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The advent of hybrid computing platforms consisting of quantum processing units integrated with conventional high-performance computing brings new opportunities for algorithm design. By strategically offloading select portions of the…

We describe a path-integral approach for including nuclear quantum effects in non-adiabatic chemical dynamics simulations. For a general physical system with multiple electronic energy levels, a corresponding isomorphic Hamiltonian is…

Statistical Mechanics · Physics 2018-06-05 Xuecheng Tao , Philip Shushkov , Thomas Miller

Adiabatic quantum computation (AQC), which is particularly useful for combinatorial optimization, becomes more powerful by using excited states, instead of ground states. However, the excited-state AQC is prone to errors due to dissipation.…

Quantum Physics · Physics 2020-12-22 Hayato Goto , Taro Kanao

Non-Hermitian Hamiltonians are relevant to describe the features of a broad class of physical phenomena, ranging from photonics and atomic and molecular systems to nuclear physics and mesoscopic electronic systems. An important question…

Mesoscale and Nanoscale Physics · Physics 2021-04-21 Ygor Pará , Giandomenico Palumbo , Tommaso Macrì

Quantum molecular dynamics requires an accurate representation of the molecular potential energy surface from a minimal number of electronic structure calculations, particularly for nonadiabatic dynamics where excited states are required.…

Chemical Physics · Physics 2016-08-24 Charles W. Heaps , David A. Mazziotti

We study the dynamics of a driven non-Hermitian superconducting qubit which is perturbed by quantum jumps between energy levels, a purely quantum effect with no classical correspondence. The quantum jumps mix the qubit states leading to…

Quantum Physics · Physics 2021-10-05 Weijian Chen , Maryam Abbasi , Yogesh N. Joglekar , Kater W. Murch

Simulating quantum many-body systems is a highly demanding task since the required resources grow exponentially with the dimension of the system. In the case of fermionic systems, this is even harder since nonlocal interactions emerge due…

We characterize excited state quantum phase transitions in the two dimensional limit of the vibron model with the quantum fidelity susceptibility, comparing the obtained results with the information provided by the participation ratio. As…

Quantum Physics · Physics 2022-01-05 J. Khalouf-Rivera , M. Carvajal , F. Pérez-Bernal

Accurate simulation of the non-adiabatic dynamics of molecules in excited electronic states is key to understanding molecular photo-physical processes. Here we present a novel method, based on a semiclassical approximation, that is as…

Chemical Physics · Physics 2016-05-24 Alexander White , Sergei Tretiak , Dmitry Mozyrsky

Quantum computation offers potential exponential speedups for simulating certain physical systems, but its application to nonlinear dynamics is inherently constrained by the requirement of unitary evolution. We propose the quantum Koopman…

Quantum Physics · Physics 2025-07-30 Baoyang Zhang , Zhen Lu , Yaomin Zhao , Yue Yang

We formulate a method for incorporating quantum fluctuations into molecular- dynamics simulations of many-body systems, such as those employed for energetic nuclear collision processes. Based on Fermi's Golden Rule, we allow spontaneous…

Nuclear Theory · Physics 2009-10-28 Akira Ohnishi , Jorgen Randrup

The recent advancement of quantum computer hardware offers the potential to simulate quantum many-body systems beyond the capability of its classical counterparts. However, most current works focus on simulating the ground-state properties…

Quantum Physics · Physics 2022-06-14 Chee Kong Lee , Shi-Xin Zhang , Chang-Yu Hsieh , Shengyu Zhang , Liang Shi

One among the possible realizations of non-Hermitian systems is based on open quantum systems by omitting quantum jumping terms in the master equation. This is a good approximation at short times where the effects of quantum jumps can be…

Quantum Physics · Physics 2023-09-21 Xiangyu Niu , Jianning Li , S. L. Wu , X. X. Yi

Accurate simulation of dynamical processes in molecules and reactions is among the most challenging problems in quantum chemistry. Quantum computers promise efficient chemical simulation, but the existing quantum algorithms require many…

Efficient numerical methods are still lacking to probe the unconventional dynamics of quantum many-body systems under non-unitary evolution. In this work, we use Faber polynomials to numerically simulate both the dynamics of non-Hermitian…

Quantum Physics · Physics 2025-04-09 Rafael D. Soares , Marco Schirò

We develop a density matrix formalism to describe coupled electron-nuclear dynamics. To this end we introduce an effective Hamiltonian formalism that describes electronic transitions and small (quantum) nuclear fluctuations along a…

Chemical Physics · Physics 2020-09-07 Eugene Stolyarov , Alexander White , Dmitry Mozyrsky

Modeling electronic systems is an important application for quantum computers. In the context of materials science, an important open problem is the computational description of chemical reactions on surfaces. In this work, we outline a…

Noise is ubiquitous in real quantum systems, leading to non-Hermitian quantum dynamics, and may affect the fundamental states of matter. Here we report in experiment a quantum simulation of the two-dimensional non-Hermitian quantum…

Quantum Physics · Physics 2022-07-01 Zidong Lin , Lin Zhang , Xinyue Long , Yu-ang Fan , Yishan Li , Kai Tang , Jun Li , XinFang Nie , Tao Xin , Xiong-Jun Liu , Dawei Lu

We develop a trajectory-based approach for excited-state molecular dynamics simulations of systems subject to an external periodic drive. We combine the exact-factorization formalism, allowing to treat electron-nuclear systems in…

Chemical Physics · Physics 2021-03-31 Marco Schirò , Florian G. Eich , Federica Agostini

We discuss the emulation of non-Hermitian dynamics during a given time window by a low-dimensional quantum system coupled to a finite set of equidistant discrete states acting as an effective continuum. We first emulate the decay of an…

Quantum Physics · Physics 2025-02-05 Eloi Flament , François Impens , David Guéry-Odelin