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Related papers: Projected Augmented Waves (PAW) motivated mixed ba…

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We calculate complete basis set (CBS) limit extrapolated ionization potentials (IP) and electron affinities (EA) with Slater Type Basis sets for the molecules in the GW100 database. To this end, we present two new Slater Type orbital (STO)…

Chemical Physics · Physics 2021-07-14 Arno Förster , Lucas Visscher

Motivated by the recently proposed parallel orbital-updating approach in real space method, we propose a parallel orbital-updating based plane-wave basis method for electronic structure calculations, for solving the corresponding eigenvalue…

Computational Physics · Physics 2017-09-13 Yan Pan , Xiaoying Dai , Stefano de Gironcoli , Xin-Gao Gong , Gian-Marco Rignanese , Aihui Zhou

The full-potential linearized augmented-plane wave (FP-LAPW) method is well known to enable most accurate calculations of the electronic structure and magnetic properties of crystals and surfaces. The implementation of atomic forces has…

Condensed Matter · Physics 2009-10-31 Max Petersen , Frank Wagner , Lars Hufnagel , Matthias Scheffler , Peter Blaha , Karlheinz Schwarz

Accurate large-scale Kohn-Sham density functional theory (DFT) calculations are essential for modeling complex material systems, including interfaces, defects, nanoclusters, and twisted two-dimensional heterostructures. Achieving chemical…

Computational Physics · Physics 2026-04-30 Kartick Ramakrishnan , Phani Motamarri

To solve the Kohn-Sham equation within the framework of density functional theory, we develop a scheme to construct numerical atomic orbital (NAO) basis sets by contracting truncated spherical waves (TSWs). The contraction minimizes the…

Chemical Physics · Physics 2026-04-10 Yike Huang , Zuxin Jin , Linfeng Zhang , Mohan Chen , Rui Chen , Ling Li

We examine the challenge of performing accurate electronic structure calculations at high pressures by comparing the results of all-electron full potential linearized augmented-plane-wave calculations with those of the projector augmented…

Computational Physics · Physics 2018-01-11 Kanchan Sarkar , Mehmet Topsakal , N. A. W. Holzwarth , Renata M. Wentzcovitch

We have developed the quasiparticle self-consistent GW (QSGW) method based on a recently developed mixed basis all-electron full-potential method (the PMT method), which uses the augmented plane waves (APWs) and the highly localized…

Materials Science · Physics 2014-08-18 Takao Kotani

First principles calculations based on density functional theory are having an incerasing impact on our understanding of molecule-surface interactions. For example, calculations of the multi-dimensional potential energy surface have…

Materials Science · Physics 2007-05-23 O. Gulseren , D. M. Bird , S. E. Humphreys

A model of localized electron wave packets (WPs) with variable position and width (floating and breathing) that are spin-coupled as per the valence-bond theory is presented. It produces accurate potential energy curves of LiH in the ground…

Chemical Physics · Physics 2018-03-07 Koji Ando

The projected oscillator orbitals (pOOs) are localized virtual orbitals constructed by multiplying localized occupied orbitals by harmonics. Following a recent paper by Mussard and \'Angy\'an (Theor Chem Acc 134:1, 2015), further…

Chemical Physics · Physics 2018-11-09 Bastien Mussard

Extended Lagrangian Born-Oppenheimer molecular dynamics [Niklasson, Phys. Rev. Lett. 100 123004 (2008)] has been generalized to the propagation of the electronic wavefunctions. The technique allows highly efficient first principles…

Materials Science · Physics 2011-10-07 Peter Steneteg , Igor A. Abrikosov , Valery Weber , Anders M. N. Niklasson

Gaussian wave packets (GWPs) are well suited as basis functions to describe the time evolution of arbitrary wave functions in systems with nonsingular smooth potentials. They are less so in atomic systems on account of the singular behavior…

Atomic Physics · Physics 2015-05-13 Tomaž Fabčič , Jörg Main , Günter Wunner

In this paper, we extend the reduced-basis methods developed earlier for wave equations to goal-oriented wave equations with affine parameter dependence. The essential new ingredient is the dual (or adjoint) problem and the use of its…

Computational Physics · Physics 2013-05-16 Khac Chi Hoang , Pierre Kerfriden , Stephane P. A. Bordas

We present an implementation of the GW approximation for the electronic self-energy within the full-potential linearized augmented-plane-wave (FLAPW) method. The algorithm uses an all-electron mixed product basis for the representation of…

Materials Science · Physics 2010-11-15 Christoph Friedrich , Stefan Blügel , Arno Schindlmayr

Density functional theory with linear combination of atomic orbitals (LCAO) basis sets is useful for studying large atomic systems, especially when it comes to computationally highly demanding time-dependent dynamics. We have implemented…

Materials Science · Physics 2025-05-02 Vladimír Zobač , Mikael Kuisma , Ask Hjorth Larsen , Tuomas Rossi , Toma Susi

By carefully choosing parameters and including more semi-core orbitals as valence electrons, we have constructed a high quality projected augmented wave (PAW) dataset that yields results comparable to existing full-potential linearized…

Strongly Correlated Electrons · Physics 2010-12-30 Chao Cao , Yu-ning Wu , Rashid Hamdan , Yun-Peng Wang , Hai-Ping Cheng

The Pseudo-Boolean Optimization (PBO) and Maximum Satisfiability (MaxSAT) problems are natural optimization extensions of Boolean Satisfiability (SAT). In the recent past, different algorithms have been proposed for PBO and for MaxSAT,…

Artificial Intelligence · Computer Science 2009-03-06 Vasco Manquinho , Joao Marques-Silva , Jordi Planes

A new implementation of the GW approximation (GWA) based on the all-electron Projector-Augmented-Wave method (PAW) is presented, where the screened Coulomb interaction is computed within the Random Phase Approximation (RPA) instead of the…

Materials Science · Physics 2009-11-10 S. Lebègue , B. Arnaud , M. Alouani , P. E. Bloechl

Doubly resonant optical parametric oscillators (OPOs) under continuous wave (CW) pumping are particularly notable for their low threshold and narrow linewidth. Backward OPOs (BOPOs) realized through backward quasi-phase matching which…

A construction of node-less atomic orbitals and energy-dependent, node-reduced partial waves is presented, that contains the full information of the atomic eigenstates and that allows to represent the scattering properties in a transparent…

Chemical Physics · Physics 2012-10-23 Peter E. Blöchl , Clemens Först