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Catalyst discovery is paramount to support access to energy and key chemical feedstocks in a post fossil fuel era. Exhaustive computational searches of large material design spaces using ab-initio methods like density functional theory…

Materials Science · Physics 2022-08-29 Brook Wander , Kirby Broderick , Zachary W. Ulissi

Paired electrolysis at industrial current densities offers an energy-efficient and sustainable alternative to thermocatalytic chemical synthesis by leveraging anodic and cathodic valorization. However, its industrial feasibility remains…

Magnetic cooling based on the magnetocaloric effect is a promising solid-state refrigeration technology for a wide range of applications in different temperature ranges. Previous studies have mostly focused on near room temperature (300 K)…

Materials Science · Physics 2024-03-06 Jiaoyue Yuan , Runqing Yang , Lokanath Patra , Bolin Liao

Methyl valerate (C$_6$H$_{12}$O$_2$, methyl pentanoate) is a methyl ester and a relevant surrogate component for biodiesel. In this work, we present ignition delays of methyl valerate measured using a rapid compression machine at a range of…

Chemical Physics · Physics 2017-06-07 Bryan W. Weber , Justin Bunnell , Kamal Kumar , Chih-Jen Sung

The autoignition delays of mixtures of methyl-cyclohexane (MCH), oxygen, nitrogen, and argon have been studied in a heated rapid compression machine under the conditions $P_C$ = 50 bar, $T_C$ = 690 - 910K. Three different mixture…

Chemical Physics · Physics 2017-06-07 Bryan W. Weber , William J. Pitz , Chih-Jen Sung , Marco Mehl , Emma J. Silke , Alexander C. Davis

Magnesium hydride (MgH2) is a promising material for hydrogen storage because of its abundance and beneficial properties, such as high storage capacity and cost-effectiveness under mild conditions. Despite of these benefits, MgH2…

Materials Science · Physics 2025-01-09 Yogesh Kumar Yadav , Mohammad Abu Shaz , Thakur Prasad Yadav

One of the most important and difficult parts of constructing a multidimensional numerical simulation of flame acceleration and deflagration-to-detonation transition (DDT) in a reacting flow is finding a reliable and affordable model of the…

Fluid Dynamics · Physics 2017-09-04 Carolyn R. Kaplan , Alp Ozgen , Elaine S. Oran

Aqueous hydrolysis is used to chemically recycle polyethylene terephthalate (PET) due to the production of high-quality terephthalic acid (TPA), the PET monomer. PET hydrolysis depends on various reaction conditions including PET size,…

Machine Learning · Computer Science 2022-02-01 Hossein Abedsoltan , Zeinab Zoghi , Amir H. Mohammadi

The production of hydrogen fuels, via water splitting, is of practical relevance for meeting global energy needs and mitigating the environmental consequences of fossil-fuel-based transportation. Water photoelectrolysis has been proposed as…

Alloys present the great potential in catalysis because of their adjustable compositions, structures and element distributions, which unfortunately also limit the fast screening of the potential alloy catalysts. Machine learning methods are…

Materials Science · Physics 2021-07-07 Xin Li , Bo Li , Zhiwen Chen , Wang Gao , Qing Jiang

Safe and high-density storage of hydrogen, for a clean-fuel economy, can be realized by hydride-forming materials, but these materials should be able to store hydrogen at room temperature. Some high-entropy alloys (HEAs) have recently been…

Materials Science · Physics 2024-05-31 Shivam Dangwal , Yuji Ikeda , Blazej Grabowski , Kaveh Edalati

The use of synthetic fuels is a promising way to reduce emissions significantly. To accelerate cost-effective large-scale synthetic fuel deployment, we optimize a novel 1 MW PtL-plant in terms of PtL-efficiency and fuel production costs.…

Optimization and Control · Mathematics 2023-11-15 David Huber , Felix Birkelbach , René Hofmann

We develop a one-dimensional mathematical model for the loading process of hydrogen in a metal hydride tank. The model describes the evolution of the density and pressure of the hydrogen gas, the temperature of the tank, the averaged…

Materials Science · Physics 2025-07-31 Francesc Font , Attila Husar , Tim Myers , Maria Aguareles , Esther Barrabés

The last years saw a renewal of interest for hypersonic research in general and regenerative cooling specifically, with a large increase of the number of dedicated facilities and technical studies. In order to quantify the heat transfer in…

Methane ($CH_4$) is a potent anthropogenic greenhouse gas, contributing 86 times more to global warming than Carbon Dioxide ($CO_2$) over 20 years, and it also acts as an air pollutant. Given its high radiative forcing potential and…

Computer Vision and Pattern Recognition · Computer Science 2024-08-28 Enno Tiemann , Shanyu Zhou , Alexander Kläser , Konrad Heidler , Rochelle Schneider , Xiao Xiang Zhu

One pot synthetic technique was used to synthesize mesoporous fullerene using highly ordered mesoporous template such as KIT6-150 and SBA-15-150. Highly ordered porous fullerene with cross linkage between the fullerene molecules was…

Materials Science · Physics 2015-03-12 Sujit K. Mondal

For ethylene carbonate on the (100) surface of lithium, we calculate the adsorption energy in two binding motifs as well as the barrier height for a ring-opening decomposition reaction. We validate a scheme for producing results in the…

Metal-organic framework (MOF) derived materials formed through high temperature processes show great potential as catalysts. However, understanding of structure-property relationships between the initial MOF and the resulting MOF-derived…

Materials Science · Physics 2026-01-26 Connor W. Edwards , Oliver M. Linder-Patton , Jack D. Evans

Aims: The production of saturated organic molecules in hot cores and corinos is not well understood. The standard approach is to assume that, as temperatures heat up during star formation, methanol and other species evaporate from grain…

Astrophysics · Physics 2009-11-11 R. T. Garrod , E. Herbst

The equation of state of liquid metallic hydrogen is solved numerically. Investigations are carried out at temperatures, which correspond both to the experimental conditions under which metallic hydrogen is produced on earth and the…

Chemical Physics · Physics 2016-02-25 V. T. Shvets