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Quantum Phase Estimation is a crucial component of several front-running quantum algorithms. Improving the efficiency and accuracy of QPE is currently a very active field of research. In this work, we present a hybrid quantum-classical…

Quantum Physics · Physics 2024-09-25 S. M. Lim , C. E. Susa , R. Cohen

The maturation of analytical derivative theory over the past few decades has enabled classical electronic structure theory to provide accurate and efficient predictions of a wide variety of observable properties. However, classical…

Quantum Physics · Physics 2019-06-21 Robert M. Parrish , Edward G. Hohenstein , Peter L. McMahon , Todd J. Martinez

Uncertainty quantification (UQ) is an important technique for ensuring the trustworthiness of LLMs, given their tendency to hallucinate. Existing state-of-the-art UQ approaches for free-form generation rely heavily on sampling, which incurs…

Computation and Language · Computer Science 2026-05-07 Mingda Li , Rundong Lv , Xinyu Li , Weinan Zhang , Ting Liu

Estimation of physical observables for unknown quantum states is an important problem that underlies a wide range of fields, including quantum information processing, quantum physics, and quantum chemistry. In the context of quantum…

Quantum Physics · Physics 2024-05-21 Yuma Nakamura , Yoshichika Yano , Nobuyuki Yoshioka

In this proceedings we present quantum machine learning optimization experiments using stochastic gradient descent with the parameter shift rule algorithm. We first describe the gradient evaluation algorithm and its optimization procedure…

Quantum Physics · Physics 2022-10-21 Matteo Robbiati , Stavros Efthymiou , Andrea Pasquale , Stefano Carrazza

Variational quantum algorithms use non-convex optimization methods to find the optimal parameters for a parametrized quantum circuit in order to solve a computational problem. The choice of the circuit ansatz, which consists of…

Quantum Physics · Physics 2024-03-13 Roeland Wiersema , Dylan Lewis , David Wierichs , Juan Carrasquilla , Nathan Killoran

Classical machine learning often struggles with complex, high-dimensional data. Quantum machine learning offers a potential solution, promising more efficient processing. The quantum convolutional neural network (QCNN), a hybrid algorithm,…

Quantum Physics · Physics 2025-07-25 Hinako Asaoka , Kazue Kudo

We develop analytical gradients of ground- and excited-state energies with respect to system parameters including the nuclear coordinates for the hybrid quantum/classical multistate contracted variational quantum eigensolver (MC-VQE)…

Quantum Physics · Physics 2021-10-12 Robert M. Parrish , Gian-Luca R. Anselmetti , Christian Gogolin

Differential-algebraic equations (DAEs) with state-dependent events arise in systems whose continuous dynamics are constrained by algebraic equations and interrupted by mode changes, switching logic, impacts, or state reinitializations.…

Machine Learning · Computer Science 2026-05-08 Ion Matei , Maksym Zhenirovskyy , Anthony Wong

Distributed quantum computing (DQC) is crucial for high-volume quantum processing in the NISQ era. Many different technologies are utilized to implement a quantum computer, each with a different advantages and disadvantages. Various…

Quantum Physics · Physics 2025-05-26 Juan C. Boschero , Niels M. P. Neumann , Ward van der Schoot , Frank Phillipson

Stochastic gradient descent (SGD) and projected stochastic gradient descent (PSGD) are scalable algorithms to compute model parameters in unconstrained and constrained optimization problems. In comparison with SGD, PSGD forces its iterative…

Machine Learning · Statistics 2022-03-24 Ruiqi Liu , Mingao Yuan , Zuofeng Shang

Calibration of large-scale differential equation models to observational or experimental data is a widespread challenge throughout applied sciences and engineering. A crucial bottleneck in state-of-the art calibration methods is the…

Optimization and Control · Mathematics 2021-02-23 Jon Cockayne , Andrew B. Duncan

We propose a quantum machine learning framework for estimating classical covariance matrices using parameterized quantum circuits within the Pauli-Correlation-Encoding (PCE) paradigm. We introduce two quantum covariance estimators: the…

Quantum Physics · Physics 2026-04-08 Vicente P. Soloviev , Bibhas Adhikari

Adiabatic quantum computing is a universal model for quantum computing whose implementation using a gate-based quantum computer requires depths that are unreachable in the early fault-tolerant era. To mitigate the limitations of near-term…

Quantum Physics · Physics 2024-10-18 Ioannis Kolotouros , Ioannis Petrongonas , Miloš Prokop , Petros Wallden

Compressive covariance estimation has arisen as a class of techniques whose aim is to obtain second-order statistics of stochastic processes from compressive measurements. Recently, these methods have been used in various image processing…

Image and Video Processing · Electrical Eng. & Systems 2022-07-27 Jonathan Monsalve , Juan Ramirez , Iñaki Esnaola , Henry Arguello

Finding the ground state of a Hamiltonian system is of great significance in many-body quantum physics and quantum chemistry. We propose an improved iterative quantum algorithm to prepare the ground state of a Hamiltonian. The crucial point…

Quantum Physics · Physics 2022-10-25 Jin-Min Liang , Qiao-Qiao Lv , Shu-Qian Shen , Ming Li , Zhi-Xi Wang , Shao-Ming Fei

This paper proposes a novel parameter selection strategy for kernel-based gradient descent (KGD) algorithms, integrating bias-variance analysis with the splitting method. We introduce the concept of empirical effective dimension to quantify…

Machine Learning · Statistics 2026-03-05 Xiaotong Liu , Yunwen Lei , Xiangyu Chang , Shao-Bo Lin

Efficiently characterising quantum systems, verifying operations of quantum devices and validating underpinning physical models, are central challenges for the development of quantum technologies and for our continued understanding of…

We present a quantum algorithm for computing the period lattice of infrastructures of fixed dimension. The algorithm applies to infrastructures that satisfy certain conditions. The latter are always fulfilled for infrastructures obtained…

Quantum Physics · Physics 2012-06-13 Felix Fontein , Pawel Wocjan

Differential equations (DEs) serve as the cornerstone for a wide range of scientific endeavors, their solutions weaving through the core of diverse fields such as structural engineering, fluid dynamics, and financial modeling. DEs are…

Quantum Physics · Physics 2025-06-10 Josephine Hunout , Sylvain Laizet , Lorenzo Iannucci
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