English
Related papers

Related papers: Efficient simulations of Hartree--Fock equations b…

200 papers

The development of machine learning is promoting the search for fast and stable minimization algorithms. To this end, we suggest a change in the current gradient descent methods that should speed up the motion in flat regions and slow it…

Machine Learning · Computer Science 2019-06-13 Marco Baiesi

Accelerated coordinate descent is widely used in optimization due to its cheap per-iteration cost and scalability to large-scale problems. Up to a primal-dual transformation, it is also the same as accelerated stochastic gradient descent…

Optimization and Control · Mathematics 2016-05-30 Zeyuan Allen-Zhu , Zheng Qu , Peter Richtárik , Yang Yuan

We present here a review of the fundamental topics of Hartree-Fock theory in Quantum Chemistry. From the molecular Hamiltonian, using and discussing the Born-Oppenheimer approximation, we arrive to the Hartree and Hartree-Fock equations for…

Chemical Physics · Physics 2008-11-25 Pablo Echenique , J. L. Alonso

Generating intelligent robot behavior in contact-rich settings is a research problem where zeroth-order methods currently prevail. Developing methods that make use of first/second order information about rigid-body dynamics in the presence…

Robotics · Computer Science 2026-05-26 Onur Beker , Andreas René Geist , Anselm Paulus , Georg Martius

We consider the projected gradient algorithm for the nonconvex best subset selection problem that minimizes a given empirical loss function under an $\ell_0$-norm constraint. Through decomposing the feasible set of the given sparsity…

Optimization and Control · Mathematics 2026-02-13 Jan Harold Alcantara , Ching-pei Lee

We propose an ab-initio molecular dynamics method, capable to reduce dramatically the autocorrelation time required for the simulation of classical and quantum particles at finite temperature. The method is based on an efficient…

Strongly Correlated Electrons · Physics 2017-01-11 Sandro Sorella , Guglielmo Mazzola

Recent advances in both theoretical and computational methods have enabled large-scale, precision calculations of the properties of atomic nuclei. With the growing complexity of modern nuclear theory, however, also comes the need for novel…

Nuclear Theory · Physics 2024-11-26 R. Y. Cheng , K. Godbey , Y. B. Niu , Y. G. Ma , W. B. He , S. M. Wang

To efficiently implement many-qubit gates for use in quantum simulations on quantum computers we develop and present methods reexpressing exp[-i (H_1 + H_2 + ...) \Delta t] as a product of factors exp[-i H_1 \Delta t], exp[-i H_2 \Delta t],…

Quantum Physics · Physics 2009-10-31 A. T. Sornborger , E. D. Stewart

We propose a variant of the classical conditional gradient method for sparse inverse problems with differentiable measurement models. Such models arise in many practical problems including superresolution, time-series modeling, and matrix…

Optimization and Control · Mathematics 2015-07-07 Nicholas Boyd , Geoffrey Schiebinger , Benjamin Recht

We benchmark three standard approximations for the many-body problem -- the Hartree-Fock, projected Hartree-Fock, and random phase approximations -- against full numerical configuration-interaction calculations of the electronic structure…

Atomic Physics · Physics 2012-08-31 Micah D. Schuster , Calvin W. Johnson , Joshua T. Staker

In this paper, we propose a Distributed Accumulated Newton Conjugate gradiEnt (DANCE) method in which sample size is gradually increasing to quickly obtain a solution whose empirical loss is under satisfactory statistical accuracy. Our…

Machine Learning · Computer Science 2020-03-11 Majid Jahani , Xi He , Chenxin Ma , Aryan Mokhtari , Dheevatsa Mudigere , Alejandro Ribeiro , Martin Takáč

A class of monotone operator equations, which can be decomposed into sum of the gradient of a strongly convex function and a linear and skew-symmetric operator, is considered in this work. Based on discretization of the generalized gradient…

Optimization and Control · Mathematics 2025-01-22 Long Chen , Jingrong Wei

We propose an adaptive step size with an energy approach for a suitable class of preconditioned gradient descent methods. We focus on settings where the preconditioning is applied to address the constraints in optimization problems, such as…

Optimization and Control · Mathematics 2024-06-17 Hailiang Liu , Levon Nurbekyan , Xuping Tian , Yunan Yang

The preformation factor quantifies the probability of {\alpha} particles preforming on the surface of the parent nucleus in decay theory and is closely related to the study of {\alpha} clustering structure. In this work, a multilayer…

Nuclear Theory · Physics 2025-04-04 Jiaqi Luo , Yang Xu , Xiaolong Li , Junxiang Wang , Yangjie Zhang , Jungang Deng , Fang Zhang , Nana Ma

A novel and highly efficient computational framework for reconstructing binary-type images suitable for models of various complexity seen in diverse biomedical applications is developed and validated. Efficiency in computational speed and…

Optimization and Control · Mathematics 2024-02-09 Paul R. Arbic , Vladislav Bukshtynov

This paper provides a theoretical and numerical comparison of classical first-order splitting methods for solving smooth convex optimization problems and cocoercive equations. From a theoretical point of view, we compare convergence rates…

Optimization and Control · Mathematics 2022-07-15 Luis Briceño-Arias , Nelly Pustelnik

We develop a new method of implementing the Hartree-Fock calculations. A class of Gaussian bases is assumed, which includes the Kamimura-Gauss basis-set as well as the set equivalent to the harmonic-oscillator basis-set. By using the…

Nuclear Theory · Physics 2011-07-19 H. Nakada , M. Sato

We develop a micromorphic-based approach for finite element stabilization of reaction-convection-diffusion equations, by gradient enhancement of the field of interest via introducing an auxiliary variable. The well-posedness of the…

Mathematical Physics · Physics 2025-10-15 Soheil Firooz , B. Daya Reddy , Paul Steinmann

A novel multiscale numerical method is developed to accelerate direct simulation Monte Carlo (DSMC) simulations for polyatomic gases with internal energy. This approach applies the general synthetic iterative scheme to stochastic…

Computational Physics · Physics 2025-01-22 Liyan Luo , Tao Huang , Qi Li , Lei Wu

We describe a method of solving the nuclear Skyrme-Hartree-Fock problem by using a deformed Cartesian harmonic oscillator basis. The complete list of expressions required to calculate local densities, total energy, and self-consistent…

Nuclear Theory · Physics 2009-10-30 J. Dobaczewski , J. Dudek