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The use of biomaterials - with techniques such as DNA-directed assembly or bio-directed synthesis - can surpass top-down fabrication techniques in creating plasmonic superstructures, in terms of spatial resolution, range of functionality…

Manipulating external stimuli is crucial for enhancing and controlling the optical response in chiral structures. This study introduces chiral structures composed of single, dimer, or trimer arrays of plasmonic and magneto-plasmonic…

Chiral four-wave-mixing signals are calculated using the irreducible tensor formalism. Different polarization and crossing angle configurations allow to single out the magnetic dipole and the electric quadrupole interactions. Other…

Chemical Physics · Physics 2020-07-30 Jérémy R. Rouxel , Ahmadreza Rajabi , Shaul Mukamel

Electron transmission through chiral molecules induced by circularly polarized light can be very different for mirror-image structures, a peculiar fact given that the electronic energy spectra of the systems are identical. We propose that…

Chemical Physics · Physics 2009-11-13 Spiros S. Skourtis , David N. Beratan , Ron Naaman , Abraham Nitzan , David H. Waldeck

We study the generic interaction of a monochromatic electromagnetic field with bi-isotropic nanoparticles. Such an interaction is described by dipole-coupling terms associated with the breaking of dual, P- and T-symmetries, including the…

Optics · Physics 2014-07-23 Konstantin Y. Bliokh , Yuri S. Kivshar , Franco Nori

Chiral materials display a property called optical activity, which is the capability to interact differentially with left and right circularly polarised light. This leads to the ability to manipulate the polarisation state of light, which…

Inspired by a sea creature, we identify a robust chiral optical force that pushes the opposite enantiomers of a chiral molecule towards regions of orthogonal linear polarization in an optical field via electric dipole interactions. Our…

We present a combined classical and quantum electrodynamics description of the coupling between two circularly-polarized quantum emitters held above a metal surface supporting surface plasmons. Depending on their position and their natural…

Mesoscale and Nanoscale Physics · Physics 2019-02-11 C. A. Downing , J. C. López Carreño , F. P. Laussy , E. del Valle , A. I. Fernández-Domínguez

The van der Waals dispersion interaction between two chiral molecules in the presence of arbirary magnetoelectric media is derived using perturbation theory. To be general, the molecular polarisabilities are assumed to be of electric,…

Quantum Physics · Physics 2020-06-24 Hassan Safari , Pablo Barcellona , Stefan Yoshi Buhmann , Akbar Salam

The absorption of large bipolarons is investigated using the path-integral method. The response of a bipolaron to an external electromagnetic field is derived in the framework of the memory-function approach. The bipolaron optical…

Strongly Correlated Electrons · Physics 2009-10-31 J. T. Devreese , S. N. Klimin , V. M. Fomin

Molecular chirality plays an important role in chemistry and biology, allows control of biological interactions, affects drugs efficacy and safety, and promotes synthesis of new materials. In general, chirality manifests itself in optical…

Optics · Physics 2026-04-10 Yuanyang Xie , Alexey V. Krasavin , Anatoly V. Zayats

We propose a gain-assisted enantioselective scheme in dye-doped chiral particles, demonstrating optical pulling and pushing forces that can be tuned using externally controllable parameters. By controlling the concentration of dye molecules…

Strong enhancement of molecular circular dichroism has the potential to enable efficient asymmetric photolysis, a method of chiral separation that has conventionally been impeded by insufficient yield and low enantiomeric excess. Here, we…

Spectroscopic techniques that are sensitive to molecular chirality are important analytical tools to quantitatively determine enantiomeric excess and purity of chiral molecular samples. Many chiroptical processes however produce weak…

Chemical Physics · Physics 2026-04-02 Sebastian Hartweg , Dusan k. Bozanic , Gustavo A. Garcia-Macias , Laurent Nahon

A simple molecular model of chiral molecules is presented in this paper : the chiral dipolar hard sphere model. The discriminatory interaction between enantiomers is represented by electrostatic (or magnetic) dipoles-dipoles interactions :…

Soft Condensed Matter · Physics 2010-09-08 Martial Mazars

We show that a nonchiral atom can act as an antenna to induce a photoelectron circular dichroism in a nearby chiral molecule in a three-step process: The donor atom (antenna) is initially resonantly excited by circularly polarized…

Atomic and Molecular Clusters · Physics 2025-05-14 Stefan Yoshi Buhmann , Andreas Hans , Janine C. Franz , Philipp V. Demekhin

Identifying the handedness of chiral molecules is of fundamental importance in chemistry, biology, pharmacy, and medicine. Nanophotonic structures allow us to control light at the nanoscale and offer powerful tools for chiral sensing,…

Circular dichroism (CD) caused by the response of a chiral object to circularly polarized light has been well established, and the strong CD of plasmonic meta-molecules has also become of interest in recent years; however, their response if…

Optics · Physics 2020-09-30 Yangzhe Guo , Guodong Zhu , Wanlu Bian , Bin Dong , Yurui Fang

We show that negative refraction with minimal absorption can be obtained by means of quantum interference effects similar to electromagnetically induced transparency. Coupling a magnetic dipole transition coherently with an electric dipole…

Quantum Physics · Physics 2009-11-13 Jürgen Kästel , Michael Fleischhauer , Susanne F. Yelin , Ronald L. Walsworth

We put forward an enantioselective method for chiral nanoparticles using optical tweezers. We demonstrate that the optical trapping force in a typical, realistic optical tweezing setup with circularly-polarized trapping beams is sensitive…

Optics · Physics 2019-11-07 R. Ali , F. A. Pinheiro , F. S. S. Rosa , R. S. Dutra , P. A. Maia Neto