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Photoelectrochemical (PEC) water splitting to generate hydrogen is one of the most studied methods for converting solar energy into clean fuel because of its simplicity and potentially low cost. Despite over 40 years of intensive research,…

Materials Science · Physics 2019-01-02 Ling-Ju Guo , Jun-Wei Luo , Tao He , Su-Huai Wei , Shu-Shen Li

We derive the photovoltaic conversion efficiency limit for two-terminal tandem solar cells with a perovskite top cell and silicon bottom cell with an embedded spectrum splitter. For large-bandgap top-cells a spectrum splitter strongly…

Optics · Physics 2020-12-24 Verena Neder , Stefan W. Tabernig , Albert Polman

The thermodynamic limit of photovoltaic efficiency for a single-junction solar cell can be readily predicted using the bandgap of the active light absorbing material. Such an approach overlooks the energy loss due to non-radiative…

Applied Physics · Physics 2021-06-21 Sunghyun Kim , Aron Walsh

The Shockley-Queisser (SQ) limit, introduced by W. Shockley and H. J. Queisser in 1961, is the most well-established fundamental efficiency limit for single-junction photovoltaic solar cells. For widely-studied semiconductors such as Si,…

Applied Physics · Physics 2021-06-09 Qian Zhou , Arfa Karani , Yaxiao Lian , Baodan Zhao , Richard H. Friend , Dawei Di

We develop a new approach to calculate the obtainable limit of photoconversion efficiency of tandem solar cells (SCs) and applied it to SCs with both vertical and lateral designs at AM0 and AM1.5 conditions. To get the maximum efficiency,…

Materials Science · Physics 2013-09-13 A. V. Sachenko , V. P. Kostylyov , N. P. Kulish , I. O. Sokolovskyi , A. I. Shkrebtii

Sub-micrometer thin films are promising platforms for emerging flexible photovoltaic devices. Although the current market already produces efficient solar cells, the average wafer thickness of these devices remains far from the…

Materials Science · Physics 2025-04-29 Cesar E. P. Villegas , Enesio Marinho , A. C. Dias , Pedro Venezuela , Alexandre R. Rocha

In recent years, halide perovskite-based solar cells have received intensive attention, and demonstrated power conversion efficiency as high as 25.8%. With regard to the toxicity of Pb and the instability of organic elements, all inorganic…

Materials Science · Physics 2022-05-04 Dibyajyoti Saikia , Mahfooz Alam , Jayanta Bera , Atanu Betal , Appala Naidu Gandhi , Satyajit Sahu

Transition metal dichalcogenide (TMD) materials have emerged as promising candidates for thin film solar cells due to their wide bandgap range across the visible wavelengths, high absorption coefficient and ease of integration with both…

Applied Physics · Physics 2020-07-01 Elaine McVay , Ahmad Zubair , Yuxuan Lin , Amirhasan Nourbakhsh , Tomás Palacios

The Shockley-Queisser limit describes the maximum solar energy conversion efficiency achievable for a particular material and is the standard by which new photovoltaic technologies are compared. This limit is based on the principle of…

Optics · Physics 2014-12-04 Yunlu Xu , Tao Gong , Jeremy N. Munday

Photovoltaic materials are recognized for their potential as sustainable energy sources that enable the conversion between light and electrical energy. However, solar cells have been unable to surpass the theoretical limit of 32%, known as…

Applied Physics · Physics 2024-06-18 Jeonggyu Hwang

Perovskite solar cells have shown power conversion efficiencies (PCE) comparable to cystalline silicon solar cell despite involving low-temperature, solution based synthesis processes outside clean room environment. As the theoretical PCE…

Applied Physics · Physics 2021-10-27 Harishankar Suman , Avijit Kumar

We analysed self-consistently photoconversion efficiency of direct-gap A3B5 semicon-ductors based solar cells and optimised their main physical characteristics. Using gallium ar-senide (GaAs) as the example and new efficient optimization…

Materials Science · Physics 2014-02-14 A. V. Sachenko , V. P. Kostylyov , M. R. Kulish , I. O. Sokolovskyi , A. Chkrebtii

Silicon solar cells dominate the solar cell market with record lab efficiencies reaching almost 26%. However, after 60 years of research, this efficiency saturated close to the theoretical limit for silicon, and radically new approaches are…

Other Condensed Matter · Physics 2018-01-30 Luis M. Pazos , Ju Min Lee , Anton Kirch , Maxim Tabachnyk , Richard H. Friend , Bruno Ehrler

The maximal concentration limit of solar radiation for photovoltaic applications is assumed to be constant, at Cmax\approx46,000 suns. This limit is easily found via a geometrical application of the 2nd law of thermodynamics to a radiation…

Materials Science · Physics 2012-07-18 Ze'ev R Abrams , Xiang Zhang

Cu based ternary chalcogenides are gathering attention for sustainable energy applications due to their reduced complexity compared to quaternary alternatives. We used drift diffusion modeling to evaluate the feasibility of photovoltaics…

Materials Science · Physics 2026-05-12 Saptarshi Mandal , Surbhi Ramawat , Sumit Kukreti , Ambesh Dixit

The pursuit of sustainable and highly efficient energy conversion necessitates a transition from toxic and unstable materials to environmentally friendly alternatives. This work presents a simulation-based numerical investigation of a fully…

Optics · Physics 2025-07-31 Md. Sad Abdullah Sami , Arpan Sur , Ehsanur Rahman

A modified detailed balance model is built to understand and quantify efficiency loss of perovskite solar cells. The modified model captures the light-absorption dependent short-circuit current, contact and transport-layer modified carrier…

Divalent cations mixed lead halide perovskites with enhanced performances, high stabilities, and reduced toxicity are requisite to make persistent progress in perovskite solar cells. However, the mixing strategy is not reported extensively…

Materials Science · Physics 2022-11-09 Anupriya Nyayban , Subhasis Panda , Avijit Chowdhury

Understanding the maximal enhancement of solar absorption in semiconductor materials by light trapping promises the development of affordable solar cells. However, the conventional Lambertian limit is only valid for idealized material…

Optics · Physics 2013-12-03 Yiling Yu , Lujun Huang , Linyou Cao

To be able to increase the efficiency of perovskite solar cells which is one of the most substantial challenges ahead in photovoltaic industry, the structural and optical properties of perovskite CH3NH3PbI3-xBrx for values x=1-3 have been…