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A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

The entropy production rate is a key quantity in non-equilibrium thermodynamics of both classical and quantum processes. No universal theory of entropy production is available to date, which hinders progress towards its full grasping. By…

Quantum Physics · Physics 2020-12-18 Alessio Belenchia , Luca Mancino , Gabriel T. Landi , Mauro Paternostro

We study the Fluctuation Theorem (FT) for entropy production in chaotic discrete-time dynamical systems on compact metric spaces, and extend it to empirical measures, all continuous potentials, and all weak Gibbs states. In particular, we…

Mathematical Physics · Physics 2026-02-13 Noé Cuneo , Vojkan Jakšić , Claude-Alain Pillet , Armen Shirikyan

Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…

Statistical Mechanics · Physics 2018-03-28 Sheldon Goldstein , David A. Huse , Joel L. Lebowitz , Pablo Sartori

The nonequilibrium thermodynamics of interacting quantum many-body systems is investigated within the framework of thermal time-dependent density functional theory using a generalized linear-response formulation for the full quantum work…

Quantum Physics · Physics 2025-12-23 Antonio Palamara , Francesco Plastina , Antonello Sindona , Irene D'Amico

We investigate the detailed properties of Observational entropy, introduced by \v{S}afr\'{a}nek et al. [Phys. Rev. A 99, 010101 (2019)] as a generalization of Boltzmann entropy to quantum mechanics. This quantity can involve multiple…

Quantum Physics · Physics 2019-01-17 Dominik Šafránek , J. M. Deutsch , Anthony Aguirre

Quantum Optimal Control Theory (QOCT) provides the necessary tools to theoretically design driving fields capable of controlling a quantum system towards a given state or along a prescribed path in Hilbert space. This theory must be…

Atomic and Molecular Clusters · Physics 2013-05-30 Alberto Castro , Jan Werschnik , Eberhard K. U. Gross

The second law of thermodynamics states that entropy increases (or does not change) by time in an isolated system. As microscopic physical laws are reversible, the origin of irreversibility is not straightforward. Although the outcome of a…

Statistical Mechanics · Physics 2013-02-19 Balint Szabo

Informational dependence between statistical or quantum subsystems can be described with Fisher matrix or Fubini-Study metric obtained from variations of the sample/configuration space coordinates. Using these non-covariant objects as…

High Energy Physics - Theory · Physics 2019-01-30 Vitaly Vanchurin

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this…

Quantum Physics · Physics 2025-12-02 J. M. Z. Choquehuanca

Observational entropy captures both the intrinsic uncertainty of a thermodynamic state and the lack of knowledge due to coarse-graining. We demonstrate two interpretations of observational entropy, one as the statistical deficiency…

Quantum Physics · Physics 2024-11-20 Ge Bai , Dominik Šafránek , Joseph Schindler , Francesco Buscemi , Valerio Scarani

The intersection of thermodynamics, quantum theory and gravity has revealed many profound insights, all the while posing new puzzles. In this article, we discuss an extension of equilibrium statistical mechanics and thermodynamics…

General Relativity and Quantum Cosmology · Physics 2019-08-13 Isha Kotecha

The classical Density Functional Theory (DFT) is introduced as an application of entropic inference for inhomogeneous fluids at thermal equilibrium. It is shown that entropic inference reproduces the variational principle of DFT when…

Statistical Mechanics · Physics 2021-09-14 Ahmad Yousefi , Ariel Caticha

Quantum Field Theory (QFT) makes predictions by combining two sets of assumptions: (1) quantum dynamics, such as a Schrodinger or Liouville equation; (2) quantum measurement, such as stochastic collapse to an eigenfunction of a measurement…

Quantum Physics · Physics 2007-05-23 Paul J. Werbos , Ludmila Dolmatova Werbos

The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…

Statistical Mechanics · Physics 2017-06-07 William Griffin , Michael Matty , Robert H. Swendsen

Quantum mechanical systems exhibit an inherently probabilistic nature upon measurement which excludes in principle the singular direct observability continual case. Quantum theory of time continuous measurements and quantum prediction…

Mathematical Physics · Physics 2007-05-23 V. P. Belavkin

We take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations and the laws of thermodynamics become well defined and viable for quantum many body…

Quantum Physics · Physics 2018-01-30 Jen-Tsung Hsiang , C. H. Chou , Y. Subaşi , B. L. Hu

A formulation of the density functional theory is constructed on the foundations of entropic inference. The theory is introduced as an application of maximum entropy for inhomogeneous fluids in thermal equilibrium. It is shown that entropic…

Statistical Mechanics · Physics 2023-12-29 Ahmad Yousefi , Ariel Caticha

It has been argued that gravity acts dissipatively on quantum-mechanical systems, inducing thermal fluctuations that become indistinguishable from quantum fluctuations. This has led some authors to demand that some form of time…

Mathematical Physics · Physics 2013-05-03 P. Fernandez de Cordoba , J. M. Isidro , Milton H. Perea