics 2025-09-11 Giorgio Visentin , Francois Mauger

In this paper, we consider the Dirac-Coulomb equation for many-particles, to describe the interaction between electrons in the system having many electrons. The four-component wave function will expanding into a finite basis-set, using…

Quantum Physics · Physics 2019-12-10 Bilal K. Jasim , Ayad A. Al-Ani , Saad N. Abood

A rapid and relatively simple scheme of calculation is elaborated and applied to cosmological recombination of helium. Employing the nonrelativistic Coulomb Green's function, a wavefunction of a colliding electron is represented in an…

Cosmology and Nongalactic Astrophysics · Physics 2022-09-13 Tamaz Kereselidze , Zaal Machavariani , Irakli Noselidze

Using Kohn-Sham density functional theory (KS-DFT), we have studied the interaction between various polyaromatic hydrocarbon molecules. The systems range from mono-cyclic benzene up to hexabenzocoronene (hbc). For several conventional…

Soft Condensed Matter · Physics 2008-07-09 O. Anatole von Lilienfeld , Denis Andrienko

The Coulomb exchange and correlation energy density functionals for electron systems are applied to nuclear systems. It is found that the exchange functionals in the generalized gradient approximation provide agreements with the exact-Fock…

Nuclear Theory · Physics 2019-12-09 Tomoya Naito , Ryosuke Akashi , Gianluca Colò , Haozhao Liang , Xavier Roca-Maza

Following a recent work [Gal, Phys. Rev. A 64, 062503 (2001)], a simple derivation of the density-functional correction of the Hartree-Fock equations, the Hartree-Fock-Kohn-Sham equations, is presented, completing an integrated view of…

Chemical Physics · Physics 2008-09-11 Tamas Gal

The Slater orbitals are the natural basis functions in quantum molecular calculations. Three-center repulsion Coulomb-exchange integrals over Slater orbitals are evaluated analytically with arbitrary orbital exponents, first for linear…

Mathematical Physics · Physics 2012-09-18 Telhat Özdogan , Maria Belen Ruiz

A robust density fitting method for calculating Coulomb matrix elements over Bloch functions based on calculation of two- and three-center matrix elements of the Ewald potential is described and implemented in a Gaussian orbital basis in…

Materials Science · Physics 2021-02-03 Charles H. Patterson

The method of screening and renormalization for including the Coulomb interaction in the framework of momentum-space integral equations is applied to the three- and four-body nuclear reactions. The Coulomb effect on the observables and the…

Nuclear Theory · Physics 2009-11-13 A. Deltuva

In this paper methods for calculations of multi-center integrals of squared Coulomb potentials and Slater-type orbitals (STO) are derived. These integrals are necessary for accurate lower bounds to energy levels of molecular systems. All…

Chemical Physics · Physics 2022-02-10 Sohei Ashida
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