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Polymer self-consistent field theory techniques are used to derive quantum density functional theory without the use of the theorems of density functional theory. Instead, a free energy is obtained from a partition function that is…

Chemical Physics · Physics 2022-11-29 Russell B. Thompson

A representation of polymer self-consistent field theory equivalent to quantum density functional theory is given in terms of non-orthogonal basis sets. Molecular integrals and self-consistent equations for spherically symmetric systems…

Atomic Physics · Physics 2026-02-05 Phil A. LeMaitre , Russell B. Thompson

In this work, we derive the time-dependent Hartree(-Fock) equations as an effective dynamics for fermionic many-particle systems. Our main results are the first for a quantum mechanical mean-field dynamics for fermions; in previous works,…

Mathematical Physics · Physics 2014-05-23 Sören Petrat

Polymer self-consistent field theory techniques are used to find radial electron densities and total binding energies for isolated atoms. Quantum particles are modelled as Gaussian threads with ring-polymer architecture in a four…

Quantum Physics · Physics 2022-11-30 Russell B. Thompson

The motivations for the construction of an 8-component representation of fermion fields based on a two dimensional representation of time reversal transformation and CPT invariance are discussed. Some of the elementary properties of the…

High Energy Physics - Theory · Physics 2007-05-23 S. Ying

An alternative approach to density functional theory based on self-consistent field theory for ring polymers is applied to neutral atoms hydrogen to neon in their ground states. The spontaneous emergence of atomic shell structure and…

Quantum Physics · Physics 2026-02-05 Phil A. LeMaitre , Russell B. Thompson

The Feynman quantum-classical isomorphism between classical statistical mechanics in 3+1 dimensions and quantum statistical mechanics in 3 dimensions is used to connect classical polymer self-consistent field theory with quantum…

Quantum Physics · Physics 2021-11-30 Russell B. Thompson

Background: The Hartree-Fock mean-field approximation is standard in combination with energy density functionals (EDF) that account for some dynamical correlations. Breaking and restoring the symmetries of the system allow for the inclusion…

Nuclear Theory · Physics 2023-11-20 Joshua Cesca , Cédric Simenel

Background: Idealised systems are commonly used in nuclear physics and condensed matter. For instance, the construction of nuclear energy density functionals involves properties of infinite matter, while neutron drops are used to test…

Nuclear Theory · Physics 2021-01-08 A. W. Bray , C. Simenel

The paper presents the representation of quantum field theory without introduction of infinity bare masses and coupling constants of fermions. Counter-terms, compensating for divergent quantities in self-energy diagrams of fermions and…

General Physics · Physics 2015-02-03 V. P. Neznamov

We introduce a new method for deriving the time-dependent Hartree or Hartree-Fock equations as an effective mean-field dynamics from the microscopic Schroedinger equation for fermionic many-particle systems in quantum mechanics. The method…

Mathematical Physics · Physics 2016-11-29 Sören Petrat , Peter Pickl

The theory of a massless two-dimensional scalar field with a periodic boundary interaction is considered. At a critical value of the period this system defines a conformal field theory and can be re-expressed in terms of free fermions,…

High Energy Physics - Theory · Physics 2009-10-09 J. Polchinski , L. Thorlacius

We study the breaking of spin symmetry for the nonlinear Hartree-Fock model describing an infinite translation-invariant interacting quantum gas (fluid phase). At zero temperature and for the Coulomb interaction in three space dimensions,…

Mathematical Physics · Physics 2019-05-30 David Gontier , Mathieu Lewin

We consider hamiltonian models representing an arbitrary number of spin $1/2$ fermion quantum fields interacting through arbitrary processes of creation or annihilation of particles. The fields may be massive or massless. The interaction…

Mathematical Physics · Physics 2020-01-08 Benjamin Alvarez , Jérémy Faupin , Jean-Claude Guillot

Problems of self-interaction arise in both classical and quantum field theories. To understand how such problems are to be addressed in a quantum theory of the Dirac and electromagnetic fields (quantum electrodynamics), we can start by…

Quantum Physics · Physics 2024-07-01 Charles T. Sebens

The equations of time-dependent density functional theory are derived, via the expression for the quantum weak value, from ring polymer quantum theory using a symmetry between time and imaginary time. The imaginary time path integral…

Quantum Physics · Physics 2025-03-21 Russell B. Thompson , Zarin Tasneem , Yves Caudano

We study the dynamics of a Fermi gas with a Coulomb interaction potential, and show that, in a mean-field limiting regime, the dynamics is described by the Hartree-Fock equation. This extends previous work of Bardos et al. to the case of…

Mathematical Physics · Physics 2011-08-30 Juerg Froehlich , Antti Knowles

Following Ref. [Oriols X 2007 Phys. Rev. Lett., 98 066803], an algorithm to deal with the exchange interaction in non-separable quantum systems is presented. The algorithm can be applied to fermions or bosons and, by construction, it…

Quantum Physics · Physics 2014-08-05 A. Alarcón , S. Yaro , X. Cartoixà , X. Oriols

We develop a quantum kinetic theory of two-dimensional electron gases in which exchange is treated self-consistently at the Hartree-Fock level and enters as a nonlocal, momentum-dependent field in phase space. By starting from the Coulomb…

Mesoscale and Nanoscale Physics · Physics 2026-03-30 J. L. Figueiredo , J. T. Mendonça , H. Terças

We propose and study a model for the equilibrium statistical mechanics of a pressurised semiflexible polymer ring. The Hamiltonian has a term which couples to the algebraic area of the ring and a term which accounts for bending…

Statistical Mechanics · Physics 2009-11-13 Mithun K. Mitra , Gautam I. Menon , R. Rajesh
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