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Observations are reported in isothermal torsional oscillation tests on melts of isotactic polypropylene (iPP) and low-density polyethylene (LDPE) in the intervals of temperature between 190 and 250C (iPP) and between 120 and 190C (LDPE).…

Materials Science · Physics 2007-05-23 A. D. Drozdov , S. Agarwal , R. K. Gupta

Liquid crystalline polymers are materials of considerable scientific interest and technological value to society [1-3]. An important subset of such materials exhibit rubber-like elasticity; these can combine the remarkable optical…

Four series of tensile loading-unloading tests are performed on isotactic polypropylene in the sub-yield domain of deformations at room temperature. In the first series, injection-molded specimens are used as produced, whereas in the other…

Materials Science · Physics 2007-05-23 A. D. Drozdov , J. deC. Christiansen

Polymer blends consisting of two or more polymers are important for a wide variety of industries and processes, but, the precise mechanism of their thermomechanical behaviour is incompletely understood. In order to understand clearly, it is…

Soft Condensed Matter · Physics 2021-01-12 Pashupati Pokharel , Feng Wei , Jianyi Shi , Yingmin Wang , Dequan Xiao

We show that non-entangled polymers display an elastic-like behaviour at a macroscopic scale (probed at some 0.100 mm thickness) up to at least hundred degrees above the glass transition temperature. This observation, found under…

Soft Condensed Matter · Physics 2016-09-12 H Mendil , P Baroni , Laurence Noirez

This study focuses on comparing the individual polymer chain dynamics in an entangled polymeric liquid under different shear and extension rates. Polymer chains under various shear rates and extension rates were simulated using a…

Chemical Physics · Physics 2021-01-15 Behrouz Behdani , Tong Mou , Cody Spratt , Slava Butcovich , Ryan Gettler , Joontaek Park

We generalize a recently investigated lattice model of semiflexible polymers formed under equilibrium polymerization in a solution and conduct a comprehensive investigation of its melting properties. The model is characterized by six…

Condensed Matter · Physics 2007-05-23 Sagar S. Rane , P. D. Gujrati

We report on the development of some process capabilities for a polymer-based, multi-layer microelectrofluidic platform, namely: the hot embossing process, metallization on polymer and polymer bonding. Hot embossing experiments were…

Other Computer Science · Computer Science 2007-11-29 S. -H. Ng , Z. -F. Wang , R. -T. Tjeung , N. De Rooij

The breakage of a polymer chain of segments, coupled by anharmonic bonds with applied constant external tensile force is studied by means of Molecular Dynamics simulation. We show that the mean life time of the chain becomes progressively…

Soft Condensed Matter · Physics 2015-05-27 J. Paturej , A. Milchev , V. G. Rostiashvili , T. A. Vilgis

The time-dependent response of polystyrene and poly(methyl methacrylate) is studied in isothermal long-term shear creep tests at small strains and various temperatures in the vicinity of the glass transition point. A micromechanical model…

Soft Condensed Matter · Physics 2007-05-23 Aleksey D. Drozdov , Joachim Kaschta

To study the cooling behavior and the glass transition of polymer melts in bulk and with free surfaces a coarse-grained weakly semi-flexible polymer model is developed. Based on a standard bead spring model with purely repulsive…

Soft Condensed Matter · Physics 2019-09-09 Hsiao-Ping Hsu , Kurt Kremer

The effective quasistatic conductivity of composite polymeric electrolytes is studied in terms of a hard-core--penetrable-layer model. Used to incorporate the interface phenomena (such as amorphization of the polymer matrix around filler…

Materials Science · Physics 2019-11-05 M. Ya. Sushko , A. K. Semenov

The lattice cluster theory (LCT) for strongly interacting, self-assembling telechelic polymers provides a theoretical tool that enables establishing the connections between important microscopic molecular details of self-assembling polymers…

Soft Condensed Matter · Physics 2016-05-31 Wen-Sheng Xu , Karl F. Freed

Polymeric materials are widely used in many applications and are especially useful when combined with other polymers to make polymer composites. The appealing features of these materials come from their having comparable levels of strength…

Applications · Statistics 2018-04-13 Caleb King , Zhibing Xu , I-Chen Lee , Yili Hong

In this review, latest updates in the poly (ethylene oxide) based electrolytes are summarized. The ultimate goal of researchers globally is towards the development of free standing solid polymeric separator for energy storage devices. This…

Applied Physics · Physics 2018-08-14 Anil Arya , A L Sharma

The mechanical resistance of a polyethylene strand subject to tension and the way its properties are affected by the presence of a knot is studied using first-principles molecular dynamics calculations. The distribution of strain energy for…

Materials Science · Physics 2009-10-31 A. Marco Saitta , Michael L. Klein

The structural aspects of polyacrylamide thin films annealed at degradation threshold temperature have been studied as a function of annealing time using in situ X-ray reflectivity technique in vacuum. We observe significant decrease of…

Soft Condensed Matter · Physics 2010-10-29 Mojammel H. Mondal , M. Mukherjee

Recently, some reports show that the ultra-low thermal conductivity of bulk polymers can be enhanced along one direction, which limits its applications. Here, we proposed paved crosswise laminate methods which can enhance the thermal…

Materials Science · Physics 2021-01-13 Xiaoxiang Yu , Chengcheng Deng , Xiaoming Huang , Nuo Yang

Bonding between polymeric interfaces is encountered widely in several industrial applications. Many of these bonding processes rely on time-consuming and temperature-dependent classical mechanism of polymer interdiffusion via reptation in a…

Soft Condensed Matter · Physics 2022-05-10 Nikhil Padhye , Ajay Vallabh

This article delves into the micro-macro modeling of polymeric fluids, considering various microscopic potential energies, including the classical Hookean potential, as well as newly proposed modified Morse and Elastic-plastic potentials.…

Soft Condensed Matter · Physics 2023-09-27 Xuelian Bao , Huaxiong Huang , Zilong Song , Shixin Xu