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The adaptive perturbation method decomposes a Hamiltonian by the diagonal elements and non-diagonal elements of the Fock state. The diagonal elements of the Fock state are solvable but can contain the information about coupling constants.…

High Energy Physics - Theory · Physics 2020-12-25 Chen-Te Ma

The electron-phonon interaction plays a crucial role in many fields of physics and chemistry. Nevertheless, its actual calculation by means of modern many-body perturbation theory is weakened by the use of model Hamiltonians that are based…

Materials Science · Physics 2015-05-15 Andrea Marini , Samuel Poncé , Xavier Gonze

Quantum entanglement is a concept commonly used with reference to the existence of certain correlations in quantum systems that have no classical interpretation. It is a useful resource to enhance the mutual information of memory channels…

Quantum Physics · Physics 2009-11-13 Tina A. C. Maiolo , Fabio Della Sala , Luigi Martina , Giulio Soliani

Perturbation theory with respect to the kinetic energy of the heavy component of a two-component quantum system is introduced. An effective Hamiltonian that is accurate to second order in the inverse heavy mass is derived. It contains a new…

Quantum Physics · Physics 2024-06-21 Ryan Requist

Systems with strong electronic Coulomb correlations often display rich phase diagrams exhibiting different ordered phases involving spin, charge, or orbital degrees of freedom. The theoretical description of the interplay of the…

Strongly Correlated Electrons · Physics 2024-01-09 E. Linnér , A. I. Lichtenstein , S. Biermann , E. A. Stepanov

The calculation of the ground state and thermodynamics of mass-imbalanced Fermi systems is a challenging many-body problem. Even in one spatial dimension, analytic solutions are limited to special configurations and numerical progress with…

Quantum Gases · Physics 2018-07-20 Lukas Rammelmüller , William J. Porter , Joaquín E. Drut , Jens Braun

An accurate determination of the electron correlation energy is essential for describing the structure, stability, and function in a wide variety of systems, ranging from gas-phase molecular assemblies to condensed matter and…

Chemical Physics · Physics 2014-03-05 Alberto Ambrosetti , Anthony M. Reilly , Robert A. DiStasio , Alexandre Tkatchenko

A variant of coupled-cluster theory is described here, wherein the degrees of freedom are fluctuations of fragments between internally correlated states. The effects of intra-fragment correlation on the inter-fragment interaction are…

Chemical Physics · Physics 2019-05-24 Yuhong Liu , Anthony D. Dutoi

We study the energy level spacing of perturbed conformal minimal models in finite volume, considering perturbations of such models that are massive but not necessarily integrable. We compute their spectrum using a renormalization group…

Statistical Mechanics · Physics 2015-05-18 G. P. Brandino , R. M. Konik , G. Mussardo

We develop a multi-reference perturbation theory for electronic structure calculations based on symmetries of the Hamiltonian. The reference Hamiltonian in the symmetry-based perturbation theory (SBPT) is chosen such that it possesses more…

Quantum Physics · Physics 2026-03-10 Hiromichi Nishimura , Nam Nguyen , Tanvi Gujarati , Mario Motta

A procedure for calculation of rotation-vibration states of medium sized molecules is presented. It combines the advantages of variational calculations and perturbation theory. The vibrational problem is solved by diagonalizing a…

Chemical Physics · Physics 2015-04-13 A. I. Pavlyuchko , S. N. Yurchenko , Jonathan Tennyson

Representing a strongly interacting multi-particle wave function in a finite product basis leads to errors. Simple rescaling of the contact interaction can preserve the low-lying energy spectrum and long-wavelength structure of wave…

Quantum Gases · Physics 2011-08-23 Thomas Ernst , David W. Hallwood , Jake Gulliksen , Hans-Dieter Meyer , Joachim Brand

Electron correlation effects are essential for an accurate ab initio description of molecules. A quantitative a priori knowledge of the single- or multi-reference nature of electronic structures as well as of the dominant contributions to…

Quantum Physics · Physics 2012-12-18 Katharina Boguslawski , Paweł Tecmer , Örs Legeza , Markus Reiher

Understanding the non-equilibrium dynamics of extended quantum systems after the trigger of a sudden, global perturbation (quench) represents a daunting challenge, especially in the presence of interactions. The main difficulties stem from…

Strongly Correlated Electrons · Physics 2009-11-13 Alexandre Faribault , Pasquale Calabrese , Jean-Sebastien Caux

Due to the infinite summation of bubble diagrams, the $GW$ approximation of Green's function perturbation theory has proven particularly effective in the weak correlation regime, where this family of Feynman diagrams is important. However,…

We develop a theoretical method within the framework of relativistic many-body theory to accurately treat correlation corrections in atoms with few valence electrons. This method combines the all-order approach currently used in precision…

Atomic Physics · Physics 2009-09-01 M. S. Safronova , M. G. Kozlov , W. R. Johnson , Dansha Jiang

A large collaboration carefully benchmarks 20 first principles many-body electronic structure methods on a test set of 7 transition metal atoms, and their ions and monoxides. Good agreement is attained between the 3 systematically converged…

A scaling theory is used to study the low energy physics of electron-electron interactions in a double quantum dot. We show that the fact that electrons are delocalized over two quantum dots does not affect the instability criterion for the…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Shaffique Adam , Piet W. Brouwer , Prashant Sharma

In this work the determination of low-energy bound states in Quantum Chromodynamics is recast so that it is linked to a weak-coupling problem. This allows one to approach the solution with the same techniques which solve Quantum…

High Energy Physics - Theory · Physics 2009-10-28 K. G. Wilson , T. Walhout , A. Harindranath , W. M. Zhang , R. J. Perry , S. Glazek

Model Hamiltonians with long-range interaction yield energies that are corrected taking into account the universal behavior of the electron-electron interaction at short range. Although the intention of the paper is to explore the…

Chemical Physics · Physics 2020-10-28 Andreas Savin