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Numerical modeling of proton exchange membrane fuel cells is at the verge of becoming predictive. A crucial requisite for this, though, is that material properties of the membrane-electrode assembly and their functional dependence on the…

Applied Physics · Physics 2019-10-03 Roman Vetter , Jürgen O. Schumacher

Effective water management is essential for the optimal performance of PEM fuel cells. We have developed an impedance model for liquid water transport through the membrane and coupled it with the two-phase model for cathode side impedance.…

Chemical Physics · Physics 2026-01-16 Andrei Kulikovsky , Tatyana Reshetenko

In this paper, a predictive constraint-aware control scheme is formulated within the Command Governor (CG) framework for localized hydration management of a proton exchange membrane (PEM) fuel cell system. First, a comprehensive nonlinear…

Systems and Control · Electrical Eng. & Systems 2025-10-20 Mostafaali Ayubirad , Zeng Qiu , Hao Wang , Chris Weinkauf , Michiel Van Nieuwstadt , Hamid R. Ossareh

We present a macrohomogeneous two-phase model of a proton exchange membrane fuel cell (PEMFC). The model takes into account the mechanical compression of the gas diffusion layer (GDL), the two-phase flow of water, the transport of the gas…

A PEM fuel cell was specially constructed to determine kinetics under conditions of well-defined gas phase composition and cell temperature. Steady state multiplicity was discovered in the autohumidification PEM fuel cell, resulting from a…

Chemical Physics · Physics 2016-09-08 J. B. Benziger , J. Moxley , S. Tulyani , A. Turner , A. B. Bocarsly , Y. G. Kevrekidis

In this paper, a nonlinear six order model is proposed for a proton exchange membrane fuel cell (PEMFC) as a control-oriented electrochemical model. Its validation is performed on a specific single cell PEMFC with effective dimension of 5…

Systems and Control · Electrical Eng. & Systems 2025-01-16 Seyed Mehdi Rakhtala , Roja Eini

Technologies based on the use of hydrogen are promising for future energy requirements in a more sustainable world. Consequently, modelling fuel cells is crucial, for instance, to optimize their control to achieve excellent performance, to…

Systems and Control · Electrical Eng. & Systems 2024-10-18 Raphaël Gass , Zhongliang Li , Rachid Outbib , Samir Jemei , Daniel Hissel

An isothermal porous-electrode model of a discharging lead-acid battery is presented, which includes an extension of concentrated-solution theory that accounts for excluded-volume effects, local pressure variation, and a detailed…

Chemical Physics · Physics 2020-06-05 Valentin Sulzer , S. Jon Chapman , Colin P. Please , David A. Howey , Charles W. Monroe

We have investigated thermodynamic and dynamic properties as well as the dielectric constant of water-metha\-nol model mixtures in the entire range of composition by using constant pressure molecular dynamics simulations at ambient…

Soft Condensed Matter · Physics 2015-12-25 E. Galicia-Andrés , H. Dominguez , L. Pusztai , O. Pizio

The urgency of the energy transition requires improving the performance and longevity of hydrogen technologies. AlphaPEM is a dynamic one-dimensional (1D) physics-based PEM fuel cell system simulator, programmed in Python and experimentally…

Systems and Control · Electrical Eng. & Systems 2026-01-28 Raphaël Gass , Zhongliang Li , Rachid Outbib , Samir Jemeï , Daniel Hissel

We present a techno-economic optimization model for evaluating the design and operation of proton exchange membrane (PEM) electrolyzers, crucial for hydrogen production powered by variable renewable electricity. This model integrates a 0-D…

Systems and Control · Electrical Eng. & Systems 2024-05-14 Landon Schofield , Benjamin Paren , Ruaridh Macdonald , Yang Shao-Horn , Dharik Mallapragada

A PEM micro fuel cell system is described which is based on self-breathing PEM micro fuel cells in the power range between 1 mW and 1W. Hydrogen is supplied with on-demand hydrogen production with help of a galvanic cell, that produces…

Other Computer Science · Computer Science 2008-12-18 Robert Hahn , Stefan Wagner , Steffen Krumbholz , Herbert Reichl

Water management is a key factor that limits PEFC's performance. We show how insights into this problem can be gained from pore-scale simulations of water invasion in a model fibrous medium. We explore the influence of contact angle on the…

Soft Condensed Matter · Physics 2009-09-17 Hamza Chraibi , L. Ceballos , M. Prat , Michel Quintard , Alexandre Vabre

Scalable hydrogen production using proton exchange membrane water electrolyzers depends on overcoming efficiency losses arising from coupled multiphase, multicomponent transport and interfacial phenomena across the membrane electrode…

Liquid water within the cathode Gas Diffusion Layer (GDL) and Gas Channel (GC) of Proton Exchange Membrane Fuel Cells (PEMFCs) is strongly coupled to gas transport properties, thereby affecting the electrochemical conversion rates. In this…

Fluid Dynamics · Physics 2023-02-16 Danan Yang , Himani Garg , Martin Andersson

In this work a 1D finite volume based model using coupled meshes is introduced to capture potential and species distribution throughout the discharge process in a lithium bismuth liquid metal battery while neglecting hydrodynamic effects,…

Chemical Physics · Physics 2023-05-30 Carolina Duczek , Norbert Weber , Omar E. Godinez-Brizuela , Tom Weier

Fluid, heat and species transport and oxygen reduction in the cathode of a PEM fuel cell are simulated using multi relaxation lattice Boltzmann method. Heat generation due to oxygen reduction and its effects on transport and reaction are…

Fluid Dynamics · Physics 2021-03-03 M. Jithin , Saurabh Siddharth , Malay K. Das , Ashoke De

The efficiency of a proton exchange membrane (PEM) fuel cell depends on the mobility of protons in the PEM, which is determined by the hydration and temperature of the membrane. While optical techniques or neutron or x-ray scattering…

Materials Science · Physics 2023-01-10 Darshan Chalise , Shreyan Majumdar , David G. Cahill

A new empirical potential for efficient, large scale molecular dynamics simulation of water is presented. The HIPPO (Hydrogen-like Intermolecular Polarizable POtential) force field is based upon the model electron density of a hydrogen-like…

Chemical Physics · Physics 2021-09-30 Joshua A. Rackers , Roseane R. Silva , Zhi Wang , Jay W. Ponder

Ever since modeling has become a mature part of proton exchange membrane fuel cell (PEMFC) research and development, it has been plagued by significant uncertainty lying in the detailed knowledge of material properties required.…

Applied Physics · Physics 2019-09-11 Roman Vetter , Jürgen O. Schumacher
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