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We show that development of polar order may spontaneously destroy the lamellar structure of a liquid crystal. This results in an unusual sequence of phases with the ferroelectric nematic phase appearing below a non-polar smectic phase. The…

Ferroelectric nematic liquid crystals are formed by achiral molecules with large dipole moments. Its three-dimensional orientational order is universally described as unidirectionally polar. We demonstrate that the ground state of…

Soft Condensed Matter · Physics 2024-04-01 Priyanka Kumari , Bijaya Basnet , Maxim O. Lavrentovich , Oleg D. Lavrentovich

Ferroelectric nematic phases are a new class of polar fluids in which spontaneous polarization is directly coupled to the orientational order, providing unique opportunities for creating self-organized materils with spatially modulated…

Polar nematic liquid crystals have two special features, compared with conventional nematic liquid crystals. First, because of flexoelectricity, the combination of polar order and splay reduces the free energy. Second, because of…

Soft Condensed Matter · Physics 2025-07-08 Lincoln Paik , Jonathan V. Selinger

Topological spin and polar textures have fascinated people in different areas of physics and technologies. However, the observations are limited in magnetic and solid-state ferroelectric systems. Ferroelectric nematic is the first…

Soft Condensed Matter · Physics 2022-12-22 Jidan Yang , Yu Zou , Wentao Tang , Jinxing Li , Mingjun Huang , Satoshi Aya

Two-dimensional polar liquid crystals have been discovered recently in monolayers of anisotropic molecules. Here, we provide a systematic theoretical description of liquid-crystalline phases for polar particles in two spatial dimensions.…

Soft Condensed Matter · Physics 2014-01-28 Raphael Wittkowski , Hartmut Löwen , Helmut R. Brand

We develop a Landau theory for bend flexoelectricity in liquid crystals of bent-core molecules. In the nematic phase of the model, the bend flexoelectric coefficient increases as we reduce the temperature toward the nematic to polar phase…

Soft Condensed Matter · Physics 2013-05-28 Shaikh M. Shamid , Subas Dhakal , Jonathan V. Selinger

In liquid crystals, if flexoelectric couplings between polar order and director gradients are strong enough, the uniform nematic phase can become unstable to formation of a modulated polar phase. Previous theories have predicted two types…

Soft Condensed Matter · Physics 2018-06-21 Shaikh M. Shamid , David W. Allender , Jonathan V. Selinger

The recent discovery of a new ferroelectric nematic (NF) liquid crystalline phase became of utmost interest for the liquid crystal (LC) and the whole soft and condensed matter fields. Contrary to the previously known ferroelectric LC…

Various possibilities of polar self-organisation in low molar mass nematic, smectic and columnar liquid crystals are discussed with particular focus on the underlying molecular symmetries and interactions. Distinction is made between vector…

Materials Science · Physics 2013-09-10 A. G. Vanakaras , D. J. Photinos

Starting from a microscopic definition of an alignment vector proportional to the polarization, we discuss the hydrodynamics of polar liquid crystals with local $C_{\infty v}$-symmetry. The free energy for polar liquid crystals differs from…

Soft Condensed Matter · Physics 2009-11-11 William Kung , M. Cristina Marchetti , Karl Saunders

The recently discovered ferroelectric nematic liquids incorporate to the functional combination of fluidity, processability and anisotropic optical properties of nematic liquids, an astonishing range of physical properties derived from the…

Topological defects play a pivotal role in the physics of liquid crystals and represent one of the most prominent and well studied aspects of mesophases. While in two-dimensional nematics, disclinations are traditionally treated as…

Soft Condensed Matter · Physics 2016-07-28 Arthur J. Vromans , Luca Giomi

The nonlinear elastic properties of nematic liquid crystals have acquired new interest with the recent experimental observation of bulk modulated nematic phases which are composed by achiral molecules. We extend the Oseen-Zocher-Frank's…

Soft Condensed Matter · Physics 2018-11-09 I. Lelidis , G. Barbero

In soft matter, the polar orientational order of molecules can facilitate the coexistence of structural chirality and ferroelectricity. The ferroelectric nematic (NF) state, exhibited by achiral calamitic molecules with large dipole…

Soft Condensed Matter · Physics 2025-03-13 Hiroya Nishikawa , Yasushi Okumura , Dennis Kwaria , Atsuko Nihonyanagi , Fumito Araoka

Ferroelectricity, a hallmark of spontaneous inversion-symmetry breaking, has been a central concept in condensed matter physics and functional materials research, yet recent discoveries are revealing that switchable polarization can emerge…

Materials Science · Physics 2026-05-11 Yudi Yang , Changming Ke , Shi Liu

Recent experimental discoveries of novel nematic types with polar order, including ferroelectric nematic and splay nematic have brought the resurgence of the interest in polar and modulated phases. One of the most important factors that is…

Soft Condensed Matter · Physics 2023-05-18 Piotr Kubala , Michał Cieśla

Polarization flutter, produced by an applied AC electric field drives an equilibrium ferroelectric nematic ($\mathrm{N_F}$) liquid crystal (LC) through a transition into a dissipative active ferroelectric nematic state exhibiting strong…

Only a few years have passed since discovery of polar nematics, and now they are becoming the most actively studied liquid crystal materials. Despite numerous breakthrough findings made recently, a theoretical systematization is still…

Soft Condensed Matter · Physics 2023-09-28 A. V. Emelyanenko , V. Yu. Rudyak , F. Araoka , H. Nishikawa , K. Ishikawa

We have structurally characterized the liquid crystal phase that appears as an intermediate state when a dielectric nematic, having polar disorder of its molecular dipoles, transitions to the almost perfectly polar-ordered ferroelectric…

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