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The quantum dynamics of vibrational polaritonic states arising from the interaction of a bistable molecule with the quantized mode of a Fabry-Perot microcavity is investigated using an asymmetric double-well potential as a simplified…

Chemical Physics · Physics 2024-01-11 Loïse Attal , Florent Calvo , Cyril Falvo , Pascal Parneix

Ion Coulomb crystals are currently establishing themselves as a highly controllable test-bed for mesoscopic systems of statistical mechanics. The detailed experimental interrogation of the dynamics of these crystals however remains an…

Quantum Physics · Physics 2015-05-05 A. Lemmer , C. Cormick , C. T. Schmiegelow , F. Schmidt-Kaler , M. B. Plenio

We analytically tackle opto-vibronic interactions in molecular systems driven by either classical or quantum light fields. In particular, we examine a simple model of molecules with two relevant electronic levels, characterized by potential…

Quantum Physics · Physics 2024-02-28 Q. Zhang , M. Asjad , M. Reitz , C. Sommer , B. Gurlek , C. Genes

We propose to study the origin of algebraic decay of two-point correlation functions observed in glasses, proteins, and quantum dots by their nonlinear response to sequences of ultrafast laser pulses. Power-law spectral singularities and…

Soft Condensed Matter · Physics 2007-05-23 F. Sanda , S. Mukamel

Recent years have seen significant developments in the study of strong light-matter coupling including the control of chemical reactions by altering the vibrational normal modes of molecules. In the vibrational strong coupling regime the…

Quantum Physics · Physics 2021-08-27 John Bonini , Johannes Flick

We present a novel theoretical approach for computing and analyzing two-dimensional spectroscopy of bosonic collective excitations in disordered many-body systems. Specifically, we employ the Keldysh formalism to derive, within a…

We theoretically propose a multidimensional high-harmonic echo spectroscopy technique which utilizes strong optical fields to resolve coherent electron dynamics spanning an energy range of multiple electron Volts. Using our recently…

Slow dynamics in an amorphous quasi-two-dimensional complex plasma, comprised of microparticles of two different sizes, was studied experimentally. The motion of individual particles was observed using video microscopy, and the self-part of…

The two-dimensional spectroscopy has recently revealed oscillatory behavior of excitation dynamics in molecular systems. However, in the majority of cases it is strongly debated if excitonic or vibrational wavepackets, or evidences of…

Chemical Physics · Physics 2012-11-27 Vytautas Butkus , Donatas Zigmantas , Leonas Valkunas , Darius Abramavicius

In this review, we discuss the use of continuous variable spectroscopy techniques for investigating quantum coherence and light-matter interactions in semiconductor systems with ultrafast dynamics. We focus on multichannel homodyne…

Mesoscale and Nanoscale Physics · Physics 2023-06-05 Carolin Lüders , Franziska Barkhausen , Matthias Pukrop , Elena Rozas , Jan Sperling , Stefan Schumacher , Marc Aßmann

A robust, simple and fast procedure for the calculation of uncertainties in relative static dielectric permittivity ($\varepsilon_s$) computed via molecular dynamics (MD) is proposed. It arises as a direct application of well founded…

Chemical Physics · Physics 2019-07-22 Hernán R. Sánchez , Ramiro M. Irastorza , C. Manuel Carlevaro

Multidimensional spectroscopy unveils the interplay of nuclear and electronic dynamics, which characterizes the ultrafast dynamics of various molecular and solid-state systems. In a class of models widely used for the simulation of such…

Quantum Physics · Physics 2023-08-28 Frank Ernesto Quintela Rodriguez , Filippo Troiani

We describe a new type of spatially periodic structure (lattice models): a polaritonic crystal (PolC) formed by a two-dimensional lattice of trapped two-level atoms interacting with quantised electromagnetic field in a cavity (or in a…

Quantum Physics · Physics 2009-10-12 I. O. Barinov , A. P. Alodjants , S. M. Arakelian

Light-matter systems allow to realize a strongly correlated phase where photons are present. In these systems strong correlations are achieved by optical nonlinearities, which appear due to the coupling of photons to atomic-like structures.…

Mesoscale and Nanoscale Physics · Physics 2011-06-10 Michael Knap , Enrico Arrigoni , Wolfgang von der Linden

This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…

Chemical Physics · Physics 2020-03-18 Felipe Herrera , Jeffrey Owrutsky

We report the first experimental two-dimensional infrared (2D IR) spectra of novel molecular photonic excitations - vibrational-polaritons. The application of advanced 2D IR spectroscopy onto novel vibrational-polariton challenges and…

We study the collective behavior of molecules placed in an infrared (IR) microcavity, incorporating the local fluctuations, i.e., dynamical disorder. The cooperative feature in vibrational polaritons is shown to be dynamically eroded, due…

Quantum Physics · Physics 2018-06-19 Zhedong Zhang , Kai Wang , Zhenhuan Yi , Shaul Mukamel , Marlan O. Scully

Quantum dynamics of the photoisomerization of a single 3,3'-diethyl-2,2'-thiacynine iodide molecule embedded in an optical microcavity was theoretically studied. The molecule was coupled to a single cavity mode via the quantum Rabi…

Quantum Physics · Physics 2019-10-01 Juan B. Pérez-Sánchez , Joel Yuen-Zhou

The ideal imaging system would efficiently capture information about all fundamental properties light: intensity, direction, wavelength, and polarization. Most common imaging systems only map the spatial degrees of freedom of light onto a…

Optics · Physics 2023-01-26 Conner Ballew , Gregory Roberts , Andrei Faraon

Forming new hybrid quasiparticles by strong light-matter coupling is a promising tool for tailoring photophysics and photochemistry of molecules. Thus, the ultrafast dynamics of polaritons formed upon strong light-matter coupling has been…

Chemical Physics · Physics 2025-05-23 Luca Nils Philipp , Eva Münzel , Julian Lüttig , Roland Mitrić