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The determination of thermal and vibrational relaxation rates of triatomic systems suitable for application in hypersonic model calculations is discussed. For this, potential energy surfaces for ground and electronically excited state…

Chemical Physics · Physics 2020-11-06 Debasish Koner , Raymond J. Bemish , Markus Meuwly

Vibrational motions in electronically excited states can be observed by either time and frequency resolved infrared absorption or by off resonant stimulated Raman techniques. Multipoint correlation function expressions are derived for both…

Quantum Physics · Physics 2017-09-13 Konstantin E. Dorfman , Benjamin P. Fingerhut , Shaul Mukamel

Superconducting electrical circuits can be used to study the physics of cavity quantum electrodynamics (QED) in new regimes, therefore realizing circuit QED. For quantum information processing and quantum optics, an interesting regime of…

Quantum Physics · Physics 2009-01-23 Maxime Boissonneault , J. M. Gambetta , Alexandre Blais

We review recent theoretical work on two closely related issues: excitation of an isolated quantum condensed matter system driven adiabatically across a continuous quantum phase transition or a gapless phase, and apparent relaxation of an…

Quantum Gases · Physics 2015-05-14 Jacek Dziarmaga

Two state-of-the-art computational approaches: quantum Monte Carlo (QMC), based on accurate total energies, and GW with exciton effects (GW-BSE), based on perturbation theory are employed to calculate ionization potentials, electron…

Materials Science · Physics 2009-10-31 Jeffrey C. Grossman , Michael Rohlfing , Lubos Mitas , Steven G. Louie , Marvin L. Cohen

Quantum chemistry simulations offer a cost-effective way for computational design of BODIPY photosensitizers with potential use in photodynamic therapy (PDT). However, accurate predictions of photophysical properties, such as excitation…

One of the goals in quantum simulation is to adiabatically generate the ground state of a complicated Hamiltonian by starting with the ground state of a simple Hamiltonian and slowly evolving the system to the complicated one. If the…

Quantum Physics · Physics 2015-08-24 Bryce Yoshimura , J. K. Freericks

The nonequilibrium dynamics of a quantum dot with electron-phonon interactions described by a generalized Holstein model is presented. A combination of methodologies including the reduced density matrix formalism, the multilayer…

Strongly Correlated Electrons · Physics 2015-06-18 Eli Y. Wilner , Haobin Wang , Michael Thoss , Eran Rabani

Non-adiabatic dynamics simulations have become a standard approach to explore photochemical reactions. Such simulations require underlying potential energy surfaces and couplings between them, calculated at a chosen level of theory, yet…

Chemical Physics · Physics 2024-05-28 Thomas V. Papineau , Denis Jacquemin , Morgane Vacher

The development of high-performance electron sources requires theoretical frameworks that accurately link the microscopic electronic properties of cathode materials to their macroscopic photoemission observables. Here, we present a…

Materials Science · Physics 2026-02-16 Richard Schier , Chen Wang , Jonas Dube , Julius Kühn , Alice Galdi , Thorsten Kamps , Caterina Cocchi

The increasing need to simulate the dynamics of photoexcited molecular and nanosystems in the sub-picosecond regime demands new efficient tools able to describe the quantum nature of matter at a low computational cost. By combining the…

We explore the potential for hybrid development of quantum hardware where currently available quantum computers simulate open Cavity Quantum Electrodynamical (CQED) systems for applications in optical quantum communication, simulation and…

Building on recent advances in quantum algorithms which measure and reuse qubits and in efficient classical simulation leveraging projective measurements, we extend these frameworks to real-time dynamics of quantum many-body systems…

Quantum Physics · Physics 2025-12-08 Bo Xiao , Benedikt Kloss , E. Miles Stoudenmire

We argue the feasibility to study the phase structure of a quantum physical system on quantum devices via adiabatic preparation of states. We introduce a novel method and successfully test it in application to the Schwinger model in the…

High Energy Physics - Lattice · Physics 2024-12-11 Oleg Kaikov , Theo Saporiti , Vasily Sazonov , Mohamed Tamaazousti

Atom-photon bound states arise from the coupling of quantum emitters to the band edge of dispersion-engineered waveguides. Thanks to their tunable-range interactions, they are promising building blocks for quantum simulators. Here, we study…

Nonadiabatic molecular dynamics offers a powerful tool for studying the photochemistry of molecular systems. Key to any nonadiabatic molecular dynamics simulation is the definition of its initial conditions, ideally representing the initial…

Chemical Physics · Physics 2023-09-08 Antonio Prlj , Daniel Hollas , Basile F. E. Curchod

Accurate description of nonadiabatic dynamics of molecules at metal surfaces involving electron transfer has been a longstanding challenge for theory. Here, we tackle this problem by first constructing high-dimensional neural network…

Materials Science · Physics 2024-01-05 Gang Meng , James Gardner , Wenjie Dou , Reinhard J. Maurer , Bin Jiang

The quantum kinetics of photons is studied directly in real time by implementing the dynamical renormalization group. In contrast to conventional approach, the dynamical renormalization group method consistently includes off-shell (energy…

High Energy Physics - Phenomenology · Physics 2009-10-31 Shang-Yung Wang

We have performed quantum molecular dynamics simulations for dense helium to study the nonmetal-to-metal transition at high pressures. We present new results for the equation of state and the Hugoniot curve in the warm dense matter region.…

An overarching goal in the flourishing field of quantum simulation for high-energy physics is the first-principles study of the microscopic dynamics of scattering processes on a quantum computer. Currently, this is hampered by small system…