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We theoretically explore photoassociation by Adiabatic Passage of two colliding cold ^{85}Rb atoms in an atomic trap to form an ultracold Rb_2 molecule. We consider the incoherent thermal nature of the scattering process in a trap and show…

Quantum Physics · Physics 2009-11-13 Evgeny A. Shapiro , Moshe Shapiro , Avi Pe'er , Jun Ye

The formation of ultracold metastable RbCs molecules is observed in a double species magneto-optical trap through photoassociation below the ^85Rb(5S_1/2)+^133Cs(6P_3/2) dissociation limit followed by spontaneous emission. The molecules are…

Atomic Physics · Physics 2015-06-03 N. Bouloufa-Maafa , M. Aymar , O. Dulieu , C. Gabbanini

We have produced ultracold heteronuclear KRb molecules by the process of photoassociation in a two-species magneto-optical trap. Following decay of the photoassociated KRb*, the molecules are detected using two-photon ionization and…

We explore the feasibility of optically forming long-range tetratomic and larger polyatomic molecules in their ground electronic state from ultracold pairs of polar molecules aligned by external fields. Depending on the relative orientation…

Atomic Physics · Physics 2021-06-16 Marko Gacesa , Jason N. Byrd , Jonathan Smucker , John A. Montgomery, , Robin Côté

Photoassociation of ultracold atoms is a resonant light-assisted collision process, in which two colliding atoms absorb a photon and form an excited molecule. Since the first observation about three decades ago, the photoassociation of…

Atomic Physics · Physics 2024-03-19 Jin Cao , Bo-Yuan Wang , Huan Yang , Zhi-Jie Fan , Zhen Su , Jun Rui , Bo Zhao , Jian-Wei Pan

The general formalism of the multipolar expansion of electrostatic interactions is applied to the calculation the potential energy between an excited atom (without fine structure) and a ground state diatomic molecule at large separations.…

Quantum Physics · Physics 2017-04-11 M. Lepers , O. Dulieu , V. Kokoouline

The paper investigates cold molecules formation in the photoassociation of two cold atoms by a strong laser pulse applied at short interatomic distances, which lead to a molecular dynamics taking place in the light-induced (adiabatic)…

Quantum Physics · Physics 2009-07-23 M. Vatasescu

We report on the creation and characterization of heteronuclear KRb Feshbach molecules in an optical dipole trap. Starting from an ultracold gas mixture of K-40 and Rb-87 atoms, we create as many as 25,000 molecules at 300 nK by rf…

Other Condensed Matter · Physics 2008-08-22 J. J. Zirbel , K. -K. Ni , S. Ospelkaus , T. L. Nicholson , M. L. Olsen , C. E. Wieman , J. Ye , D. S. Jin , P. S. Julienne

We demonstrate the formation of a single RbCs molecule during the merging of two optical tweezers, one containing a single Rb atom and the other a single Cs atom. Both atoms are initially predominantly in the motional ground states of their…

The creation of ultracold molecules is currently limited to diatomic species. In this letter we present a theoretical description of the photoassociation of ultracold atoms and molecules to create ultracold excited triatomic molecules, thus…

Atomic Physics · Physics 2015-09-02 Jesús Pérez-Ríos , Maxence Lepers , Olivier Dulieu

Utilizing single-photon photoassociation, we have achieved ultracold rubidium molecules with a high number density that provides a new efficient approach toward molecular quantum degeneracy. A new detection mechanism for ultracold molecule…

Atomic Physics · Physics 2015-06-12 Jun-Ren Chen , Cheng-Yang Kao , Hung-Bin Chen , Yi-Wei Liu

We have produced ultracold heteronuclear YbRb$^*$ molecules in a combined magneto-optical trap by photoassociation. The formation of electronically excited molecules close to the dissociation limit was observed by trap loss spectroscopy in…

Quantum Physics · Physics 2016-01-20 N. Nemitz , F. Baumer , F. Münchow , S. Tassy , A. Görlitz

Mergoassociation of two ultracold atoms to form a weakly bound molecule can occur when two optical traps that each contain a single atom are merged. Molecule formation occurs at an avoided crossing between a molecular state and the lowest…

Atomic Physics · Physics 2023-10-04 Robert C. Bird , C. Ruth Le Sueur , Jeremy M. Hutson

Photoassociation of ultracold atoms is shown to lead to alignment of the product molecules along the excitation laser polarization axis. We theoretically investigate pulsed photoassociation of $^{87}Rb$ atoms into a specific weakly-bound…

Quantum Physics · Physics 2017-11-15 S. Kallush , J. L. Carini , P. L. Gould , R. Kosloff

Ultracold metastable RbCs molecules are observed in a double species MOT through photoassociation near the Rb(5S$_{1/2}$)+Cs(6P$_{3/2}$) dissociation limit followed by radiative stabilization. The molecules are formed in their lowest…

Atomic Physics · Physics 2017-09-13 C. Gabbanini , O. Dulieu

Measurements of interactions between cold molecules and ultracold atoms can allow for a detailed understanding of fundamental collision processes. These measurements can be done using various experimental geometries including where both…

Atomic Physics · Physics 2020-03-25 N. J. Fitch , L. P. Parazzoli , H. J. Lewandowski

We demonstrate the direct formation of vibronic ground state RbCs molecules by photoassociation of ultracold atoms followed by radiative stabilization. The photoassociation proceeds through deeply-bound levels of the (2)^{3}\Pi_{0^{+}}…

Atomic Physics · Physics 2015-06-16 C. D. Bruzewicz , Mattias Gustavsson , Toshihiko Shimasaki , D. DeMille

The electrostatic interaction between an excited atom and a diatomic ground state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective…

Quantum Physics · Physics 2017-04-11 M. Lepers , R. Vexiau , N. Bouloufa , O. Dulieu , V. Kokoouline

We discuss techniques to engineer effective long-range interactions between polar molecules using external static electric and microwave fields. We consider a setup where molecules are trapped in a two-dimensional pancake geometry by a…

Quantum Physics · Physics 2009-11-13 A. Micheli , G. Pupillo , H. P. Büchler , P. Zoller

We have produced ultracold, polar RbCs* molecules via photoassociation in a laser-cooled mixture of Rb and Cs atoms. Using a model of the RbCs* molecular interaction which reproduces the observed rovibrational structure, we infer decay…

Atomic Physics · Physics 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , David DeMille , Thomas Bergeman
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