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A procedure for calculation of rotation-vibration states of medium sized molecules is presented. It combines the advantages of variational calculations and perturbation theory. The vibrational problem is solved by diagonalizing a…

Chemical Physics · Physics 2015-04-13 A. I. Pavlyuchko , S. N. Yurchenko , Jonathan Tennyson

The well-known algorithm for quantum phase estimation requires that the considered unitary is available as a conditional transformation depending on the quantum state of an ancilla register. We present an algorithm converting an unknown…

Quantum Physics · Physics 2007-05-23 Dominik Janzing

The relations between a quantum wave impedance function and elements of transfer and scattering matrixes for quantum mechanical systems with arbitrary localized form of potential were established. Obtained results allows using the…

Quantum Physics · Physics 2020-10-22 O. I. Hryhorchak

The Rabi model that describes the fundamental interaction between a two-level system with a quantized harmonic oscillator is one of the simplest and most ubiquitous models in modern physics. However, this model has not been solved exactly…

Quantum Physics · Physics 2015-06-04 Lixian Yu , Shiqun Zhu , Qifeng Liang , Gang Chen , Suotang Jia

Collective phenomena in the Tavis-Cummings model has been widely studied, focusing on the phase transition features. In many occasions, it has been used variational approaches that consider separated radiation-matters systems. In this…

Quantum Physics · Physics 2021-01-19 J. P. Restrepo Cuartas , H. Vinck-Posada

We use a natural generalization of the discrete Fourier transform to define transition maps between Hilbert subspaces and the global transport operator $Z$. By using these transition maps as Kraus (or noise) operators, an extension of the…

Mathematical Physics · Physics 2021-02-03 Jorge R. Bolaños-Servín , Roberto Quezada , Josué I. Rios-Cangas

In the present article explicit expressions for the decay rate and energy level shifts of an atom in the presence of an ideal conducting wedge, two parallel plates and a half-sheet are obtained in the frame work of the canonical…

Quantum Physics · Physics 2016-01-20 Zahra Mohammadi , Fardin Kheirandish

We introduce a framework for the calculation of ground and excited state energies of bosonic systems suitable for near-term quantum devices and apply it to molecular vibrational anharmonic Hamiltonians. Our method supports generic reference…

Quantum Physics · Physics 2020-06-24 Pauline J. Ollitrault , Alberto Baiardi , Markus Reiher , Ivano Tavernelli

We review the progress in atomic structure theory with a focus on superheavy elements and the aim to predict their ground state configuration and element's placement in the periodic table. To understand the electronic structure and…

Atomic Physics · Physics 2023-01-09 O. R. Smits , P. Indelicato , W. Nazarewicz , M. Piibeleht , P. Schwerdtfege

The variational method is used to study the energy levels of muonic helium $(\mu^{-} \, e^{-} \, He)$ with an electron in the ground state and a muon in an excited state with principal and orbital quantum numbers $n \sim l+1 \sim 14$. The…

High Energy Physics - Phenomenology · Physics 2026-05-01 A. V. Eskin , A. P. Martynenko , F. A. Martynenko , D. K. Pometko

We establish a physically meaningful representation of a quantum energy density for use in Quantum Monte Carlo calculations. The energy density operator, defined in terms of Hamiltonian components and density operators, returns the correct…

Materials Science · Physics 2013-08-09 Jaron T. Krogel , Min Yu , Jeongnim Kim , David M. Ceperley

Traditional computational methods for studying quantum many-body systems are "forward methods," which take quantum models, i.e., Hamiltonians, as input and produce ground states as output. However, such forward methods often limit one's…

Strongly Correlated Electrons · Physics 2018-07-31 Eli Chertkov , Bryan K. Clark

We prove Goldschmidt's formula [Phys. Rev. B 47 (1990) 4858] for the free energy of the quantum random energy model. In particular, we verify the location of the first order and the freezing transition in the phase diagram. The proof is…

Mathematical Physics · Physics 2020-02-19 Chokri Manai , Simone Warzel

We find an analytical expression for the conductance of a single electron transistor in the regime when temperature, level spacing, and charging energy of a grain are all of the same order. We consider the model of equidistant energy levels…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Serguei Vorojtsov

The quantum phase diagram for a finite $3$-level system in the $\Lambda$ configuration, interacting with a two-mode electromagnetic field in a cavity, is determined by means of information measures such as fidelity, fidelity susceptibility…

Quantum Physics · Physics 2023-02-21 O. Castaños , S. Cordero , R. López-Peña , E. Nahmad-Achar

The transfer-matrix methodology is used to solve linear systems of differential equations, such as those that arise when solving Schr\"odinger's equation, in situations where the solutions of interest are in the continuous part of the…

Mesoscale and Nanoscale Physics · Physics 2019-07-17 Alexandre Mayer

We develop a unified framework to compute band-geometric quantities in multiband systems whose low-energy Hamiltonians realize arbitrary $SU(2)$ representations. Exploiting the presence of a quantization axis, we use the Wigner--Eckart…

Mesoscale and Nanoscale Physics · Physics 2026-02-18 Rhonald Burgos Atencia

Quantum computers have a potential for solving quantum chemistry problems with higher accuracy than classical computers. Quantum computing quantum Monte Carlo (QC-QMC) is a QMC with a trial state prepared in quantum circuit, which is…

Quantum Physics · Physics 2024-06-07 Shu Kanno , Hajime Nakamura , Takao Kobayashi , Shigeki Gocho , Miho Hatanaka , Naoki Yamamoto , Qi Gao

In this work we investigate methods to improve the efficiency and scalability of quantum algorithms for quantum chemistry applications. We propose a transformation of the electronic structure Hamiltonian in the second quantization framework…

We investigate the connection between energy level crossings in integrable systems and their integrability, i.e. the existence of a set of non-trivial integrals of motion. In particular, we consider a general quantum Hamiltonian linear in…

Statistical Mechanics · Physics 2009-01-14 H. K. Owusu , K. Wagh , E. A. Yuzbashyan