Related papers: Quenching-driven equatorial depletion and limb asy…
The atmospheres of ultra-hot Jupiters are commonly considered to be at thermochemical equilibrium. We aim to provide disequilibrium chemistry maps for a global understanding of the chemistry in HAT-P-7b's atmosphere and assess the…
We investigate the effects of atmospheric circulation on the chemistry of the hot Jupiter HD 209458b. We use a simplified dynamical model and a robust chemical network, as opposed to previous studies which have used a three dimensional…
The atmospheric metallicity greatly influences the composition of exoplanet atmospheres. The effect of metallicity on the thermochemical equilibrium is well studied, though its effect on the disequilibrium abundance is loosely constrained.…
Due to their likely tidally synchronized nature, (ultra)hot Jupiter atmospheres should experience strongly spatially heterogeneous instellation. The large irradiation contrast and resulting atmospheric circulation induce temperature and…
With JWST, observing separate spectra of the morning and evening limbs of hot Jupiters has finally become a reality. The first such observation was reported for WASP-39b, where the evening terminator was observed to have a larger transit…
Transport-induced quenching, i.e., the homogenisation of chemical abundances by atmospheric advection, is thought to occur in the atmospheres of hot gas giant exoplanets. While some numerical modelling of this process exists, the…
On hot Jupiter exoplanets, strong horizontal and vertical winds should homogenize the abundances of the important absorbers CH$_4$ and CO much faster than chemical reactions restore chemical equilibrium. This effect, typically neglected in…
Aerosols is an old topic in the young field of exoplanet atmospheres. Understanding what they are, how they form, and where they go has long provided a fertile playground for theorists. For observers, however, aerosols have been a…
Almost all planetary atmospheres are affected by disequilibrium chemical processes. In this paper we introduce our recently developed Chemical Kinetic Model (\texttt{ChemKM}). We show that the results of our HD189733b model are in good…
Hot Jupiters have temperature gradients of several hundreds of degrees between their permanent day and nightsides. In equilibrium, the primary carbon reservoir is expected to transition from CO on the dayside to CH4 on the nightside. Theory…
We have developed 1-D photochemical and thermochemical kinetics and diffusion models for the transiting exoplanets HD 189733b and HD 209458b to study the effects of disequilibrium chemistry on the atmospheric composition of "hot Jupiters."…
Ultra-hot Jupiters are perfect targets for transmission spectroscopy. However, their atmospheres feature strong spatial variations in temperature, chemistry, dynamics, cloud coverage, and scale height. This makes transit observations at…
We have developed a one-dimensional thermochemical kinetics and diffusion model for Jupiter's atmosphere that accurately describes the transition from the thermochemical regime in the deep troposphere (where chemical equilibrium is…
Vertical mixing disrupts the thermochemical equilibrium and introduces additional heat flux that alters exoplanetary atmospheric temperatures. We investigate how this mixing-induced heat flux affects atmospheric chemistry. Temperature…
High-resolution spectroscopy has provided a wealth of information about the climate and composition of ultra-hot Jupiters. However, the 3D structure of their atmospheres makes observations more challenging to interpret, necessitating 3D…
Turbulent transport driven by secular shear instabilities can lead to enhanced vertical mixing in hot Jupiter atmospheres, impacting their cloudiness, chemistry and overall vertical structure. We discuss the turbulent regime expected and…
Transmission spectroscopy has provided unprecedented insight into the makeup of exoplanet atmospheres. A transmission spectrum contains contributions from a planet's morning and evening limbs, which can differ in temperature, composition…
The past decade has seen significant progress on the direct detection and characterization of young, self-luminous giant planets at wide orbital separations from their host stars. Some of these planets show evidence for disequilibrium…
Aerosols appear to be ubiquitous in close-in gas giant atmospheres, and disequilibrium chemistry likely impacts the emergent spectra of these planets. Lofted aerosols and disequilibrium chemistry are caused by vigorous vertical transport in…
We present highlights from a large set of simulations of a hot Jupiter atmosphere, nominally based on HD 209458b, aimed at exploring both the evolution of the deep atmosphere, and the acceleration of the zonal flow or jet. We find the…