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In an externally imposed electrolyte (salt) concentration gradient, charged colloids drift at speeds of order one micrometre per second. This phenomenon is known as diffusiophoresis. In systems with multiple salts and 'crossed' salt…

Soft Condensed Matter · Physics 2023-11-27 Ian Williams , Patrick B. Warren , Richard P. Sear , Joseph L. Keddie

Diffusiophoresis, a ubiquitous phenomenon that induces particle transport whenever solute concentration gradients are present, was recently observed in the context of microsystems and shown to strongly impact colloidal transport (patterning…

Diffusiophoresis is the spontaneous motion of particles under gradients of solutes. In electrolyte-driven diffusiophoresis, the zeta potential of the particles is an important surface property that characterizes diffusiophoretic mobility.…

Soft Condensed Matter · Physics 2022-09-30 Suin Shim , Janine K. Nunes , Guang Chen , Howard A. Stone

Diffusiophoresis of charged particles in the presence of electrolytes has been extensively studied in the literature. However, in these setups, particles typically move in a single direction, either up or down the electrolyte gradient.…

Soft Condensed Matter · Physics 2025-06-09 Ethan Coleman , Ankur Gupta

In the Nernst-Planck equations in two or more dimensions, a non-Faradaic electric current can arise as a consequence of connecting patches with different liquid junction potentials. Whereas this current vanishes for binary electrolytes or…

Soft Condensed Matter · Physics 2020-07-01 Patrick B Warren

Understanding how colloids move in crowded environments is key for gaining control over their transport in applications such as drug delivery, filtration, contaminant/microplastic remediation and agriculture. The classical models of colloid…

Soft Condensed Matter · Physics 2026-04-15 Mobin Alipour , Yiran Li , Haoyu Liu , Amir A. Pahlavan

Spatial gradients of diffusible signalling molecules play crucial roles in controlling diverse cellular behaviour such as cell differentiation, tissue patterning and chemotaxis. In this paper, we report the design and testing of a…

Quantitative Methods · Quantitative Biology 2016-12-15 Yasushi Saka , Murray MacPherson , Claudiu V. Giuraniuc

Electro- and diffusio- phoresis of particles correspond respectively to the transport of particles under electric field and solute concentration gradients. Such interfacial transport phenomena take their origin in a diffuse layer close to…

Soft Condensed Matter · Physics 2020-04-22 Sophie Marbach , Hiroaki Yoshida , Lydéric Bocquet

With an eye towards next-generation, smart, micro/nanofluidic devices, capable of responding to external stimuli or changes in environment, we demonstrate a means to achieve dynamic control of the spatio-temporal properties of the electric…

Fluid Dynamics · Physics 2017-08-08 Alicia M Boymelgreen , Tov Balli , Touvia Miloh , Gilad Yossifon

Turing patterns are fundamental in biophysics, emerging from short-range activation and long-range inhibition processes. However, their paradigm is based on diffusive transport processes, which yields Turing patters that are less sharp than…

Soft Condensed Matter · Physics 2023-11-13 Benjamin M. Alessio , Ankur Gupta

Predicting and controlling the transport of colloids in porous media is essential for applications ranging from contaminant remediation to drug delivery. In these complex environments, solute gradients are ubiquitous and could drive…

Soft Condensed Matter · Physics 2026-05-27 Aditya R. Pujari , Amir A. Pahlavan

We reveal an unreported physical mechanism that enables the pre-concentration, sorting and characterization of charged polystyrene nanobeads and liposomes dispersed in a continuous flow within a straight micron-sized channel. Initially, a…

In both biological and artificial systems, concentration gradients can serve as a convenient mechanism for manipulating particles and generating motility. Particles that interact with a solute will move along its gradient; if they…

Soft Condensed Matter · Physics 2011-07-21 Gareth P. Alexander , Andrea J. Liu

Field induced assembly of reconfigurable structures with complex hierarchical configurations has recently become an area of intense research with the promise for exciting applications in programmable self-assembly and nano/microstructure…

Soft Condensed Matter · Physics 2026-01-14 Indira Barros , Sayanth Ramachandran , Indrani Chakraborty

The electric field dielectric polarization-based separations mechanism represents a novel method for separating solutions at small length scales. An electric field gradient with a maximum strength of $\mathrm{0.4~MV/m}$ applied across a…

Chemical Physics · Physics 2023-11-29 Gaurav Anand , Samira Safaripour , Craig Snoeyink

Electrolytic diffusiophoresis refers to directional migration of colloids due to interfacial forces that develop in response to local electrolytic concentration ($c$) gradients. This physicochemical transport provides an efficient…

Soft Condensed Matter · Physics 2025-06-27 Kushagra Tiwari , Jitendra Dhakar , Kapil Upadhyaya , Akash Choudhary

We report an experimental study on the manipulation of colloidal particles in a drop sitting on a hydrogel. The manipulation is achieved by diffusiophoresis, which describes a directed motion of particles induced by solute gradients. By…

Soft Condensed Matter · Physics 2017-10-17 François Boulogne , Sangwoo Shin , Julien Dervaux , Laurent Limat , Howard A. Stone

We examine theoretically a new idea for spatial and temporal control of chemical reactions. When chemical reactions take place in a mixture of solvents, an external electric field can alter the local mixture composition thereby accelerating…

Soft Condensed Matter · Physics 2017-01-19 Shivaraj D. Deshmukh , Yoav Tsori

Most active colloid experiments are quasi-2D. Here a 3D density-matched solution of active particles propelled and aligned with an AC electric field uniquely facilitates measurement of short and long-range particle-wall interactions.…

Soft Condensed Matter · Physics 2025-05-02 Sandeep Ramteke , Jordan Dehmel , Touvia Miloh , Jarrod Schiffbauer , Alicia Boymelgreen

We present the diffusiophoresis of ellipsoidal particles induced by ionic solute gradients. Contrary to the common expectation that diffusiophoresis is shape independent, here we show experimentally that this assumption breaks down when the…

Soft Condensed Matter · Physics 2023-05-31 Viet Sang Doan , Dong-Ook Kim , Craig Snoeyink , Ying Sun , Sangwoo Shin
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