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The hyperpolarisation of nuclear spins within target molecules is a critical and complex challenge in magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) spectroscopy. Hyperpolarisation offers enormous gains in signal and…

Nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) spectroscopy of bulk quantum materials have provided insight into phenomena such as quantum phase criticality, magnetism, and superconductivity. With the emergence of…

Nuclear magnetic resonance (NMR) at the single-molecule level with atomic resolution holds transformative potential for structural biology and surface chemistry. Near-surface solid-state spin sensors with optical readout ability offer a…

Quantum Physics · Physics 2025-12-12 Yu Chen , Qi Zhang , Yuanhong Teng , Chihang Luo , Zhijie Li , Jinpeng Liu , Ya Wang , Fazhan Shi , Jiangfeng Du

The application of magnetic resonance (MR) spectroscopy at progressively smaller length scales may eventually permit "chemical imaging" of spins at the surfaces of materials and biological complexes. In particular, the negatively charged…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Hai-Jing Wang , Chang S. Shin , Scott J. Seltzer , Claudia E. Avalos , Alexander Pines , Vikram S. Bajaj

Nitrogen vacancy (NV) color centers in diamond are a leading modality for both superresolution optical imaging and nanoscale magnetic field sensing. In this work, we solve the remaining key challenge of performing optical magnetic imaging…

The integration of NMR and high pressure technique brings unique opportunities to study electronic, structural and dynamical properties under extreme conditions. Despite a great degree of success has been achieved using coil-based schemes,…

Quantum Physics · Physics 2022-03-22 Yan-Xing Shang , Fang Hong , Jian-Hong Dai , Ya-Nan Lu , Hui Yu , Yong-Hong Yu , Xiao-Hui Yu , Xin-Yu Pan , Gang-Qin Liu

Optically-detected magnetic resonance using Nitrogen Vacancy (NV) color centres in diamond is a leading modality for nanoscale magnetic field imaging, as it provides single electron spin sensitivity, three-dimensional resolution better than…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 K. Arai , C. Belthangady , H. Zhang , N. Bar-Gill , S. J. DeVience , P. Cappellaro , A. Yacoby , R. L. Walsworth

We demonstrate ionization of a molecule with the bias voltage of a Scanning Tunnelling Microscope (STM) resulting in a coexistence of a neutral and ionic molecules, i.e. radical (paramagnetic) and non-radical (diamagnetic) states. This…

Mesoscale and Nanoscale Physics · Physics 2024-04-02 Yishay Manassen , Michael Averbukh , Zion Hazan , Yahel Tzuriel , Pino Boscolo , Alexsander Shnirman , Baruch Horovitz

We demonstrate a synchronized readout (SR) technique for spectrally selective detection of oscillating magnetic fields with sub-millihertz resolution, using coherent manipulation of solid state spins. The SR technique is implemented in a…

Quantum sensors based on nitrogen-vacancy centers in diamond have emerged as a promising detection modality for nuclear magnetic resonance (NMR) spectroscopy owing to their micron-scale detection volume and non-inductive based detection. A…

We present theoretical proposals for two-dimensional nuclear magnetic resonance spectroscopy protocols based on Nitrogen-vacancy (NV) centers in diamond that are strongly coupled to the target nuclei. Continuous microwave and…

Quantum Physics · Physics 2024-10-31 Matthias Kost , Jianming Cai , Martin B. Plenio

The optically induced polarization of localized electron spins in an ensemble of quantum dots (QDs) dephases due to the interaction with the surrounding nuclear spins. Despite this dephasing, the spins in the QDs can be controlled to…

Mesoscale and Nanoscale Physics · Physics 2022-04-08 P. Schering , G. S. Uhrig

After initial proof-of-principle demonstrations, optically pumped nitrogen-vacancy (NV) centres in diamond have been proposed as a non-invasive platform to achieve hyperpolarisation of nuclear spins in molecular samples over macroscopic…

Mesoscale and Nanoscale Physics · Physics 2021-01-27 J. -P. Tetienne , L. T. Hall , A. J. Healey , G. A. L. White , M. -A. Sani , F. Separovic , L. C. L. Hollenberg

We report a method for nanometer-scale pulsed nuclear magnetic resonance imaging and spectroscopy. Periodic radiofrequency pulses are used to create temporal correlations in the statistical polarization of a solid organic sample. The spin…

Mesoscale and Nanoscale Physics · Physics 2013-10-01 John M. Nichol , Tyler R. Naibert , Eric R. Hemesath , Lincoln J. Lauhon , Raffi Budakian

Nuclear magnetic resonance (NMR) imaging with shallow nitrogen-vacancy (NV) centers in diamond offers an exciting route toward sensitive and localized chemical characterization at the nanoscale. Remarkable progress has been made to combat…

Conventional nuclear magnetic resonance (NMR) spectroscopy relies on acquiring signal from a macroscopic ensemble of molecules to gain information about molecular structure and dynamics. Transferring this technique to nanoscale sample sizes…

Mesoscale and Nanoscale Physics · Physics 2019-02-06 Jeffrey Holzgrafe , Qiushi Gu , Jan Beitner , Dhiren Kara , Helena S. Knowles , Mete Atatüre

Nuclear magnetic resonance (NMR) spectroscopy exploits the magnetic properties of atomic nuclei to discover the structure, reaction state and chemical environment of molecules. We propose a probabilistic generative model and inference…

Nuclear magnetic resonance (NMR) has enormous applications. Two-dimensional NMR is an essential technique to characterize correlations between nuclei and, hence, molecule structures. Towards the ultimate goal of single-molecule NMR,…

Quantum Physics · Physics 2016-11-30 Wen-Long Ma , Ren-Bao Liu

Magnetic resonance imaging (MRI) has revolutionized biomedical science by providing non-invasive, three-dimensional biological imaging. However, spatial resolution in conventional MRI systems is limited to tens of microns, which is…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 M. S. Grinolds , M. Warner , K. De Greve , Y. Dovzhenko , L. Thiel , R. L. Walsworth , S. Hong , P. Maletinsky , A. Yacoby

Nanodiamonds containing nitrogen vacancy (NV-) centers show promise for a number of emerging applications including targeted in vivo imaging and generating nuclear spin hyperpolarization for enhanced NMR spectroscopy and imaging. Here, we…