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In quantum chemistry, one of the most important challenges is the static correlation problem when solving the electronic Schr\"odinger equation for molecules in the Born--Oppenheimer approximation. In this article, we analyze the tailored…

Numerical Analysis · Mathematics 2019-11-21 Fabian M. Faulstich , Andre Laestadius , Örs Legeza , Reinhold Schneider , Simen Kvaal

Owing to the computational complexity of electronic structure algorithms running on classical digital computers, the range of molecular systems amenable to simulation remains tightly circumscribed even after many decades of work. Quantum…

Quantum Physics · Physics 2022-05-18 Alexis Ralli , Michael I. Williams , Peter V. Coveney

Interacting fermions on a lattice can develop strong quantum correlations, which lie at the heart of the classical intractability of many exotic phases of matter. Seminal efforts are underway in the control of artificial quantum systems,…

Mesoscale and Nanoscale Physics · Physics 2017-08-16 T. Hensgens , T. Fujita , L. Janssen , Xiao Li , C. J. Van Diepen , C. Reichl , W. Wegscheider , S. Das Sarma , L. M. K. Vandersypen

Variational quantum eigensolver ans\"atze hold considerable promise for ground-state energy calculations on near-term quantum hardware, yet most promising ansatz designs currently strongly depend on how well the molecular orbital basis…

The emerging field of strongly coupled light-matter systems has drawn significant attention in recent years due to the prospect of altering physical and chemical properties of molecules and materials. Because this emerging field draws on…

Quantum Physics · Physics 2024-01-10 Mark Kamper Svendsen , Kristian Sommer Thygesen , Angel Rubio , Johannes Flick

Computing the electronic structure of molecules with high precision is a central challenge in the field of quantum chemistry. Despite the enormous success of approximate methods, tackling this problem exactly with conventional computers is…

Quantum Physics · Physics 2020-10-20 J. Argüello-Luengo , A. González-Tudela , T. Shi , P. Zoller , J. I. Cirac

Quantifying correlation and complexity in quantum many-body states is central to advancing theoretical and computational chemistry, physics, and quantum information science. This work introduces a novel framework, mutual correlation, based…

Chemical Physics · Physics 2025-06-10 Francesco A. Evangelista

We present a mapping of correlated multi-impurity Anderson models to a cluster model coupled to a number of effective conduction bands capturing its essential low-energy physics. The major ingredient is the complex single-particle self…

Strongly Correlated Electrons · Physics 2020-12-09 Fabian Eickhoff , Frithjof B. Anders

A unitary coupled-cluster (UCC) form for the wavefunction in the variational quantum eigensolver has been suggested as a systematic way to go beyond the mean-field approximation and include electron correlation in solving quantum chemistry…

Quantum Physics · Physics 2018-09-12 Ilya G. Ryabinkin , Tzu-Ching Yen , Scott N. Genin , Artur F. Izmaylov

The control and manipulation of quantum-entangled non-local states is a crucial step for the development of quantum information processing. A promising route to achieve such states on a wide scale is to couple solid-state quantum emitters…

Optics · Physics 2022-07-06 J. -B Trebbia , Q Deplano , P Tamarat , B Lounis

Quantitative simulation of electronic structure of solids requires treating local and non-local electron correlations on an equal footing. We present a new ab initio formulation of Green's function embedding which, unlike dynamical…

Materials Science · Physics 2024-10-01 Jiachen Li , Tianyu Zhu

Quantum computing is a promising technology because of the ability of quantum computers to process vector spaces with dimensions that increase exponentially with the simulated system size. Extracting the solution, however, is challenging as…

Quantum computers hold immense potential in the field of chemistry, ushering new frontiers to solve complex many body problems that are beyond the reach of classical computers. However, noise in the current quantum hardware limits their…

Quantum Physics · Physics 2024-03-20 Chayan Patra , Sonaldeep Halder , Rahul Maitra

Recent technological advances allowed the coherent optical manipulation of high-energy electron wavepackets with attosecond precision. Here we theoretically investigate the collision of optically-modulated pulsed electron beams with atomic…

Atomic Physics · Physics 2021-04-21 Yuya Morimoto , Peter Hommelhoff , Lars Bojer Madsen

The variational quantum eigensolver has been proposed as a low-depth quantum circuit that can be employed to examine strongly correlated systems on today's noisy intermediate-scale quantum computers. We examine details associated with the…

Quantum Physics · Physics 2020-08-26 Luogen Xu , Joseph T. Lee , J. K. Freericks

Geometric phases have been used in NMR, to implement controlled phase shift gates for quantum information processing, only in weakly coupled systems in which the individual spins can be identified as qubits. In this work, we implement…

Quantum Physics · Physics 2009-11-13 T. Gopinath , Anil Kumar

Variational quantum algorithms have emerged as a powerful tool for harnessing the potential of near-term quantum devices to address complex challenges across quantum science and technology. Yet, the robust and scalable quantification of…

Quantum Physics · Physics 2025-10-21 Vahid Azimi-Mousolou , Prashant Singh

Here a finite-Lieb-lattice quantum computing circuit consisting of spin-1/2 quantum bits (qubits) and triplet couplers is designed. Important gradient - quantum entanglement - is analysed. This type of design could be realised in a vast…

Strongly Correlated Electrons · Physics 2026-04-16 Wei Wu

This article investigates quantum entanglement generated within a one-dimensional cavity where one boundary undergoes prescribed acceleration, a setup designed to mimic aspects of Hawking radiation. We quantify quantum correlations using…

General Relativity and Quantum Cosmology · Physics 2025-12-18 José Manuel Montes-Armenteros , Javier Olmedo

In this tutorial-style review we discuss basic concepts of coupled cluster theory and recent developments that increase its computational efficiency for calculations of molecules, solids and materials in general. We will touch upon the…

Materials Science · Physics 2020-04-15 Igor Ying Zhang , Andreas Grüneis