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The problem of estimating entropy production from incomplete information in stochastic thermodynamics is essential for theory and experiments. Whereas a considerable amount of work has been done on this topic, arguably, most of it is…

Statistical Mechanics · Physics 2024-12-17 Pedro E. Harunari , Carlos E. Fiore , Andre C. Barato

The theory of entropy production in nonequilibrium, Hamiltonian systems, previously described for steady states using partitions of phase space, is here extended to time dependent systems relaxing to equilibrium. We illustrate the main…

Chaotic Dynamics · Physics 2009-10-31 T. Gilbert , J. R. Dorfman , P. Gaspard

Employing the stochastic wave function method, we study quantum features of stochastic entropy production in nonequilibrium processes of open systems. It is demonstarted that continuous measurements on the environment introduce an…

Quantum Physics · Physics 2013-10-16 B. Leggio , A. Napoli , A. Messina , H. -P. Breuer

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

Statistical Mechanics · Physics 2020-10-13 Jianzhong Wu

It is known that the equilibrium properties of open classical systems that are strongly coupled to a heat bath are described by a set of thermodynamic potentials related to the system's Hamiltonian of mean force. By adapting this framework…

Statistical Mechanics · Physics 2017-06-28 Harry J. D. Miller , Janet Anders

The selection of an equilibrium state by maximising the entropy of a system, subject to certain constraints, is often powerfully motivated as an exercise in logical inference, a procedure where conclusions are reached on the basis of…

Statistical Mechanics · Physics 2015-12-03 Ian J. Ford

Entropy production is the key to the second law of thermodynamics, and it is well defined by considering a joint unitary evolution of a system $S$ and a thermal environment $E$. However, due to the diversity of the initial state and…

Quantum Physics · Physics 2022-07-19 Hao Xu , Si Yu Chen

Entropy production during the process of thermal phase-separation of multiphase flows is investigated by means of a discrete Boltzmann kinetic model. The entropy production rate is found to increase during the spinodal decomposition stage…

Statistical Mechanics · Physics 2019-03-18 Yudong Zhang , Aiguo Xu , Guangcai Zhang , Yanbiao Gan , Zhihua Chen , Sauro Succi

The second law of nonequilibrium thermodynamics within the open system paradigm (a small system coupled to one or multiple baths) is derived. This is done by showing positivity of entropy production for arbitrary Hamiltonian dynamics for a…

Statistical Mechanics · Physics 2020-08-28 Philipp Strasberg

The question of characterization of the degree of non-equilibrium activity in active matter systems is studied in the context of a stochastic microswimmer model driven by a chemical cycle. The resulting dynamical properties and entropy…

Statistical Mechanics · Physics 2024-05-27 Michalis Chatzittofi , Jaime Agudo-Canalejo , Ramin Golestanian

A complete mathematical theory of nonequilibrium thermodynamics of stochastic systems in terms of master equations is presented. As generalizations of isothermal entropy and free energy, two functions of states play central roles: the Gibbs…

Statistical Mechanics · Physics 2010-05-28 Hao Ge , Hong Qian

A theory for non-equilibrium systems is derived from a maximum entropy approach similar in spirit to the equilibrium theory given by Gibbs. Requiring Hamilton's principle of stationary action to be satisfied on average during a trajectory,…

Statistical Mechanics · Physics 2019-02-04 David M. Rogers , Susan B. Rempe

By using entropy and entropy production, we calculate the steady flux of some phenomena. The method we use is a competition method, $S_S/\tau+\sigma={\it maximum}$, where $S_S$ is system entropy, $\sigma$ is entropy production and $\tau$ is…

Statistical Mechanics · Physics 2016-07-26 Yong-Jun Zhang

Far-from-equilibrium thermodynamics underpins the emergence of life, but how has been a long-outstanding puzzle. Best candidate theories based on the maximum entropy production principle could not be unequivocally proven, in part due to…

Quantitative Methods · Quantitative Biology 2017-10-10 Robert G. Endres

We propose an expression for the production of entropy for system described by a stochastic dynamics which is appropriate for the case where the reverse transition rate vanishes but the forward transition is nonzero. The expression is…

Statistical Mechanics · Physics 2024-08-22 Tânia Tome , Mário J. de Oliveira

Recently, the fundamental laws of thermodynamics have been reconsidered for small systems. The discovery of the fluctuation relations has spurred theoretical and experimental studies on thermodynamics of systems with few degrees of freedom.…

Statistical Mechanics · Physics 2021-08-10 J. V. Koski , T. Sagawa , O. -P. Saira , Y. Yoon , A. Kutvonen , P. Solinas , M. Möttönen , T. Ala-Nissila , J. P. Pekola

We explore the consequences of a deterministic microscopic thermostat-reservoir contact mechanism. With different temperature reservoirs at each end of a two-dimensional system, a heat current is produced and the system has an anomalous…

Statistical Mechanics · Physics 2015-06-15 Gary P. Morriss , Daniel P. Truant

We consider optimization of the average entropy production in inhomogeneous temperature environments within the framework of stochastic thermodynamics. For systems modeled by Langevin equations (e.g. a colloidal particle in a heat bath) it…

Statistical Mechanics · Physics 2013-03-14 Stefano Bo , Erik Aurell , Ralf Eichhorn , Antonio Celani

Thermodynamic uncertainty relations reveal a fundamental trade-off between the precision of a trajectory observable and entropy production, where the uncertainty of the observable is quantified by its variance. In information theory,…

Statistical Mechanics · Physics 2025-11-25 Yoshihiko Hasegawa , Tomohiro Nishiyama

The second law of thermodynamics, which asserts the non-negativity of the average total entropy production of a combined system and its environment, is a direct consequence of applying Jensen's inequality to a fluctuation relation. It is…

Statistical Mechanics · Physics 2017-03-22 Surachate Limkumnerd