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The geometric shape, symmetry, and topology of colloidal particles often allow for controlling colloidal phase behavior and physical properties of these soft matter systems. In liquid crystalline dispersions, colloidal particles with low…

Soft Condensed Matter · Physics 2024-10-14 Ye Yuan , Ivan I. Smalyukh

We report Monte Carlo studies of a two-dimensional soft colloidal crystal confined in a strip geometry by parallel walls. The wall-particle interaction has corrugations along the length of the strip. Compressing the crystal by decreasing…

Soft Condensed Matter · Physics 2013-05-29 Yu-Hang Chui , Surajit Sengupta , Ian K. Snook , Kurt Binder

Deviations from the perfect atomic arrangements in crystals play an important role in affecting their properties. Similarly, diffusion of such deviations is behind many microstructural changes in solids. However, observation of point defect…

Materials Science · Physics 2014-07-28 Jani Kotakoski , Clemens Mangler , Jannik C. Meyer

Plasmonic crystals are well known to have band structure including a bandgap, enabling the control of surface plasmon propagation and confinement. The band dispersion relation of bulk crystals has been generally measured by…

Our previous molecular dynamic simulation studies of simple two-dimensional (2D) systems \cite{matt_big} suggested that both geometrical defects (localized, large-amplitude deviations from hexagonal ordering) and topological defects…

Statistical Mechanics · Physics 2007-05-23 Yves Lansac , Matthew A. Glaser , Noel A. Clark

The structural characterization of microgels at interfaces is fundamental to understand both their 2D phase behavior and their role as stabilizers that enable emulsions to be broken on demand. However, this characterization is usually…

We use confocal microscopy to study an equilibrated crystal-liquid interface in a colloidal suspension. Capillary waves roughen the surface, but locally the intrinsic interface is sharply defined. We use local measurements of the structure…

Soft Condensed Matter · Physics 2009-09-28 Jessica Hernández-Guzmán , Eric R. Weeks

The kinetics of phase transition processes often governs the resulting material microstruc-ture. Using optical microscopy, we here investigate the formation and stabilization of a po-rous crystalline microstructure forming in low-salt…

Soft Condensed Matter · Physics 2023-06-23 Nina Lorenz , Christopher Wittenberg , Thomas Palberg

Using the path-integral Monte Carlo method, we calculate the energy to form single and pair vacancies and interstitials in a two-dimensional Wigner crystal of electrons. We confirm that the lowest-lying energy defects of a 2D electron…

Condensed Matter · Physics 2009-10-31 Ladir Cândido , Philip Phillips , D. M. Ceperley

Colloidal dispersions are prized as model systems to understand basic properties of materials, and are central to a wide range of industries from cosmetics to foods to agrichemicals. Among the key developments in using colloids to address…

Soft Condensed Matter · Physics 2022-06-22 Jun Dong , Francesco Turci , Robert L. Jack , Malcolm A. Faers , C. Patrick Royall

Thermoresponsive microgels find widespread use as colloidal model systems, because their temperature-dependent size allows facile tuning of their volume fraction "in situ". However, an interaction potential unifying their behavior across…

Spherical colloidal crystals (CCs) self-assemble on the interface between two liquids. These 2D structures unconventionally combine local hexagonal order and spherical geometry. Nowadays CCs are actively studied by altering their…

Soft Condensed Matter · Physics 2015-10-28 D. S. Roshal , A. E. Myasnikova , S. B. Rochal

Point defects in real crystals at finite temperatures are inevitable. Their dynamics severely influence the mechanical properties of crystals under shear giving rise to nonlinear effects such as ductility. Therefore, it is crucial to…

Soft Condensed Matter · Physics 2021-02-02 Gaurav P. Shrivastav , Gerhard Kahl

Point defects play a crucial role in crystalline materials as they do not only impact the thermodynamic properties but are also central to kinetic processes. While they are necessary in thermodynamic equilibrium spontaneous defect formation…

Materials Science · Physics 2020-08-03 Erik Fransson , Paul Erhart

In this article, we demonstrate a method for inducing reversible crystal-to-crystal transitions in binary mixtures of soft colloidal particles. Through a controlled decrease of salinity and increasingly dominating electrostatic…

Soft Condensed Matter · Physics 2021-08-30 Jasper N. Immink , Maxime J. Bergman , J. J. Erik Maris , Joakim Stenhammar , Peter Schurtenberger

The mechanical, structural and functional properties of crystals are determined by their defects and the distribution of stresses surrounding these defects has broad implications for the understanding of transport phenomena. When the defect…

Materials Science · Physics 2016-09-02 Neil Y. C. Lin , Matthew Bierbaum , Peter Schall , James P. Sethna , Itai Cohen

Liquid crystals inevitably possess topological defect excitations generated through boundary conditions, applied fields or in quenches to the ordered phase. In equilibrium pairs of defects coarsen and annihilate as the uniform ground state…

Soft Condensed Matter · Physics 2013-06-05 Luca Giomi , Mark J. Bowick , Xu Ma , M. Cristina Marchetti

A coherent x-ray diffraction experiment was performed on an isolated colloidal crystal grain at the coherence beamline P10 at PETRA III. Using azimuthal rotation scans the three-dimensional (3D) scattered intensity in reciprocal space from…

Soft colloids are increasingly used as model systems to address fundamental issues such as crystallisation and the glass and jamming transitions. Among the available classes of soft colloids, microgels are emerging as the gold standard.…

Microgels are often discussed as well-suited model system for soft colloids. In contrast to rigid spheres, the microgel volume and, coupled to this, the volume fraction in dispersion can be manipulated by external stimuli. This behavior is…