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Density functional theory (DFT) became a universal approach to compute ground-state and excited configurations of many-electron systems held together by an external one-body potential in condensed-matter, atomic, and molecular physics. At…

Nuclear Theory · Physics 2011-09-30 J. Dobaczewski

The results of fabrication and characterization of atomic structure of nanocrystalline thin layers of Y2O3 in cubic and monoclinic phases is reported. Experimental data demonstrate crystalline ordering in nanocrystalline films with average…

Materials Science · Physics 2022-12-28 D. W. Boukhvalov , D. A. Zatsepin , Yu. A. Kuznetsova , N. V. Gavrilov , A. F. Zatsepin

Structural, mechanical, electronic, and thermodynamic properties of fluorite and tetragonal phases of ZrH$_{2}$ are systematically studied by employing the density functional theory within generalized gradient approximation. The existence…

Materials Science · Physics 2010-08-02 Peng Zhang , Bao-Tian Wang , Chao-Hui He , Ping Zhang

Density functional theory (DFT) is an incredible success story. The low computational cost, combined with useful (but not yet chemical) accuracy, has made DFT a standard technique in most branches of chemistry and materials science.…

Chemical Physics · Physics 2015-06-03 Kieron Burke

Static electric response properties of atoms and molecules are reported within the real-space Cartesian grid implementation of pseudopotential Kohn-Sham (KS) density functional theory (DFT). A detailed systematic investigation is made for a…

Chemical Physics · Physics 2019-04-26 Tanmay Mandal , Abhisek Ghosal , Amlan K. Roy

Extraordinary new materials named quasicrystals and characterized by noncrystallographic rotational symmetry and quasiperiodic translational properties have attracted scrutiny. Study of quasicrystals may shed light on the most basic notions…

Strongly Correlated Electrons · Physics 2013-06-27 V. R. Shaginyan , A. Z. Msezane , K. G. Popov , G. S. Japaridze , V. A. Khodel

Thermodynamics provides a transparent definition of the free energy of density functional theory (DFT), and of its derivatives - the potentials, at finite temperatures T. By taking the T to 0 limit, it is shown here that both DFT and…

Materials Science · Physics 2016-08-31 Nathan Argaman , Guy Makov

The Mg-Zn and Al-Zn binary alloys have been investigated theoretically under static isotropic pressure. The stable phases of these binaries on both initially hexagonal-close-packed (HCP) and face-centered-cubic (FCC) lattices have been…

Materials Science · Physics 2021-05-06 Mohammad Alidoust , David Kleiven , Jaakko Akola

A density functional theory (DFT) framework is presented that links functional derivatives of free-energy functionals to non-linear static density response functions in quantum many-body systems. Within this framework, explicit expressions…

The freezing transition of hard spheres has been well described by various versions of density-functional theory (DFT). These theories should possess the close-packed crystal as a special limit, which represents an extreme testing ground…

Soft Condensed Matter · Physics 2009-10-31 Benito Groh , Bela Mulder

Following our previous work this article reports a study on the stability of the 18-fold symmetry soft-matter quasicrystals, in which the extended free energy is a basis for the analysis that is similar to the study of the 12-fold symmetry…

Soft Condensed Matter · Physics 2019-09-23 Zhi-Yi Tang , Tian-You Fan

We compare predictions from two familiar models of the metastable supercooled liquid respectively constructed with thermodynamic and dynamic approach. In the so called density functional theory (DFT) the free energy $F[\rho]$ of the liquid…

Statistical Mechanics · Physics 2016-04-20 Leishangthem Premkumar , Neeta Bidhoodi , Shankar P. Das

This chapter starts with a summary of the atomistic processes that occur during epitaxy. We then introduce density functional theory (DFT) and describe its implementation into state-of-the-art computations of complex processes in condensed…

Condensed Matter · Physics 2009-09-25 P. Ruggerone , C. Ratsch , M. Scheffler

We examine the out-of-equilibrium dynamical evolution of density profiles of ultrasoft particles under time-varying external confining potentials in three spatial dimensions. The theoretical formalism employed is the dynamical density…

Soft Condensed Matter · Physics 2009-11-10 J. Dzubiella , C. N. Likos

We investigate crystalline thermodynamic stable lithium silicides phases (LixSiy) with density functional theory (DFT) and a force-field method based on modified embedded atoms (MEAM) and compare our results with experimental data. This…

Computational Physics · Physics 2016-10-31 Sebastian Schwalbe , Thomas Gruber , Kai Trepte , Franziska Biedermann , Florian Mertens , Jens Kortus

Quasicrystals can be considered, from the point of view of their electronic properties, as being intermediate between metals and insulators. For example, experiments show that quasicrystalline alloys such as AlCuFe or AlPdMn have…

Strongly Correlated Electrons · Physics 2009-11-11 A. Jagannathan , F. Piechon

A two-dimensional system of soft particles interacting via a two-length-scale potential is studied. Density functional theory and Brownian dynamics simulations reveal a fluid phase and two crystalline phases with different lattice spacing.…

Soft Condensed Matter · Physics 2013-10-30 A. J. Archer , A. M. Rucklidge , E. Knobloch

This paper reports formation enthalpies of phases in the Al-Mn-Pd ternary alloy system as calculated from first principles using electronic density functional theory. We consider all crystal structures as reported in the assessed phase…

Materials Science · Physics 2023-02-27 Marek Mihalkovic , Michael Widom

Although much is known about the metastable liquid branch of hard spheres--from low dimension $d$ up to ${d\to\infty}$--its crystal counterpart remains largely unexplored for $d>3$. In particular, it is unclear whether the crystal phase is…

Statistical Mechanics · Physics 2022-05-03 Patrick Charbonneau , Caitlin M. Gish , Robert S. Hoy , Peter K. Morse

Dynamical Mean-Field Theory (DMFT) has established itself as a reliable and well-controlled approximation to study correlation effects in bulk solids and also two-dimensional systems. In combination with standard density-functional theory…

Atomic and Molecular Clusters · Physics 2015-05-30 V. Turkowski , A. Kabir , N. Nayyar , Talat S. Rahman
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