Related papers: Solvable toy model of negative energetic elasticit…
The negative internal energetic contribution to the elastic modulus (negative energetic elasticity) has been recently observed in polymer gels. This finding challenges the conventional notion that the elastic moduli of rubberlike materials…
In a recent Letter, Shirai and Sakumichi [Phys. Rev. Lett. 130, 148101 (2023), arXiv:2202.12483] presented a study focusing on the origin of a temperature-dependent negative contribution $G_U(T)$ to the elastic modulus $G(T)$ of hydrogels…
Negative energetic elasticity in gels challenges the conventional understanding of gel elasticity; despite extensive research, a concise explanation remains elusive. In this study, we use the weakly self-avoiding walk (the Domb-Joyce model;…
Rubber elasticity is the archetype of the entropic force emerging from the second law of thermodynamics; numerous experimental and theoretical studies on natural and synthetic rubbers have shown that the elasticity originates mostly from…
We consider a coarse-grained polymer model in order to investigate the origin of a recently discovered negative energy-related contribution to the elastic modulus $G(T)$ of rubber-like gels. From this model, we are able to compute an exact…
We recently found that the energy contribution to the linear elasticity of polymer gels in the as-prepared state can be a significant negative value; the shear modulus is not proportional to the absolute temperature [Y. Yoshikawa et al.,…
We study a single lattice polymer chain under a fixed end-to-end distance, incorporating both Domb--Joyce (DJ) soft-core self-repulsion between polymer segments and a local bending-energy cost. By decomposing the stiffness into energetic…
The elastic response is studied of a single flexible chain grafted on a rigid plane and an ensemble of non-interacting tethered chains. It is demonstrated that the entropic theory of rubber elasticity leads to conclusions that disagree with…
We consider a thin elastic sheet in the shape of a disk whose reference metric is that of a singular cone. I.e., the reference metric is flat away from the center and has a defect there. We define a geometrically fully nonlinear free…
The Ising one-dimensional (1D) chain with spin $S=1/2$ and magnetoelastic interactions is studied with the lattice contribution included in the form of elastic interaction and thermal vibrations simultaneously taken into account. The…
We use the lattice model of directed walks to investigate the conformational as well as the adsorption properties of a semiflexible homopolymer chain immersed in a good solvent in two and three dimensions. To account for the stiffness in…
We introduce and implement a Monte Carlo scheme to study the equilibrium statistics of polymers in the globular phase. It is based on a model of "interacting elastic lattice polymers" and allows a sufficiently good sampling of long and…
A thermodynamically related model is developed for describing elastic rubber-like behavior of amorphous and crystallizing polymers and demonstrated on example of simple extension. Both the “entropic” and “energetic”…
The elasticity of rubbery polymer networks has been considered to be entropy-driven. On the other hand, studies on single polymer chain mechanics have revealed that the elasticity of ultimately stretched polymer chains is dominated by the…
We study energy relaxation in a phenomenological model for polymer built from rheological considerations: a one dimensional nonlinear lattice with dissipative couplings. These couplings are well known in polymer's community to be possibly…
We study correlation properties of the generalized elastic model which accounts for the dynamics of polymers, membranes, surfaces and fluctuating interfaces, among others. We develop a theoretical framework which leads to the emergence of…
The free energy of a two-dimensional system at criticality has in general an universal part proportional the logarithm of the system size. This term was shown by Cardy and Peschel to be related to the curvature of the system, with smooth…
We consider models for elastic liquids, such as solutions of flexible polymers. They introduce a relaxation time $\lambda$ into the system, over which stresses relax. We study the kinematics of the problem, and clarify the relationship…
We study the behavior of the elastic polymer, a model of a directed polymer in a continuous Gaussian random environment that is independent in time and correlated in space, as the dimension of the environment is taken to infinity. We give…
A polymer-chain network is a collection of interconnected polymer-chains, made themselves of the repetition of a single pattern called a monomer. Our first main result establishes that, for a class of models for polymer-chain networks, the…