Related papers: Performance enhancement of electrocatalytic hydrog…
In water electrolysis, bubbles form on the electrode and interact through processes such as collision and coalescence. However, the impact of bubble coalescence a fundamental process governing electrolytic bubble behaviour-on electrolysis…
Electrolytically generated gas bubbles can significantly hamper the overall electrolysis efficiency. Therefore it is crucial to understand their dynamics in order to optimise water electrolyzer systems. Here we demonstrate a distinct…
The formation, growth and detachment of gas bubbles on electrodes are omnipresent in electrolysis and other gas-producing chemical processes. To better understand their role in the mass transfer efficiency, we perform experiments involving…
The dynamics of hydrogen bubbles produced by water electrolysis in an acidic electrolyte are studied using electrochemical and optical methods. A defined cyclic modulation of the electric potential is applied at a microelectrode to produce…
Enhancing the efficiency of water electrolysis, which can be severely impacted by the nucleation and growth of bubbles, is key in the energy transition. In this combined experimental and numerical study, in-situ bubble evolution and…
The removal of microbubbles from substrates is crucial for the efficiency of many catalytic and electrochemical gas evolution reactions in liquids. The current work investigates the coalescence and detachment of bubbles generated from…
Understanding how bubbles influence the efficiency of water electrolysis is crucial to achieve economically competitive hydrogen, generated by renewable energy sources, such as wind and solar power. Water electrolysis is typically performed…
Water electrolysis performed in microsystems with a fast change of voltage polarity produces optically invisible nanobubbles containing H2 and O2 gases. In this form the gases are able to the reverse reaction of water formation. Here we…
Bubble coalescence can promote bubble departure at much smaller sizes compared to buoyancy. This can critically enhance the efficiency of gas-evolving electrochemical processes, such as water electrolysis. In this study, we integrate…
Water electrolysis in a microsystem is observed and analyzed on a short-time scale ~10 us. Very unusual properties of the process are stressed. An extremely high current density is observed because the process is not limited by the…
Gas bubble accumulation on substrates reduces the efficiency of many physicochemical processes, such as water electrolysis. For microbubbles, where buoyancy is negligible, coalescence-induced jumping driven by the release of surface energy…
In gas evolving electrolysis, bubbles grow at electrodes due to a diffusive influx from oversaturation generated locally in the electrolyte by the electrode reaction. When considering electrodes of micrometer-size resembling catalytic…
We have studied the evolution of an excited electron bubble in superfluid 4He for several tens of picoseconds combining the dynamics of the liquid with an adiabatic evolution for the electron. The path followed by the excited bubble in its…
Three-dimensional direct numerical simulation of electrolysis is applied to investigate the growth and detachment of bubbles at electrodes. The moving gas-liquid interface is modeled employing the VOF-based method. To ensure the accuracy of…
Determining the nature of surface roughness and electrode pore structure on H2 bubble evolution rate and quantity, and bubble trapping under electrolytic conditions is important for quantifying useful gas production during total water…
A surprising phenomenon is presented: a bubble, produced from water electrolysis, is immobilized in the liquid (as if the Archimedes' buoyant force were annihilated). This is achieved using a nanoelectrode (1 nm to 1 $\mu$m of curvature…
Bubbles are known to influence energy and mass transfer in gas evolving electrodes. However, we lack a detailed understanding on the intricate dependencies between bubble evolution processes and electrochemical phenomena. This review…
Electrolysis of water is employed to produce surface nanobubbles on highly orientated pyrolytic graphite (HOPG) surfaces. Hydrogen (oxygen) nanobubbles are formed when the HOPG surface acts as negative (positive) electrode. Coverage and…
Inhibition of bubble coalescence in electrolyte solutions enables the formation of oceanic whitecaps and affects the heat and mass transfer in many bubble related engineering processes. For different electrolytes, the ability to inhibit…
A brief analysis of the physics and effects of electrolytic gas evolution is presented. Aspects considered include bubble nucleation, growth, and detachment, enhancement of mass and heat transfer, and decrease of apparent electrical…