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Two-dimensional ferroelectric materials are beneficial for power-efficient memory devices and transistor applications. Here, we predict out-of-plane ferroelectricity in a new family of buckled metal oxide (MO; M: Ge, Sn, Pb) monolayers with…

Applied Physics · Physics 2024-10-28 Ateeb Naseer , Musaib Rafiq , Somnath Bhowmick , Amit Agarwal , Yogesh Singh Chauhan

Functionalities in crystalline materials are determined by 3-dimensional collective interactions of atoms. The confinement of dimensionality in condensed matter provides an exotic research direction to understand the interaction of atoms,…

The capacity and stability of constituent electrodes determine the performance of Li-ion batteries. In this study, density functional theory is employed to explore the potential application of recently synthesized two dimensional…

Mesoscale and Nanoscale Physics · Physics 2014-09-24 Shijun Zhao , Wei Kang

The development of safe, efficient, and reversible hydrogen storage materials is critical for advancing hydrogen-based energy technologies and achieving carbon-neutral goals. Ennea-Graphene, a new 2D carbon allotrope made of 4-, 5-, 6-, and…

We perform first-principles calculations to explore electronic, thermodynamic, and dielectric properties of two-dimensional (2D) layered, alkaline-earth hydroxides Ca(OH)2 and Mg(OH)2. We calculate the lattice parameters, exfoliation…

Materials Science · Physics 2022-04-12 Mehrdad Rostami Osanloo , Kolade A. Oyekan , William G. Vandenberghe

Among exciting recent advances in the field of two-dimensional (2D) materials, the successful fabrications of the C60 fullerene networks has been a particularly inspiring accomplishment. Motivated by the recent achievements, herein we…

Materials Science · Physics 2023-08-11 Bohayra Mortazavi , Yves Remond , Hongyuan Fang , Timon Rabczuk , Xiaoying Zhuang

The hydrogen-methane compound (H_2)_4CH_4---or for short H4M---is one of the most promising hydrogen-storage materials. This van der Waals compound is extremely rich in molecular hydrogen: 33.3 mass%, not including the hydrogen bound in…

Materials Science · Physics 2012-10-09 Q. Li , T. Thonhauser

Metal-organic frameworks (MOFs) have emerged as promising materials for carbon capture applications due to their high CO2 capacities and tunable properties. Amongst the many possible MOFs, metal-substituted compounds based on M-DOBDC and…

Materials Science · Physics 2016-03-11 Hyun Seung Koh , Malay Kumar Rana , Jinhyung Hwang , Donald J. Siegel

The energy demands for the growing development of society need to be catered with alternative and green fuels like hydrogen energy for a lasting and sustainable culture. One essential component of the hydrogen economy is the efficiency of…

Materials Science · Physics 2023-03-07 Mukesh Singh , Alok Shukla , Brahmananda Chakraborty

Identifying applicable anode materials is a significant task for Li- and Na-ion battery (LIB and NIB) technologies. We propose the GaN monolayer (2D GaN) can be a good anode candidate. The GaN monolayer manifests stable Li/Na adsorption and…

Materials Science · Physics 2018-12-31 Xiaoming Zhang , Lei Jin , Xuefang Dai , Guifeng Chen , Guodong Liu

Two-dimensional materials composed of transition metal carbides and nitrides (MXenes) are poised to revolutionize energy conversion and storage. In this work, we used density functional theory (DFT) to investigate adsorption of Mg and Na…

Materials Science · Physics 2021-12-01 G. Chaney , D. Çakır , F. M. Peeters , C. Ataca

Efficient and high capacity storage materials are indispensable for a hydrogen-based economy. In silico tools can accelerate the process of discovery of new adsorbent materials with optimal hydrogen adsorption enthalpies. Density functional…

Chemical Physics · Physics 2020-06-26 Srimukh Prasad Veccham , Martin Head-Gordon

Hydrogen gas is a promising alternative to fossil fuels due to its high energy output and environmentally safe byproducts. Various morphologies of photocatalytic materials have been explored for high-efficiency H$_2$ production, for…

Materials Science · Physics 2025-03-04 Adway Gupta , Arunima Singh

The hydrogen adsorption sites in MOF5 were determined using neutron powder diffraction along with first-principles calculations. The metal-oxide cluster is primarily responsible for the adsorption while the organic linker plays only a…

Materials Science · Physics 2009-11-11 T. Yildirim , M. R. Hartman

In this work, we have studied the hydrogen adsorption-desorption properties and storage capacities of Li functionalized [2,2,2]paracyclophane (PCP222) using dispersion-corrected density functional theory and molecular dynamic simulation.…

Chemical Physics · Physics 2023-01-11 Rakesh K. Sahoo , Sridhar Sahu

Fast-growing electronics industry and future energy storage needs have encouraged the design of rechargeable batteries with higher storage capacities, and longer life times. In this regard, two-dimensional (2D) materials, specifically boron…

Applied Physics · Physics 2018-03-21 Meysam Makaremi , Bohayra Mortazavi , Chandra Veer Singh

Magnesium hydride has great potential as a solid hydrogen (H) storage material because of its high H storage capacity of 7.6 wt%. However, its slow hydrogenation and dehydrogenation kinetics and the high temperature of 300 $^\circ$C…

Materials Science · Physics 2023-04-25 R. Kadono , M. Hiraishi , H. Okabe , A. Koda , T. U. Ito

Two-dimensional (2D) boron-based materials have gained increasing interest due to their exceptional physicochemical properties and potential technological applications. In this way, borospherenes, a 2D Boron-based fullerene-like lattice…

The storage of hydrogen (H$_2$) is of economic and ecological relevance, because it could potentially replace petroleum-based fuels. However, H$_2$ storage at mild condition remains one of the bottlenecks for its widespread usage. In order…

Materials Science · Physics 2019-12-24 Srimanta Pakhira , Jose L. Mendoza-Cortes

Covalent functionalization is a way to tune the electrochemical properties of hexagonal boron nitride (h-BN) monolayers. The wide band gap insulator h-BN may become metallic conductor upon functionalization with strong oxidants, such as…

Materials Science · Physics 2018-08-23 Karoly Nemeth